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Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.

Low carbon emissions policies for the transportation sector have recently driven more interest in using low net-carbon fuels, including biodiesel. An internal combustion engine (ICE) can operate effectively using biodiesel while achieving lower engine-out emissions, such as soot, mostly thanks to oxygenate content in biodiesel. This study selected a heavy-duty (HD) single-cylinder engine (SCE) platform to test biodiesel fuel blends with 20% and 100% biodiesel content by volume, referred to as B20, and B100. Test conditions include a parametric study of exhaust gas recirculating (EGR), and the start of injection (SOI) performed at low and high engine load operating points. In-cylinder pressure and engine-out emissions (NOX and soot) measurements were collected to compare diesel and biodiesel fuels.

Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.

As an alternative fuel, renewable diesel (RD) could improve the performance of conventional internal combustion engines (ICE) because of its difference in fuel properties. With almost no aromatic content in the fuel, RD produces less soot emissions than diesel. The higher cetane number (CN) of RD also promotes ignition of the fuel, which is critical, especially under low load, and low reactivity conditions. This study tested RD fuel in a heavy-duty single-cylinder engine (SCE) under compression-ignition (CI) operation. Test condition includes low and high load points with change in exhaust gas recirculation (EGR) and start of injection (SOI). Measurements and analysis are provided to study combustion and emissions, including particulate matters (PM) mass and particle number (PN). It was found that while the combustion of RD and diesel are very similar, PM and PN emissions of RD were reduced substantially compared to diesel.

Increased in-cylinder hydrogen levels have been shown to improve burn durations, combustion stability, HC emissions and knock resistance which can directly translate into enhanced engine efficiency. External fuel reformation can also be used to increase the hydrogen yield. During the High-Efficiency, Dilute Gasoline Engine (HEDGE) consortium at Southwest Research Institute (SwRI), the potential of increased hydrogen production in a dedicated-exhaust gas recirculation (D-EGR) engine was evaluated exploiting the water gas shift (WGS) and steam reformation (SR) reactions. It was found that neither approach could produce sustained hydrogen enrichment in a real exhaust environment, even while utilizing a lean-rich switching regeneration strategy. Platinum group metal (PGM) and Ni WGS catalysts were tested with a focus on hydrogen production and catalyst durability.

Many studies on low speed pre-ignition have been published to investigate the impact of fuel properties and of lubricant properties. Fuels with high aromatic content or higher distillation temperatures have been shown to increase LSPI activity. The results have also shown that oil additives such as calcium sulfonate tend to increase the occurrence of LSPI while others such as magnesium sulfonate tend to decrease the occurrence. Very few studies have varied the fuel and oil properties at the same time. This approach is useful in isolating only the impact of the oil or the fuel, but both fluids impact the LSPI behavior of the engine simultaneously. To understand how the lubricant and fuel impacts on LSPI interact, a series of LSPI tests were performed with a matrix which combined fuels and lubricants with a range of LSPI activity. This study was intended to determine if a low activity lubricant could suppress the increased LSPI from a high activity fuel, and vice versa.

The influence of nozzle geometry on spray and combustion of diesel continues to be a topic of great research interest. One area of promise, injector nozzles with micro-holes (i.e. down to 30 μm), still need further investigation. Reduction of nozzle orifice diameter and increased fuel injection pressure typically promotes air entrainment near-nozzle during start of injection. This leads to better premixing and consequently leaner combustion, hence lowering the formation of soot. Advances in numerical simulation have made it possible to study the effect of different nozzle diameters on the spray and combustion in great detail. In this study, a baseline model was developed for investigating the spray and combustion of diesel fuel at the Spray A condition (nozzle diameter of 90 μm) from the Engine Combustion Network (ECN) community.

Recently conducted work has been funded by the California Air Resources Board (CARB) to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions for heavy-duty on-road engines. In addition to NOX emissions, greenhouse gas (GHG), CO2 and methane emissions regulations from heavy-duty engines are also becoming more stringent. To achieve low cold-start NOX and methane emissions, the exhaust aftertreatment must be brought up to temperature quickly while keeping proper air-fuel ratio control; however, a balance between catalyst light-off and fuel penalty must be addressed to meet future CO2 emissions regulations. This paper details the work executed to improve catalyst light-off for a natural gas engine with a close-coupled and an underfloor three-way-catalyst while meeting an FTP NOX emission target of 0.02 g/bhp-hr and minimizing any fuel penalty.

To better understand real fuel effects on LSPI, a matrix was developed to vary certain chemical and physical properties of gasoline. The primary focus of the study was the impact of paraffinic, olefinic, and aromatic components upon LSPI. Secondary goals of this testing were to study the impact of ethanol content and fuel volatility as defined by the T90 temperature. The LSPI rate increased with ethanol content but was insensitive to olefin content. Additionally, increased aromatic content uniformly led to increased LSPI rates. For all blends, lower T90 temperatures resulted in decreased LSPI activity. The correlation between fuel octane (as RON or MON) suggests that octane itself does not play a role; however, the sensitivity of the fuel (RON-MON) does have some correlation with LSPI. Finally, the results of this analysis show that there is no correlation between the laminar flame speed of a fuel and the LSPI rate.

The primary focus of this investigation was to determine the hydrogen reformation, efficiency and knock mitigation benefits of methanol-fueled Dedicated EGR (D-EGR®) operation, when compared to other EGR types. A 2.0 L turbocharged port fuel injected engine was operated with internal EGR, high-pressure loop (HPL) EGR and D-EGR configurations. The internal, HPL-EGR, and D-EGR configurations were operated on neat methanol to demonstrate the relative benefit of D-EGR over other EGR types. The D-EGR configuration was also tested on high octane gasoline to highlight the differences to methanol. An additional sub-task of the work was to investigate the combustion response of these configurations. Methanol did not increase its H2 yield for a given D-EGR cylinder equivalence ratio, even though the H:C ratio of methanol is over twice typical gasoline.

It is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards of 0.20 g/bhp-hr, the National Ambient Air Quality Standards (NAAQS) requirements for ambient ozone will not be met. It is expected that further reductions in NOX emissions from the heavy-duty fleet will be required to achieve compliance with the ambient ozone requirement. To study the feasibility of further reductions, the California Air Resources Board (CARB) funded a research program to demonstrate the potential to reach 0.02 g/bhp-hr NOX emissions. This paper details the work executed to achieve this goal on the heavy-duty Federal Test Procedure (FTP) with a heavy-duty natural gas engine equipped with a three-way catalyst. A Cummins ISX-12G natural gas engine was modified and coupled with an advanced catalyst system.

The impact of additive and oil chemistry on low speed pre-ignition (LSPI) was evaluated. An additive metals matrix varied the levels of zinc dialkyldithiophosphate (ZDDP), calcium sulfonate, and molybdenum within the range of commercially available engine lubricants. A separate test matrix varied the detergent chemistry (calcium vs. magnesium), lubricant volatility, and base stock chemistry. All lubricants were evaluated on a LSPI test cycle developed by Southwest Research Institute within its Pre-Ignition Prevention Program (P3) using a GM LHU 2.0 L turbocharged GDI engine. It was observed that increasing the concentration of calcium leads to an increase in the LSPI rate. At low calcium levels, near-zero LSPI rates were observed. The addition of zinc and molybdenum additives had a negative effect on the LSPI rate; however, this was only seen at higher calcium concentrations.

In response to the sensitivity to diesel aftertreatment costs in the medium duty market, a John Deere 4045 was converted to burn gasoline with high levels of EGR. This presented some unique challenges not seen in light duty gasoline engines as the flat head and diesel adapted ports do not provide optimum in-cylinder turbulence. As the bore size increases, there is more opportunity for knock or incomplete combustion to occur. Also, the high dilution used to reduce knock slows the burn rates. In order to speed up the burn rates, various levels of swirl were investigated. A four valve head with different levels of port masking showed that increasing the swirl ratio decreased the combustion duration, but ultimately ran into high pumping work required to generate the desired swirl. A two valve head was used to overcome the breathing issue seen in the four valve head with port masking.

Dual fuel engines have shown significant potential as high efficiency powerplants. In one example, SwRI® has run a high EGR, dual-fuel engine using gasoline as the main fuel and diesel as the ignition source, achieving high thermal efficiencies with near zero NOx and smoke emissions. However, assuming a tank size that could be reasonably packaged, the diesel fuel tank would need to be refilled often due to the relatively high fraction of diesel required. To reduce the refill interval, SwRI investigated various alternative fluids as potential ignition sources. The fluids included: Ultra Low Sulfur Diesel (ULSD), Biodiesel, NORPAR (a commercially available mixture of normal paraffins: n-pentadecane (normal C15H32), and n-hexadecane (normal C16H34)) and ashless lubrication oil. Lubrication oil was considered due to its high cetane number (CN) and high viscosity, hence high ignitability.

The performance of an organic Rankine cycle (ORC) used to recover waste heat from the exhaust of a diesel and a spark ignition engine for electric power generation was modeled. The design elements of the ORC incorporated into the thermodynamic model were based on an experimental study performed at Oak Ridge National Laboratory in which a regenerative organic Rankine cycle system was designed, assembled and integrated into the exhaust of a 1.9 liter 4-cylinder automotive turbo-diesel. This engine was operated at a single fixed-load point at which Rankine cycle state point temperatures as well as the electrical power output of an electric generator coupled to a turbine that expanded R245fa refrigerant were measured. These data were used for model calibration.

Proposed emissions standards will require that emissions control systems function at extremely high efficiency. Recently, studies have shown that elevated gasoline fuel sulfur levels (GFSL) can impair catalytic converter efficiency. In this study, a variety of tri-metal catalysts were evaluated to determine if formulation changes could reduce emissions sensitivity to GFSL. Catalysts with elemental composition similar to an OEM, but with double the precious metal (PM) loading, were evaluated using 38 and 620 ppm GFSL. Doubling the PM loading significantly reduced catalyst sensitivity to sulfur. Doubling the rhodium loading, at the expense of the platinum loading, significantly improved NOx emission sulfur sensitivity.