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Technical Paper

Low NOx Emissions Performance after 800,000 Miles Aging Using CDA and an Electric Heater

2024-07-02
2024-01-3011
Engine and aftertreatment solutions have been identified to meet the upcoming ultra-low NOX regulations on heavy duty vehicles in the United States and Europe. These standards will require changes to current conventional aftertreatment systems for dealing with low exhaust temperature scenarios while increasing the useful life of the engine and aftertreatment system. Previous studies have shown feasibility of meeting the US EPA and California Air Resource Board (CARB) requirements. This work includes a 15L diesel engine equipped with cylinder deactivation (CDA) and an aftertreatment system that was fully DAAAC aged to 800,000 miles. The aftertreatment system includes an e-heater (electric heater), light-off Selective Catalytic Reduction (LO-SCR) followed by a primary aftertreatment system containing a DPF and SCR.
Technical Paper

Development of a Hybrid-Electric Medium-HD Demonstrator Vehicle with a Pent-Roof SI Natural Gas Engine

2024-06-12
2024-37-0026
In response to global climate change, there is a widespread push to reduce carbon emissions in the transportation sector. For the difficult to decarbonize heavy-duty (HD) vehicle sector, lower carbon intensity fuels can offer a low-cost, near-term solution for CO2 reduction. The use of natural gas can provide such an alternative for HD vehicles while the increasing availability of renewable natural gas affords the opportunity for much deeper reductions in net-CO2 emissions. With this in consideration, the US National Renewable Energy Laboratory launched the Natural Gas Vehicle Research and Development Project to stimulate advancements in technology and availability of natural gas vehicles. As part of this program, Southwest Research Institute developed a hybrid-electric medium-HD vehicle (class 6) to demonstrate a substantial CO2 reduction over the baseline diesel vehicle and ultra-low NOx emissions.
Technical Paper

Engine-out Gaseous Emissions in a Diesel Engine using Methanol as a Low-carbon Fuel under Dual-fuel Operation

2024-04-09
2024-01-2364
In this study, engine-out gaseous emissions are reviewed using the Fourier Transform Infrared (FTIR) spectroscopy measurement of methanol diesel dual fuel combustion experiments performed in a heavy-duty diesel engine. Comparison to the baseline diesel-only condition shows that methanol-diesel dual fuel combustion leads to higher regulated carbon monoxide (CO) emissions and unburned hydrocarbons (UHC). However, NOX emissions were reduced effectively with increasing methanol substitution rate (MSR). Under dual-fuel operation with methanol, emissions of nitrogen oxides (NOX), including nitric oxide (NO), nitrogen dioxide (NO2), and nitrous oxide (N2O), indicate the potential to reduce the burden of NOX on diesel after-treatment devices such as selective catalytic reduction (SCR).
Technical Paper

Diesel Oxidation Catalyst Performance with Biodiesel Formulations

2024-04-09
2024-01-2711
Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC.
Technical Paper

Further Advances in Demonstration of a Heavy-Duty Low NOX System for 2027 and Beyond

2024-04-09
2024-01-2129
Multiple areas in the U.S. continue to struggle with achieving National Ambient Air Quality Standards for ozone. These continued issues highlight the need for further reductions in NOX emission standards in multiple industry sectors, with heavy-duty on-highway engines being one of the most important areas to be addressed. Starting in 2014, CARB initiated a series of technical demonstration programs aimed at examining the feasibility of achieving up to a 90% reduction in tailpipe NOX, while at the same time maintaining a path towards GHG reductions that will be required as part of the Heavy-Duty Phase 2 GHG program. These programs culminated in the Stage 3 Low NOX program, which demonstrated low NOX emissions while maintaining GHG emissions at levels comparable to the baseline engine.
Technical Paper

CARB Off-Road Low NOx Demonstration Program - Engine Calibration and Initial Test Results

2024-04-09
2024-01-2130
Off-road diesel engines remain one of the most significant contributors to the overall oxides of nitrogen (NOX) inventory and the California Air Resources Board (CARB) has indicated that reductions of up to 90% from current standards may be necessary to achieve its air quality goals. In recognition of this, CARB has funded a program aimed at demonstrating emission control technologies for off-road engines. This program builds on previous efforts to demonstrate Low NOX technologies for on-road engines. The objective was to demonstrate technologies to reduce tailpipe NOX and particulate matter (PM) emissions by 90 and 75%, respectively, from the current Tier 4 Final standards. In addition, the emission reductions were to be achieved while also demonstrating a 5 to 8.6% carbon dioxide (CO2) reduction and remaining Greenhouse Gas (GHG) neutral with respect to nitrous oxide (N2O) and methane (CH4).
Technical Paper

High-Load Engine Simulation of Renewable Diesel Fuel Using A Reduced Mechanism

2023-10-31
2023-01-1620
According to the Annual Energy Outlook 2022 (AEO2022) report, almost 30% of the transport sector will still use internal combustion engines (ICE) until 2050. The transportation sector has been actively seeking different methods to reduce the CO2 emissions footprint of fossil fuels. The use of lower carbon-intensity fuels such as Renewable Diesel (RD) can enable a pathway to decarbonize the transport industry. This suggests the need for experimental or advanced numerical studies of RD to gain an understanding of its combustion and emissions performance. This work presents a numerical modeling approach to study the combustion and emissions of RD. The numerical model utilized the development of a reduced chemical kinetic mechanism for RD’s fuel chemistry. The final reduced mechanism for RD consists of 139 species and 721 reactions, which significantly shortened the computational time from using the detailed mechanism.
Technical Paper

Improved Combustion Efficiency in Methanol/Renewable Diesel Dual Fuel Combustion by Advanced Injection Timing and Increased Intake Temperature: Single-Cylinder Experiment

2023-10-31
2023-01-1641
Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.
Technical Paper

Evaluating the Impact of Oil Viscoelasticity on Bearing Friction

2023-10-31
2023-01-1648
In this work, a novel bearing test rig was used to evaluate the impact of oil viscoelasticity on friction torque and oil film thickness in a hydrodynamic journal bearing. The test rig used an electric motor to rotate a test journal, while a hydraulic actuator applied radial load to the connecting rod bearing. Lubrication of the journal bearing was accomplished via a series of axial and radial drillings in the test shaft and journal, replicating oil delivery in a conventional engine crankshaft. Journal bearing inserts from a commercial, medium duty diesel engine (Cummins ISB) were used. Oil film thickness was measured using high precision eddy current sensors. Oil film thickness measurements were taken at two locations, allowing for calculation of minimum oil film thickness. A high-precision, in-line torque meter was used to measure friction torque. Four test oils were prepared and evaluated.
Technical Paper

Comparison on Combustion and Emissions Performance of Biodiesel and Diesel in a Heavy-duty Diesel Engine: NOX, Particulate Matter, and Particle Size Distribution

2023-09-29
2023-32-0100
Low carbon emissions policies for the transportation sector have recently driven more interest in using low net-carbon fuels, including biodiesel. An internal combustion engine (ICE) can operate effectively using biodiesel while achieving lower engine-out emissions, such as soot, mostly thanks to oxygenate content in biodiesel. This study selected a heavy-duty (HD) single-cylinder engine (SCE) platform to test biodiesel fuel blends with 20% and 100% biodiesel content by volume, referred to as B20, and B100. Test conditions include a parametric study of exhaust gas recirculating (EGR), and the start of injection (SOI) performed at low and high engine load operating points. In-cylinder pressure and engine-out emissions (NOX and soot) measurements were collected to compare diesel and biodiesel fuels.
Technical Paper

Numerical Study of Dual Fuel Methanol/Diesel Combustion under Engine-like Condition

2023-09-29
2023-32-0121
Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part I: Accelerated Ash Loading and DPF Performance Evaluation

2023-04-11
2023-01-0297
The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part II: Chemical and Microscopic Characterization of Aged DPFs

2023-04-11
2023-01-0296
This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.
Technical Paper

Engine and Emissions Performance of Renewable Diesel in a Heavy-Duty Diesel Engine: A Single-cylinder Engine Experiment

2023-04-11
2023-01-0273
As an alternative fuel, renewable diesel (RD) could improve the performance of conventional internal combustion engines (ICE) because of its difference in fuel properties. With almost no aromatic content in the fuel, RD produces less soot emissions than diesel. The higher cetane number (CN) of RD also promotes ignition of the fuel, which is critical, especially under low load, and low reactivity conditions. This study tested RD fuel in a heavy-duty single-cylinder engine (SCE) under compression-ignition (CI) operation. Test condition includes low and high load points with change in exhaust gas recirculation (EGR) and start of injection (SOI). Measurements and analysis are provided to study combustion and emissions, including particulate matters (PM) mass and particle number (PN). It was found that while the combustion of RD and diesel are very similar, PM and PN emissions of RD were reduced substantially compared to diesel.
Journal Article

Impact of Hydrothermal and Chemical Aging on SCR Storage Characteristics and NOx Reduction Performance in an Ultra-Low NOx System

2023-04-11
2023-01-0360
This work is a part of medium-duty Low NOx technology development project with a focus on evaluating a combination of engine and advanced aftertreatment for 0.02 g/bhp-hr NOx regulation proposed by CARB (California air resource board). In this project, a control oriented chemical kinetics model of SCR (Selective catalytic reduction) was used in the aftertreatment controller that is susceptible to performance degradation due to hydrothermal and chemical aging. This paper focuses on modeling the NOx conversion and NH3 storage characteristics using a controls oriented SCR plant model which is further used for a model-based urea dosing scheme. A set of steady state reactor tests were used to calibrate the SCR performance at degreened, hydrothermal only and hydrothermal + chemical aging conditions and also to determine inhibition factors related to aging. The resultant model is capable of simulating SCR performance deterioration such as a reduction in NOx conversion and NH3 storage.
Technical Paper

An Update on Continuing Progress Towards Heavy-Duty Low NOX and CO2 in 2027 and Beyond

2023-04-11
2023-01-0357
Despite considerable progress towards clean air in previous decades, parts of the United States continue to struggle with the challenge of meeting the ambient air quality targets for smog-forming ozone mandated by the U.S. EPA, with some of the most significant challenges being seen in California. These continuing issues have highlighted the need for further reductions in emissions of NOX, which is a precursor for ozone formation, from a number of key sectors including the commercial vehicle sector. In response, the California Air Resources Board (CARB) embarked on a regulatory effort culminating in the adoption of the California Heavy-Duty Low NOX Omnibus regulation.[1] This regulatory effort was supported by a series of technical programs conducted at Southwest Research Institute (SwRI).
Journal Article

Low Ambient Temperature Impact on a Low NOX Demonstration System

2023-04-11
2023-01-0361
In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.
Journal Article

Technology Levers for Meeting 2027 NOx and CO2 Regulations

2023-04-11
2023-01-0354
Commercial vehicles require fast aftertreatment heat-up to move the SCR catalyst into the most efficient temperature range to meet upcoming NOX regulations while minimizing CO2. The focus of this paper is to identify the technology levers when used independently and also together for the purpose of NOX and CO2 reduction toward achieving 2027 emissions levels while remaining CO2 neutral or better. A series of independent levers including cylinder deactivation, LO-SCR, electric aftertreatment heating and fuel burner technologies were explored. All fell short for meeting the 2027 CARB transient emission targets when used independently. However, the combinations of two of these levers were shown to approach the goal of transient emissions with one configuration meeting the requirement. Finally, the combination of three independent levers were shown to achieve 40% margin for meeting 2027 transient NOx emissions while remaining CO2 neutral.
Journal Article

Impact of Second NH3 Storage Site on SCR NO x Conversion in an Ultra-Low NO x Aftertreatment System

2023-04-11
2023-01-0367
Typical two-site storage-based SCR plant models in literature consider NH3 stored in the first site to participate in NH3 storage, NOx conversion and second site to only participate in NH3 storage passively. This paper focuses on quantifying the impact of stored NH3 in the second site on the overall NOx conversion for an ultra-low NOx system due to intra site NH3 mass transfer. Accounting for this intra site mass transfer leads to better prediction of SCR out NH3 thus ensuring compliance with NH3 coverage targets and improved dosing characteristics of the controller that is critical to achieving ultra-low NOx standard. The stored NH3 in the second site undergoes mass transfer to the first site during temperature ramps encountered in a transient cycle that leads to increased NOx conversion in conditions where the dosing is switched off. The resultant NH3 coverage fraction prediction is critical in dosing control of SCR.
Technical Paper

The DAAAC Protocol: A Procedure for Developing Accelerated Aging Cycles for Diesel Aftertreatment

2022-08-30
2022-01-1017
Accelerated aging of automotive gasoline emissions catalysts has been performed on bench engines for decades. The EPA regulations include an accelerated aging cycle called the Standard Bench Cycle (SBC) that is modeled on the RAT-A cycle developed by GM Corp. and published in 1988. However, this cycle cannot be used for diesel aftertreatment components because it is based on stoichiometric operation, whereas diesel engines typically operate under excess air (lean) conditions. The need for accelerated aging cycles for diesel emissions systems can be illustrated by considering that the full useful life (FUL) requirement in the United States for an on-highway truck is 435,000 miles, and an off-road application may be 8,000 hours. With the recent CARB Omibus legislation, the durability duration will be increasing for on-road applications by as much as 80 percent in the next decade.
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