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The effects of hydrogen ratio and exhaust gas recirculation (EGR) on combustion and emissions in a hydrogen/diesel dual-fuel premixed charge compression ignition (PCCI) engine were investigated. The control of combustion phasing could be improved using hydrogen enrichment and EGR due to the retarded combustion phasing with a higher hydrogen ratio. The indicated mean effective pressure (IMEP) was increased with a higher hydrogen ratio because the hydrogen enrichment intensified the high temperature reactions and thus decreased the combustion duration. Hydrocarbon (HC) and carbon monoxide (CO) emissions were reduced significantly in a hydrogen/diesel dual-fuel PCCI mode with a similar NOx emissions level as that of the diesel PCCI mode.