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Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

Southwest Research Institute (SwRI) has successfully demonstrated the cooled EGR concept via the High Efficiency Dilute Gasoline Engine (HEDGE) consortium. Dilution of intake charge provides three significant benefits - (1) Better Cycle Efficiency (2) Knock Resistance and (3) Lower NOx/PM Emissions. But EGR dilution also poses challenges in terms of combustion stability, condensation and power density. The Dedicated EGR (D-EGR) concept brings back some of the stability lost due to EGR dilution by introducing reformates such as CO and H2 into the intake charge. Control of air, EGR, fuel, and ignition remains a challenge to realizing the aforementioned benefits without sacrificing performance and drivability. This paper addresses the DEGR solution from a controls standpoint. SwRI has been developing a unified framework for controlling a generic combustion engine (gasoline, diesel, dual-fuel natural gas etc.).

The presented work describes how spark calorimeter testing was used for parametric study and secondary circuit model calibration. Tests were conducted at different pressures, sparkplug gaps and supplied primary energies. The conversion efficiency increases and the spark duration decreases when the gas pressure or the sparkplug gap size is increased. Both gas pressure and sparkplug gas size increase the positive column voltage which represents part of the electrical energy delivered to the gas. The opposite direction occurs when the supplied primary energy is increased. The testing results were then used to calibrate the secondary circuit model which consisted of the sparkplug, the sparkplug gap and the secondary wiring. A step-by-step method was used to calibrate the three constants of the model to match the calculated delivered energy with test data during arc / glow phase.

Enhancement of fuel/air mixing is one path towards enabling future diesel engines to increase efficiency and control emissions. Air-assist fuel injections have shown potential for low pressure applications and the current work aims to extend air-assist feasibility understanding to high pressure environments. Analyses were completed and carried out for traditional high pressure fuel-only, internal air-assist, and external air-assist fuel/air mixing processes. A combination of analytical 0-D theory and 3D CFD were used to help understand the processes and guide the design of the air-assisted setup. The internal air-assisted setup was determined to have excellent liquid fuel vaporization, but poorer fuel dispersion than the traditional high-pressure fuel injections.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.

Total and solid particle mass, size, and number were measured in the dilute exhaust of a 2009 vehicle equipped with a gasoline direct injection engine along with an exhaust three-way-catalyst. The measurements were performed over the FTP-75 and the US06 drive cycles using three different U.S. commercially available fuels, Fuels A, B, and C, where Fuel B was the most volatile and Fuel C was the least volatile with higher fractions of low vapor pressure hydrocarbons (C10 to C12), compared to the other two fuels. Substantial differences in particle mass and number emission levels were observed among the different fuels tested. The more volatile gasoline fuel, Fuel B, resulted in the lowest total (solid plus volatile) and solid particle mass and number emissions. This fuel resulted in a 62 percent reduction in solid particle number and an 88 percent reduction in soot mass during the highest emitting cold-start phase, Phasel, of the FTP-75, compared to Fuel C.

In-cylinder emission controls were the focus for diesel engines for many decades before the emergence of diesel aftertreatment. Even with modern aftertreatment, control of in-cylinder processes remains a key issue for developing diesel vehicles with low tailpipe emissions. A reduction in in-cylinder emissions makes aftertreatment more effective at lower cost with superior fuel economy. This paper describes a study focused on an in-cylinder combustion control approach using a Delphi E3 flexible fuel system to achieve low engine-out NOx and PM emissions. A 2003 model year Detroit Diesel Corporation Series 60 14L heady-duty diesel engine, modified to accept the Delphi E3 unit injectors, and ultra low sulfur fuel were used throughout this study. The process of achieving premixed low temperature combustion within the limited range of parameters of the stock ECU was investigated.

A gasoline direct injection engine was operated at elevated EGR levels over a significant portion of the performance map. The engine was modified to use both cooled and un-cooled EGR in high pressure loop and low pressure loop configurations. The addition of EGR at low and part load was shown to decrease NO and CO emissions and to reduce fuel consumption by up to 4%, primarily through the reduction in pumping losses. At high loads, the addition of EGR resulted in higher fuel consumption benefits of 10-20% as well as the expected NO and CO reductions. The fuel economy benefit at high loads resulted from a decrease in knock tendency and a subsequent improvement in combustion phasing as well as reductions in exhaust temperatures that eliminated the requirement for over-fuelling.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

A fire exposure test was conducted on a 72.4 liter composite (Type HGV-4) hydrogen fuel tank at an initial hydrogen pressure of 34.3 MPa (ca 5000 psi). No Pressure Relief Device was installed on the tank to ensure catastrophic failure for analysis. The cylinder ruptured at 35.7 MPa after a 370 kW fire exposure for 6 min 27 seconds. Blast wave pressures measured along a line perpendicular to the cylinder axis were 18% to 25% less the values calculated from ideal blast wave correlations using a blast energy of 13.4 MJ, which is based on the ideal gas internal energy at the 35.7 MPa burst pressure. The resulting hydrogen fireball maximum diameter of 7.7 m is about 19% less than the value predicted from existing correlations using the 1.64 kg hydrogen mass in the tank.

Tremendous amount of useful information can be extracted from the cylinder pressure signal for engine combustion control. However, the physical cylinder pressure sensors are undesirably expensive and their health need to be monitored for fault diagnostic purpose as well. This paper presents the results of the development of a virtual cylinder pressure sensor (VCPS) with individual variable-oriented independent estimators. Two neural network-based independent cylinder pressure related variable estimators were developed and verified at steady state. The results show that these models can predict the variables correctly compared with the extracted variables from the measured physical cylinder pressure sensor signal. Good generalization capabilities of the developed models are observed in the sense that the models work well not only for the training data set but also for the new inputs that they have never been exposed to before.

This paper describes the design and functionality of an in-situ air entrainment measuring device for analysis of the air entrainment and air release properties of lubricating fluids. The apparatus allows for a variety of measurement techniques for the aeration and deaeration of the lubricating fluid at various temperatures, pressures, and agitation speeds. This test apparatus is patent pending because of its unique ability to allow for continuous, in-situ measurement of the fluid properties and the rates of change of these properties. Most other measurement techniques and apparatuses do not allow for uninterrupted measurement. This apparatus is also unique in that it is capable of detecting minor fluid density changes at a lower level and with more accuracy than all other current techniques or apparatuses.

A technique was developed for measuring the Laminar Burning Velocity (LBV) of multi-component fuel blends for use in high-performance spark-ignition engines. This technique involves the use of a centrally-ignited spherical combustion chamber, and a complementary analysis code. The technique was validated by examining several single-component fuels, and the computational procedure was extended to handle multi-component fuels without requiring detailed knowledge of their chemical composition. Experiments performed on an instrumented high-speed engine showed good agreement between the observed heat-release rates of the fuels and their predicted ranking based on the measured LBV parameters.

Particle size distribution and number concentration were measured in the dilute exhaust of a heavy-duty diesel engine for steady-state and transient engine operation using two different dilution systems that included a full flow CVS that was coupled to an ejector pump (CVS-EP), and a double-ejector micro-dilution tunnel (DEMDT) that was connected to engine exhaust close to turbocharger outlet. Measurements were performed using a scanning mobility particle sizer (SMPS), an electrical low pressure impactor (ELPI), and a parallel flow diffusion battery (PFDB). Fuels with sulfur content of about 385 ppm and 1 ppm were used for this work. The PFDB performed well in measuring nanoparticles in the size range below 56 nm when compared with the SMPS. This was especially valid when a distinct log-normal size distribution in the size range below 56 nm in diameter, the upper size limit of the PFDB, was present.

It has been shown within the catalyst industry that the emission performance with higher cell density technology and therefore with higher specific geometric area is improved. The focus of this study was to compare the overall performance of high cell density catalysts, up to 1600cpsi, using a MY 2001 production vehicle with a 4.7ltr.V8 engine. The substrates were configured to be on the edge of the design capability. The goal was to develop cost optimized systems with similar emission and back pressure performance, which meet physical and production requirements. This paper will present the results of a preliminary computer simulation study and the final emission testing of a production vehicle. For the pre-evaluation a numerical simulation model was used to compare the light-off performance of different substrate designs in the cold start portion of the FTP test cycle.

The effect of low temperature intake air on the knock limited brake mean effective pressure (BMEP) in a spark ignited natural gas engine is described in this paper. This work was conducted to demonstrate the feasibility of using the vaporization of liquefied natural gas (LNG) to reduce the intake air temperature of engines operating on LNG fuel. The effect on steady-state emissions and transient response are also reported. Three different intake air temperatures were tested and evaluated as to their impact upon engine performance and gaseous emissions output. The results of these tests are as follows. The reduced intake air temperature allowed for a 30.7% (501 kPa) increase in the knock-limited BMEP (comparing the 10°C (50°F) intake air results with the 54.4°C (130°F) results). Exhaust emissions were recorded at constant BMEP for varying intake air temperatures.

The overall program objectives were three fold: assess the benefits and limitations of oxygenated diesel fuels on engine performance and emissions identify oxygenates most suitable for potential use in future diesel formulations based on physico-chemical properties (e.g. flash point), toxicity, biodegradability and estimated cost of production perform limited emissions and performance testing of the oxygenated diesel blends select at least two oxygenated compounds for advanced engine testing In Part 1 of this program which is described in this paper, an extensive literature review was conducted to identify potential oxygenates for blending into diesel fuels. As many as 71 oxygenates were identified for the initial screening process. Based on a set of physical and chemical properties, a screening methodology was developed to select the 8 oxygenates that will be eligible for engine testing.

While standardized laboratory-scale wear tests are available to predict the lubricity of liquid fuels under ambient conditions, the reality is that many injection systems operate at elevated temperatures where fuel vaporization is too excessive to perform the measure satisfactorily. The present paper describes a High Pressure High Frequency Reciprocating Rig (HPHFRR) purposely designed to evaluate fuel lubricity in a pressurized environment at temperatures of up to 300°C. The remaining test parameters are identical to those of the widely standardized High Frequency Reciprocating Rig (HFRR). Results obtained using the HPHFRR indicate that wear rate with poor lubricity fuels is strongly sensitive to both temperature and oxygen partial pressure and may be orders of magnitude higher than at ambient conditions. Surprisingly however, wear rate was found to decrease dramatically at temperatures above 100°C, possibly due to evaporation of dissolved moisture.