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Thermal and mixing stratifications have been thought as one of the ways to avoid an excessive pressure rise on HCCI combustion. The purpose of this research is to investigate the potential of thermal and mixing stratifications for reducing PRR (Pressure Rise Rate) on HCCI combustion. The pre-mixture with thermal and mixing stratifications is charged in RCM (Rapid Compression Machine). After that, the pre-mixture is compressed and in that process, in-cylinder gas pressure and chemiluminescence images are obtained and analyzed. Furthermore, experimental results are compared with the computational results calculated by using multi-zone model for analyzing these mechanisms.