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In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

The effects of temperature, crack tip opening rate and rubber content on static fracture characteristics of CNBR (Cross-linked acryloNitrile Butadiene Rubber) modified epoxy adhesives were investigated under mode I loading. Loading-unloading tests were statically performed by using DCB (Double Cantilever Beam) specimens. The fracture toughness increased with increasing the rubber content. The fracture toughness of CNBR modified and unmodified epoxy adhesives was much influenced by temperature and crack tip opening rate. The surface topology of fractured surface was changed by temperature and type of adhesive.

The effects of inclusion of glass beads and rubber modification on the fatigue fracture characteristics of an epoxy adhesive were investigated. Hybrid effects were also investigated when not only the epoxy adhesive was rubber modified but also when glass beads were mixed simultaneously. Fatigue crack growth resistance was greatly increased due to glass beads, CTBN and CNBR modifications at the second stage of crack growth (da/dN=10-4-10-3 mm/cycle). However, the energy release rate at threshold for both CNBR and CTBN modified adhesives were lower than that for the unmodified adhesive. No significant hybrid effects were distinguishable.

The effects of CNBR (cross-linked acrylonitrile butadiene rubber) modification on the fracture characteristics of epoxy adhesives were investigated under Mode I static loading. Fracture tests were conducted by using DCB (double cantilever beam) specimens. Rubber content, adhesive thickness and loading rate were changed. The crack extension resistance (given by energy release rate) of the epoxy adhesives was much improved by CNBR modification. For the rubber modified epoxy adhesives, the crack extension resistance becomes high with an increase in adhesive thickness as well as loading rate. The reason why the CNBR modification improves the crack extension resistance was explained based on the surface observation and fractal dimension of the fractured surface.