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A family of water-based sol-gel coatings has been developed as an environmentally-friendly alternative to traditional aerospace finishing materials and processes. The sol-gel hybrid network is based on a reactive mixture of an organo-functionalized silane with a stabilized zirconium complex. Thin films of the material self-assemble on metal surfaces, resulting in a gradient coating that provides durable adhesion for paints, adhesives, and sealants. Use of the novel coating as a surface pretreatment for the exterior of commercial aircraft has enabled environmental, health, and safety benefits due to elimination of hexavalent chromium, and flight test and early fleet survey data support the laboratory observations that the sol gel coating reduces the occurrence of “rivet rash” adhesion failures. Modifications of the basic inorganic/organic hybrid network have yielded multifunctional coatings with promise for applications such as corrosion control and oxidation protection.

This white paper will outline the material and processes, which have been developed for the fabrication and application of an integrated composite firewall primary structure for use in military and commercial aircraft. Military and commercial aircraft have requirements to protect occupants from fire. One specific fire protection requirement is to contain a (1100°C/2000°F) flame for 15 minutes. This protection on composites is usually provided by a metallic firewall attached to the composite structure. The integrated ceramic composite firewall is an improvement over existing metallic firewall technology. This technology reduces cost, part count, weight, and manufacturing complexity of composites, which require fire protection. The integrated ceramic composite firewall material and process incorporates ceramic fabric and film adhesive into one unique material.

Trace chemical contaminants produced by equipment offgassing and human metabolic processes are removed from the atmosphere of the International Space Station's U.S. Segment by a trace contaminant control subassembly (TCCS). The TCCS employs a combination of physical adsorption, thermal catalytic oxidation, and chemical adsorption processes to accomplish its task. A large bed of granular activated charcoal is a primary component of the TCCS. The charcoal contained in this bed, known as the charcoal bed assembly (CBA), is expendable and must be replaced periodically. Pre-flight engineering analyses based upon TCCS performance testing results established a service life estimate of 1 year. After nearly 1 year of cumulative in-flight operations, the first CBA was returned for refurbishment. Charcoal samples were collected and analyzed for loading to determine the best estimate for the CBA's service life.