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High fidelity engine simulation requires realistic fuel models. Although typical automotive fuels consist of more than few hundreds of hydrocarbon species, researches show that the physical and chemical properties of the real fuels could be represented by appropriate surrogate fuel models. It is desirable to represent the fuel using the same set of physical and chemical surrogate components. However, when the reaction mechanisms for a certain physical surrogate component is not available, the chemistry of the unmatched physical component is described using that of a similar chemical surrogate component at the expense of accuracy. In order to reduce the prediction error while maintaining the computational efficiency, a method of on-the-fly reactivity adjustment (ReAd) of chemical reaction mechanism along with fuel re-distribution based on reactivity is presented and tested in this study.

Knock in a Rotax-914 engine was modeled and investigated using an improved version of the KIVA-3V code with a G-equation combustion model, together with a reduced chemical kinetics model. The ERC-PRF mechanism with 47 species and 132 reactions [1] was adopted to model the end gas auto-ignition in front of the flame front. The model was validated by a Caterpillar SI engine and a Rotax-914 engine in different operating conditions. The simulation results agree well with available experimental results. A new engineering quantified knock criterion based on chemical mechanism was then proposed. Hydroperoxyl radical (HO2) shows obvious accumulation before auto-ignition and a sudden decrease after auto-ignition. These properties are considered to be a good capability for HO2 to investigate engine knock problems.

Physical, chemical, and biological characterization data for the particulate emissions from a Caterpillar 3208 diesel engine with and without Corning porous ceramic particulate traps are presented. Measurements made at EPA modes 3,4,5,9,lO and 11 include total hydrocarbon, oxides of nitrogen and total particulate matter emissions including the solid fraction (SOL), soluble organic fraction (SOF) and sulfate fraction (SO4), Chemical character was defined by fractionation of the SOF while biological character was defined by analysis of Ames Salmonella/ microsome bioassay data. The trap produced a wide range of total particulate reduction efficiencies (0-97%) depending on the character of the particulate. The chemical character of the SOF was significantly changed through the trap as was the biological character. The mutagenic specific activity of the SOF was generally increased through the trap but this was offset by a decrease in SOF mass emissions.

The infrared radiation method of compression and end-gas temperature measurement was applied to the problem of measuring gas temperatures up to the time of knock. Pressure data were taken for each run on a CFR engine with mixtures of isooctane and n-heptane under both knocking and nonknocking conditions. Main engine parameters studied were the intake pressure, intake temperature, and engine speed. The rate and extent of chemical energy release were calculated from the temperature and pressure histories using an energy balance. The computed rates of chemical energy release were correlated to a chain-type kinetic model

The results of both theoretical and experimental studies on the self-ignition of single pure hydrocarbon drops are described. In this work single drops were subjected to air streams heated to such degrees that self-ignition of the drops would occur. Experimental heat and mass transfer parameters, as well as ignition delay data for different fuels and at different operating conditions were obtained. The experimental data were then used in conjunction with boundary layer correlations to evaluate the extent of the ignition delay that is physical (vaporization) and chemical (molecular interaction).

THE PRESENT WORK uses both the hot-motored technique and a nitrogen technique to obtain three pressure-time records — one without either vaporization or chemical reaction, one with vaporization only, and one with both vaporization and chemical reaction. By comparison of these three records, rates of vaporization and rates of chemical reaction can be determined during the ignition delay period in an operating diesel engine. Such data are shown for different fuels and operating conditions. Estimations are made of the penetration and temperatures existing in the spray.*

AN analysis of phenomena occurring during the ignition delay period is presented. Vaporization of atomized fuel is shown to take place under conditions ranging between single droplet and adiabatic saturation from edge to center of the spray. Mechanisms of vaporization and combustible mixture formation are presented for both cases. Correlation of theoretical analysis with experimental data from both a combustion bomb and diesel engine is presented to establish actual conditions existing during vaporization. Estimates of physical and chemical delays for the engine and bomb are given.

THIS paper is a sequel of the paper, “Photo-Electric Combustion Analysis,” presented at the 1936 Semi-Annual Meeting of the Society. The indicator described in that paper has been used to study combustion of 28 fuels and chemicals. A complete table of information of the materials used as fuels is included. The results obtained from over 1000 oscillograms show a different shape of ignition-lag curve versus injection advance angle than it is ordinarily thought to have. Even though the cetane values for these 28 fuels varied from 24 to 100, they all had nearly the same ignition lag when injected near the dead-center position. This minimum value is shown to be about 1/1000 sec. The fuels of higher-cetane value reach this minimum at an earlier injection angle than do those of low-cetane value. The paper shows how a high-cetane fuel can be just as rough as a low-cetane fuel if the injection timing is too early.