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Urea-SCR system consisted of combined deNOx catalysts with wide range of temperature window, injector, sensor and injection controller. Synthetic gas activity test and NOx conversion efficiency test on the engine bench were carried out to evaluate and improve the performance of this system. To better suit the application of the urea-SCR system without engine modification, temperature of catalyst and engine RPM were used as input data to control amounts of urea aqueous solution that reacts with NOx. We concentrated on designing types of deNOx catalysts and controlling amounts of urea solution under different driving conditions to achieve higher NOx reduction and wider temperature window. Designed urea-SCR system showed substantial NOx reduction performance and relatively wide temperature window under different driving conditions.