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This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

Aldehydes and ketones are known as one of the hazardous air pollutants. Usually, acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are used for automotive exhaust carbonyls collection. Then, aldehydes and ketones combined with DNPH are analyzed by HPLC/UV (High Performance Liquid Chromatography/ Ultra Violet Detection). DNPH cartridge is used widely for a good point of the handling although handling of DNPH solution is not so convienient. However, the analytical result of acrolein using DNPH cartridge was known as the low reliability. Acrolein-DNPH is changed to acrolein-DNPH-DNPH in the cartridge with acid atmosphere before extraction. And then, acrorein-DNPH-DNPH is changed to acrorein-DNPH-DNPH-DNPH with an acid atmosphere. As a result of such chemical reaction before extraction, the acrolein-DNPH is detected to low concentration. We found that at the low temperature condition, acrolein-DNPH concentration decrease speed is held down.

This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.

The Agency of Natural Resources and Energy, Ministry of Economy, Trade and Industry has conducted conformity tests of diesel fuel containing Fatty Acid Methyl Ester (FAME) to amend diesel fuel standards in Japan. The objective of the tests is to examine appropriate specifications of diesel fuel containing FAME for automotive use for existing vehicles in the Japanese market. The conformity testing includes verification of fuel system component compatibility, tail pipe emissions, and characterization of the reliability and durability of the engine system, including the fuel injection system. In designing the conformity tests, the maximum FAME concentration was 5%. Most of the new standards are essentially equivalent to EN14214, but the total acid number (TAN) of specific acids, and oxidation stability of the new standards for diesel fuel containing FAME, are different from EN14214.

For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.

Impact of oil-derived ash on the pressure drop of continuous regeneration-type diesel particulate filter (CR-DPF) was investigated through 600hrs running test at maximum power point on a 6.9L diesel engine, which meets the Japanese long-term emission regulations enacted in 1998, using approximately 50ppm sulfur content fuel. Sulfated ash content of test oils were varied as 0.96, 1.31, and 1.70 mass%, respectively. During the running test, the exhaust pressure drop through CR-DPF was measured. And after the test, the ventilation resistance through CR-DPF was also evaluated before and after the baking process, which was applied to eliminate the effect of soot accumulated in CR-DPF. The results revealed that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF. According to microscope examination of the baked DPF, ash was mainly accumulated on the wall surface of CR-DPF, and that seemed to be related to the magnitude of pressure drop caused by ash.

In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.

Four urea SCR systems were developed and evaluated on a C/D and on the road to investigate their potential for Japanese emission regulations in 2005 and beyond. Test results showed that NOx conversion ratios were 50 to 70% during the Japanese D13 mode cycle, and the ratios under the transient driving cycle were lower than those tested during a steady state. Unregulated emissions, such as benzene, aldehyde and benzo[a]pyrene, existed either at a trace level using the oxidation catalyst, or lower than a base diesel engine, when no oxidation catalyst was used. The health effects of particulate matter emitted from the SCR system were almost the same as those from conventional diesel engines, as evaluated by the Ames test and in vitro micronucleus test. Thermal degradation products, such as cyanuric acid and melamine, were two to four figures lower compared with the toxicological information of Safety Information Resources Inc. (SIRI).

In this research, a test apparatus (VPT-HFRR) for evaluating lubricity was manufactured at an arbitrary pressure according to the lubricity test method (HFRR) for diesel fuel. The lubricity of LPG blended fuel (LBF) for diesel engines was examined using VPT-HFRR., This was a value close to that of diesel fuel, and when a suitable lubricity had been maintained, it was checked. Prototype trucks were manufactured and their durability was examined. After a run of 70,000km or more, no serious trouble had occurred, and when LBF was maintained at a suitable lubricity, it was checked.

Fuels of wide range of density and viscosity were tested by using a DI diesel engine that conforms to present Japanese regulations. A total of 9 fuels was tested. Six test fuels were commercial automotive diesel fuel available in Japan. In order to expand the density range, test fuels of kerosene, high-density diesel fuel and automotive diesel fuel in Singapore were also included. The density range was 0.796 to 0.856 (g/cm3), and the viscosity range was 1.52 to 5.44 (mm2/s). The test mode was Japanese D13. Also, some fuels were tested by the Japanese transient test mode. Moreover, fuel spray was observed by an optical method to clarify the relationship between viscosity and Sauter mean diameter.

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

A premixed charge compression ignition methanol engine targeting a drastic decrease in NOx emissions and a brake specific energy consumption equivalent to that of a DI diesel engine has been developed (1). The problems of this combustion system are that the brake thermal efficiency decreases, and CO and THC emissions increase due to a deterioration of high load combustion. The purpose of this study is to improve the high load combustion of a premixed charge compression ignition methanol engine using a flash boiling fuel injection technique. The results of this study have shown that the premixed charge compression ignition methanol combustion system using a flash boiling fuel injection technique increases the brake thermal efficiency, decreases CO and THC emissions, while maintaining low NOx emissions in the high load region.

A new combustion system targeting a drastic decrease in NOx emission and a brake specific energy consumption equivalent to that of a DI diesel engine has been developed. In this new combustion system, a lean burn system using early injection was employed to reduce NOx emission and an auto-ignition DI engine system was employed to achieve the low energy consumption. Methanol was used as the fuel for reducing NOx emission. The objective of this study is to clarify the possibility of the system for the auto-ignition of a premixed lean mixture of methanol fuel. This study shows that the gas temperature at ignition, Tig, is the predominant factor affecting auto-ignition. Auto-ignition occurs when Tig exceeds approximately 1000K. The methanol lean burn system in an auto-ignition DI engine drastically decreased NOx emission with almost the same brake specific energy consumption as a diesel engine in the middle load region.