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The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

This work concerns the modelling of soot formation process in diesel spray combustion under engine-like conditions. The key aim is to investigate the soot formation characteristics at different ambient temperatures. Prior to simulating the diesel combustion, numerical models including a revised multi-step soot model is validated by comparing to the experimental data of n-dodecane fuel in which the associated chemistry is better understood. In the diesel spray simulations, a single component n-heptane mechanism and the multi-component Diesel Oil Surrogate (DOS) model are adopted. A newly developed C16-based model which comprises skeletal mechanisms of n-hexadecane, heptamethylnonane, cyclohexane and toluene is also implemented. Comparisons of the results show that the simulated liftoff lengths are reasonably well-matched to the experimental measurement, where the relative differences are retained to below 18%.

In this reported work, 2-dimsensional computational fluid dynamics studies of n-heptane combustion and soot formation processes in the Sandia constant-volume vessel are carried out. The key interest here is to elucidate how the chemical kinetics affects the combustion and soot formation events. Numerical computation is performed using OpenFOAM and chemistry coordinate mapping (CCM) approach is used to expedite the calculation. Three n-heptane kinetic mechanisms with different chemistry sizes and comprehensiveness in oxidation pathways and soot precursor formation are adopted. The three examined chemical models use acetylene (C2H2), benzene ring (A1) and pyrene (A4) as soot precursor. They are henceforth addressed as nhepC2H2, nhepA1 and nhepA4, respectively for brevity. Here, a multistep soot model is coupled with the spray combustion solver to simulate the soot formation/oxidation processes.

This work presents the experimental investigation of Diesel Particulate Filter (DPF) regeneration and a calibration procedure of a 1D DPF simulation model based on the commercial software AVL BOOST v. 5.1. Model constants and parameters are fitted on the basis of a number of steady state DPF experiments where the DPF is exposed to real engine exhaust gas in a test bed. The DPF is a silicon carbide filter of the wall flow type without a catalytic coating. A key task concerning the DPF model calibration is to perform accurate DPF experiments because measured gas concentrations, temperatures and soot mass concentrations are used as model boundary conditions. An in-house-developed raw exhaust gas sampling technique is used to measure the soot concentration upstream the DPF which is also needed to find the DPF soot burn rate.

The described investigation was carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline.

A novel base metal-palladium catalytic coating was applied on commercial silicon carbide wall flow diesel filters and tested in an engine test bench. This catalytic coating limits the NO2 formation and even removes NO2 within a wide temperature range. Soot combustion, HC conversion and CO conversion properties are comparable to current platinum-based coatings, but at a lower cost. This paper compares the results from engine bench tests of present commercial solutions as regards NO2-, HC-, CO-removal and soot combustion with the novel coating. Furthermore, emission test results from base metal-palladium coated diesel particulate filters installed on operating taxis and related test cycle data are presented. A significant reduction in NO2 emission compared to present technology is measured.

A naturally aspirated, direct injection diesel engine was modified in order to be run on dimethyl ether (DME), with a conventional pump-line-nozzle system. The effects of various modifications to engine timing and the injection system as well as EGR were experimentally determined. Compared to the original diesel engine, the NOx emissions were reduced by over 70% through the use of suitable timing, lowered injector opening pressure and EGR. Particulate emissions were very low, and represent over a 90% reduction as compared to the original diesel version. The original pump-line-nozzle injection system was found to be not well suited to DME operation, CO and HC emissions were substantially higher due to secondary injections, caused by high pressure oscillations and residual pressure with the DME.

The paper presents a 2-dimensional model for the calculation of the regeneration process in a wall flow diesel particulate filter. The model includes heat transfer by conduction and convection, a model for particle combustion based on diffusive burning of individual particles, and flow through the channels and across the filter walls. It was found that only the pressure drop across the walls need be considered for normal regeneration conditions. Comparisons between model predictions and experimental results for spatial dependent temperature time histories, and integrated degree of regeneration are used to validate the model. The validations were carried out for a series of severe regenerations, where there are large changes in flow and temperature throughout the process. Relative magnitudes of energy flows due to combustion, convection, and conduction are presented, as well as parametric studies of the effects of temperature, oxygen concentration and soot loading.

Studies were performed with three commonly used additive metals, cerium copper, and iron, with a conventional and a low sulfur fuel in order to investigate fuel additive effects on engine particulate emissions before a particulate filter. Measurements were made on a 4 cylinder direct injection diesel engine and included total particulate mass, soluble organic fraction for both fuels, and polynuclear aromatic hydrocarbon emissions for the low sulfur fuel. The cerium based additive reduced the emissions with both fuels, with the largest effect being on the non-SOF fraction. With the other additives and the high sulfur fuel, non-SOF emissions were increased, increasing total particulate emissions. Copper was found to reduce the polynuclear aromatic hydrocarbons, and cerium was found to have the least effect. The use of an SiC wall flow filter reduced particulate and polynuclear aromatic emissions by over 90%.

The main purpose of this study was to investigate the influence of diesel engine conditions on the mutagenic activity of the exhaust. Special emphasis was put on investigation of the influence of nitrogen oxides content. Experiments with a diesel engine have been carried out in the laboratory and the emissions of carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) and particulate matter (PM) have been measured at different engine conditions. The particulate matter was extracted in order to obtain the soluble organic fraction (SOF), and this fraction was analyzed for mutagenic activity in the Salmonella/microsome assay (AMES test). It was found that the mutagenic activity evidently depended on the PAH content (PAH = Polycyclic Aromatic Hydrocarbons) of the exhaust gas rather than the NOx content. However, the percentage of the direct mutagenic activity of the total mutagenic activity increased as the NOx content in the exhaust gas increased.

Silicon Carbide (SiC) has been shown to have a high melting/decomposition temperature, good mechanical strength, and high thermal conductivity, which make it well suited for use as a material for diesel particulate filters. The high thermal conductivity of the material tends to reduce the temperature gradients and maximum temperature which arise during regeneration. The purpose of this paper is to experimentally investigate the thermal loading which arise under regenerations of varying severity. An experimental study is presented, in which regenerations of varying severity are conducted for uncoated SiC and Cordierite filters. The severity is varied through changes in the particle loading on the filters and by changing the flow conditions during the regeneration process itself. Temperature distributions throughout the filters are measured during these regeneration.

Recent studies have shown that SiC provides substantial advantages for use as the material for wall flow diesel particulate filters. In addition to very advantageous thermal properties, it has been shown that SiC based filter material has higher permeability than Cordierite. This paper presents a comparison of the basic flow characteristics of SiC based and Cordierite based wall flow filter material, expressed in terms of parameters which are basic materials properties that are independent of filter geometry. In addition, the flow characteristics of the particulate matter collected on the filter during engine operation are presented. The results show that the advantageous flow characteristics observed with the basic filter material are retained for loaded filters, up to very high loadings.

Many of the materials which have been developed for use as particle filters in the exhaust of diesel engines have characteristics which give rise to significant problems in practical use. Due to its special characteristics, it is shown that SiC is very well suited for use as the base material for particulate filters. The physical and thermal properties of porous SiC substrate material as applied to diesel particulate filters have been determined and are presented. Experimental results from several types of filter regeneration processes in exhaust gas systems confirm the improvements in the area of thermal load and reduction in temperature level during regeneration. The reduction in temperature during regeneration is shown to be consistent with the high thermal conductivity of SiC.