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Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine.

Autoignition delay times of two full blend gasoline fuels (high and low RON) were explored in a rapid compression machine. CO2 dilution by mass was introduced at 0%, 15%, and 30% levels with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy is used to represent exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines by using CO2 as a surrogate for major EGR constituents(N2, CO2, H2O). Experiments were conducted over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. The full blend fuels were admitted directly into the combustion chamber for mixture preparation using the direct test chamber (DTC) approach. CO2 addition retarded the autoignition times for the fuels studied here. The retarding effect of the CO2 dilution was more pronounced in the NTC region when compared to the lower and higher temperature range.

Rapid Compression Machines (RCM) offer the ability to easily change the compression ratio and the pressure/mixture composition/temperature to gather ignition delay data at various engine relevant conditions. Therefore, RCMs with optical access to the combustion chamber can provide an effective way to analyze macroscopic spray characteristics needed to understand the spray injection process and for spray model development, validation and calibration at conditions that are suitable for engines. Fuel surrogates can help control fuel parameters, develop models for spray and combustion, and perform laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of multicomponent gasoline surrogates in comparison to their gasoline counterparts, under gasoline direct injection (GDI) engine conditions.

In this work autoignition delay times of two multi-component surrogates (high and low RON) were experimentally compared with their target full blend gasoline fuels. The study was conducted in a rapid compression machine (RCM) test facility and a direct test chamber (DTC) charge preparation approach was used for mixture preparation. Experiments were carried over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. Dilution in the reactant mixture was varied from 0% to 30% CO2 (by mass), with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy emulates exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. The multicomponent surrogate captured the reactivity trends of the gasoline-air mixtures reasonably well in comparison to the single component (iso-octane) surrogate.

Previous studies have shown that several facility dependent factors can influence ignition delay times measured in a rapid compression machine. Compression ratio variation represents one such aspect of many facility-to facility differences in RCMs, and can have a major impact on measured ignition delay times due to changes in surface-area-to-volume ratio, initial conditions and compression duration even when the same compressed conditions are maintained. In this study, iso-octane, which exhibits two stage ignition delay and has a pronounced negative temperature coefficient (NTC) region, is used to investigate the effects of changing compression ratio on ignition delay. Resulting trends are also compared to previous results obtained with ethanol, which has very different combustion properties. Experiments were carried out for rich mixtures (ϕ = 1.3) of iso-octane and air over a compressed temperature range of 675-900 K at 20 bar compressed pressure.

Ignition delay, using a rapid compression machine (RCM), is defined as the time period between the end of compression and the maximum rate of pressure rise due to combustion, at a given compressed condition of temperature and pressure. The same compressed conditions can be reached by a variety of combinations of compression ratio, initial temperature, initial pressure, diluent gas composition, etc. It has been assumed that the value of ignition delay, for a given fuel and at a given set of compressed conditions, would be the same, irrespective of the variety of the above-mentioned combinations that were used to achieve the compressed conditions. In this study, a range of initial conditions and compression ratios are studied to determine their effect on ignition delay time and to show how ignition delay time can differ even at the same compressed conditions.

Iso-Octane (2,2,4-trimethlypentane) is an important gasoline primary reference fuel (PRF) surrogate. Auto ignition of iso-octane was examined using a rapid compression machine (RCM) with iso-octane, air and carbon dioxide (CO2) mixtures. Experiments were conducted over a temperature range of 650K-900K at 20bar and 10 bar compressed conditions for equivalence ratios (Φ =) 0.6, 0.8, 1.0 and 1.3. CO2 dilution by mass was introduced at 0%, 15% and 30% levels with the O2:N2 mole ratio fixed at 1:3.76 emulating the exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. In this study the direct test chamber (DTC) approach is used for introducing iso-octane directly into the RCM test chamber via a direct injector. The results using this approach are compared with other RCM data available in the literature at undiluted Φ = 1.0 and 20 bar compressed pressure and show good agreement.