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As emissions regulations become stricter, a variety of advanced combustion concepts that can reduce emissions with a higher thermal efficiency have been suggested. Dual-fuel combustion is one of the alternatives that has both premixed and non-premixed combustion characteristics. Knowing the effects of the mixture formation in dual-fuel combustion is important because it determines the ignition location and the following combustion phase. Hence, a thorough investigation on the related factors, such as the engine hardware or fuel spray, is required. Meanwhile, Computational Fluid Dynamics (CFD) is a good technique to visualize the in-cylinder phenomena and enables quantitative investigations into the detailed combustion characteristics. In this paper, a 3-dimensional CFD simulation was used to investigate the effects of the mixture formation in dual-fuel combustion. The combustion model consists of two parts.