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Technical Paper

Development of Mo-Free Ultra-High Strength 1.6-GPa Bolt with Delayed Fracture Resistance for Multi-Link Type Engine

2024-04-09
2024-01-2070
Mo-free 1.6-GPa bolt was developed for a Variable Compression Turbo (VC-Turbo) engine, which is environment friendly and improves fuel efficiency and output. Mo contributes to the improvement of delayed fracture resistance; therefore, the main objective is to achieve both high strength and delayed fracture resistance. Therefore, Si is added to the developed steel to achieve high strength and delayed fracture resistance. The delayed fracture tests were performed employing the Hc/He method. Hc is the limit of the diffusible hydrogen content without causing a delayed fracture under tightening, and He is the diffusible hydrogen content entering under a hydrogen-charging condition equivalent to the actual environment. The delayed fracture resistance is compared between the developed steel and the SCM440 utilized for 1.2-GPa class bolt as a representative of the current high-strength bolts.
Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Journal Article

Development of Heat Resistant Titanium Alloy for Exhaust Valves Applicable for Motorcycles

2016-11-08
2016-32-0023
Amidst of the recent concerns on depletion of natural resources, a new heat resistant titanium alloy has been developed using the minimum amount of rare metals. Using Ti-811 as a basis and modifying the alloy composition to Ti-7Al-2Mo-0.2Si-0.15C-0.2Nb, the mechanical property, the creep resistance and the oxidation resistance at high temperatures are improved. At the same time, with the β transformation point shifted to a higher temperature, the hot formability is also improved. The newly developed alloy has made it possible to expand the application of titanium material to exhaust valves in reciprocating engines.
Journal Article

Development of High Fatigue Strength for Powder-Forged Connecting Rods

2008-04-14
2008-01-0849
Technology has been developed to increase the fatigue strength of powder-forged connecting rods. The fatigue strength of powder-forged materials was increased without adding special alloy components or lowering workability by adjusting the ratios of the conventional main mixed powders (iron, carbon, copper). In addition to solid solution strengthening of the ferrite using copper, reducing porosity, which is a material surface defect, is also an effective method of increasing fatigue strength. Reducing carbon content greatly reduced the occurrence of defects in the forging stage. The results of this research showed that the fatigue strength of high strength powder-forged connecting rods can be increased by 30% or more over that of conventional materials, allowing powder-forged connecting rods to be applied to even higher output and higher load engines than before.
Technical Paper

Development of 1600 N/mm2 Class Ultra-High Strength Bolts

2003-03-03
2003-01-1179
1 Many different bolts are employed in automobiles for different purposes and uses, and their strength generally ranges from 700 N/mm2 to 1200 N/mm2. Automobiles face the issue of making improvements in fuel economy as an environmental measure, and there is consequently a requirement to lighten component parts. The creationof higher-strength bolts is an important factor in achieving lighter weight. Increasing the strength, however, can also bring about an increased incidence of delayed fracture, and the conventional solution used to require the application of special steels such as expensive maraging steel. The present development addressed this issue by focusing on high carbon steel rod, which had been considered less susceptible to delayed fracture, although heading was also considered to be difficult. Heading techniques were therefore devised that made it possible not only to form bolts from this material, but also to provide satisfactory strength.
Technical Paper

The development of lead-free machinable aluminum alloy for environmental protection

2000-06-12
2000-05-0152
The influence of additional elements of aluminum alloy, especially of the elements other than conventional low melting point metals on machinability was investigated. Namely, the respective influences of Si, Ni, Mn and Fe on the machinability of AA6061 alloy used as base material were investigated. With the increase in the amount of each element the machinability of the alloy was improved. Si was the most effective among them, and Ni, Mn and Fe followed it in this order. It was found by microscopic observation that machinability was improved in proportion to the dispersion density of the second phase particles formed by the respective additional elements.
Technical Paper

Research on the Application of Aluminum Door Beams for Automobiles

1998-02-23
980454
The effect of cross-section and type of alloy on the performance of aluminum extrusions as door beams was investigated. As a result, aluminum door beams were developed which have bending properties comparing favorably with those of door beams made of high tensile strength steel with a tensile strength of 1470 N/mm2. Furthermore, a technology to design door beams with the required performance and bending properties dealing with various car models was developed by making the most of the versatility of aluminum extrusions produced in various types of cross-sections.
Technical Paper

Filiform Corrosion of Aluminum Auto Body Sheet in Accelerated and Outdoor Environments

1997-02-24
970735
This paper discusses a portion of a larger program on filiform corrosion concentrating on test methodologies and environmental mechanisms that contribute to filiform corrosion. It is organized into four sections, the first covers background of filiform corrosion, materials used in the study, and procedures for the sample preparation and testing. Following this, there are sections on outdoor testing, accelerated testing, and environmental parameters all of which include some procedural information, results and conclusions.
Technical Paper

Influence of Surface Treatments on Durability of Painted Aluminum Alloys

1997-02-24
970731
Increasing use of aluminum in automotive components has led to lower fuel consumption and enhanced performance of automotive designs. From a manufacturing standpoint, aluminum provides the additional advantage of utilizing same processes as steel. Performance and durability of painted aluminum cars, however, is dependent on proper optimization of process conditions. As part of an extensive study of factors influencing corrosion resistance of painted aluminum, the present study deals with the influence of pretreatment and coating variables and the interaction of alloy composition with zinc phosphate and electrocoat. Interfacial analysis of corrosion products indicates the relative influence of alloying elements on stability of the metal/phosphate/electrocoat interface. As a result, guidelines and recommendations on aluminum processing in an automotive manufacturing floor have been developed.
Technical Paper

Laser Welding of Aluminum Alloy Plate, Extrusion and Casting

1996-02-01
960160
This paper studies the influence of welding parameters on the mechanical properties of butt joints, using aluminum plates, extrusion and casting by CO2 laser. As a result of this study, good welds have been obtained by optimum power output of laser and welding speed for each material. It also shows that the feeding of filler metal can improve joint efficiency and can perform tensile failure position away from weld metal and can extend the tolerance of root gap for butt joints. These technique lead to improve joint strength of laser welds as strong as that of arc welds. Also bending property and fatigue strength are equal to that of other conventional welds. This investigation confirms that laser welding for joining of aluminum alloys can be used, and that the techniques in this study will be able to be applied for automobile structures.
Technical Paper

Development of Galvanized Aluminum Alloy Sheet for Body Panels with an Excellent Filiform Corrosion Resistance

1993-03-01
930703
Filiform corrosion phenomenon and its prevention method for 5000 series aluminum alloy sheet have been investigated. The painted aluminum alloy sheets were subject significantly to filiform corrosion caused by formation of a mottled and coarse zinc phosphate film during chemical conversion process. On the other hand, galvanized aluminum alloy sheet showed an uniform and fine phosphate film in a brief time and the filiform corrosion resistance was improved markedly. The test results of press-forming and corrosion for the prototype engine hoods made of this newly developed galvanized sheets have revealed a good formability and an excellent filiform corrosion resistance.
Technical Paper

Static and Dynamic Structural Performance of Extruded Aluminum Reinforcing Beams for Bumpers

1993-03-01
930709
This paper reports a method to evaluate structural performance of extruded aluminum thin-walled box section beams for automobile bumper reinforcement. According to U. S. Federal safety performance requirements for automobile bumper systems, the systems should be able to bear the dynamic load of pendulum impact. To evaluate performance of the bumper system, two stages of research were executed: (1) Bending tests and analyses under quasi-static loading, and (2) Dynamic pendulum tests and their simulation using the finite element method. As a result of these investigations, the relationship between the collapse moment of the beam and the permanent set caused by pendulum test, the effect of absorbers, and the effect of torsional force are discussed.
Technical Paper

Weathering Test of Hem Model Set Inside Automotive Door

1989-12-01
892568
In order to simulate the perforation corrosion of an automobile, hem model samples made of various kinds of coated steel sheets were set inside of the door outer panel and the door was exposed in the open air with once a week 5% salt spraying. After two years, the model samples were disassembled for investigation. Perforation corrosion occurred most severely just above the lapped portion of outer and inner specimens. Red rust samples taken from the hem model and from a field vehicle run in Detroit did not show clear pearks of spectra by X-ray diffraction analysis, whearas the one formed by a conventional cyclic corrosion test showed peaks of Fe3O4. These facts indicate that this new test well simulates the corrosion environment of an actual automobile hem portion. Corrosion resistance of many kinds of coated steel sheets was studied by this new test method. Perforation depth became smaller as a coating weight of pure zinc electroplated steel sheet increased.
Technical Paper

Organic Coated Steel Sheet for Automotive Body Panel

1989-02-01
890710
A thin organic coated steel sheet (HI-SUPER-DN) has been recently developed for automotive body panel applications. The steel sheet consists of a Zn-Ni alloy-plated layer, a chromate film and a thin organic coated layer, which is composed of colloidal silica, organic polymer and an organic additive. Corrosion resistance, formability of the coated layer, weidability and electropaintability of the steel sheet required for automotive body panel were studied. An increase in the colloidal silica in the organic coated layer improves corrosion resistance. However, the formability of the organic coated layer deteriorates with such as increase in the colloidal silica. We have optimized the ratio of colloidal silica to organic polymer so as to balance both the corrosion resistance and the formability of the organic coated layer. Futhermore, the bake-hardenability of the steel sheet was maintained by a relatively low temperature baking of the chromate film and the organic coated layer.
Technical Paper

Effect of Chemical Composition on Sag Resistance of Suspension Spring

1982-02-01
820128
This paper summarizes a laboratory study aimed at revealing the effect of chemical elements. Si, Cr, Mo and V, on the sag resistance and developing new steels with all the characteristics required for suspension coil spring in comparison with AISI 9260. It was found that as far as sag resistance is concerned an optimum silicon content exist (1.5 silicon) and chromium deteriorates sag resistance and molybdenum and vanadium improve it. Further studies showed that Si-Cr-V steels are the best spring steels available, particularly 1.5Si-0.5Cr-G.2V steel has all the required characteristics, e.g., good sag resistance, good decarburizing resistance and sufficient hardenability.
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