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Exergy or availability is the potential of a system to do work. In this paper, an innovative exergy-based control approach is presented for Internal Combustion Engines (ICEs). An exergy model is developed for a Homogeneous Charge Compression Ignition (HCCI) engine. The exergy model is based on quantification of the Second Law of Thermodynamic (SLT) and irreversibilities which are not identified in commonly used First Law of Thermodynamics (FLT) analysis. An experimental data set for 175 different ICE operating conditions is used to construct the SLT efficiency maps. Depending on the application, two different SLT efficiency maps are generated including the applications in which work is the desired output, and the applications where Combined Power and Exhaust Exergy (CPEX) is the desired output. The sources of irreversibility and exergy loss are identified for a single cylinder Ricardo HCCI engine.

Precise cycle-to-cycle control of combustion is the major challenge to reduce fuel consumption in Homogenous Charge Compression Ignition (HCCI) engines, while maintaining low emission levels. This paper outlines a framework for simultaneous control of HCCI combustion phasing and Indicated Mean Effective Pressure (IMEP) on a cycle-to-cycle basis. A dynamic control model is extended to predict behavior of HCCI engine by capturing main physical processes through an HCCI engine cycle. Performance of the model is validated by comparison with the experimental data from a single cylinder Ricardo engine. For 60 different steady state and transient HCCI conditions, the model predicts the combustion phasing and IMEP with average errors less than 1.4 CAD and 0.2 bar respectively. A two-input two-output controller is designed to control combustion phasing and IMEP by adjusting fuel equivalence ratio and blending ratio of two Primary Reference Fuels (PRFs).