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With the continuing improvements to thermoelectric (TE) materials and systems, their potential for both energy recovery and thermal management is increasingly apparent. Recent developments in materials and notably Skutterudites have allowed materials to be matched much more closely to the working temperatures of a light duty power-train. The choice of TE materials remains a substantial question in the design of a thermoelectric generator (TEG). While the quest for improvements in materials performance continues, the work reported in this paper is characterized by the decision to focus on the refinement of one class of TE materials: Skutterudites. In parallel, the engineering work on the integration of the TE materials into a heat exchanger could continue and be focused on the properties of this class of material. Skutterudites offer the combination of a high working temperature and a competitive electrical output (defined by ZT, the figure of merit).

Recent work on thermo-electric (TE) systems has highlighted the need for refined heat transfer design as well as the long standing need for improved materials performance. Recent work on heat transfer for TE systems has shown that enhanced heat transfer is needed over and above what would normally be seen in a vehicle exhaust system. In particular a better understanding of flow development and boundary layer behaviour is needed to support new design proposals. In the meantime, recent work in TE materials suggests that with the use of skutterudites significant performance benefits can accrue over existing materials. The current generation of TE materials have non-dimensional thermoelectric figure of merit (ZT) values of around 1. Skutterudites have been demonstrated to have ZT values of about 1.4 and can maintain these values over a wider temperature range than do existing materials through the engineering of the TE device.