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The natural gas/diesel dual-fuel engine is an interesting technique to reduce greenhouse gas emission. A limitation of this concept is the emission of un-combusted methane. In this study we analyzed the influence of PFI gas-injection timing on cylinder to cylinder gas-distribution, and the resulting methane emissions. This was done on a 6 cylinder HD engine test bench and in a GT-power simulation of the same engine. The main variable in all tests was the timing of the intake port gas injection, placed either before, after, or during the intake stroke. It showed that injecting outside of the intake window resulted in significant variation of the amount of trapped gaseous fuel over the 6 cylinders, having a strong impact on methane emissions. Injecting outside of the intake stroke results in gas awaiting in the intake port. Both testing and simulation made clear that as a result of this, cylinder 1 leans out and cylinder 6 enriches.