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Technical Paper

Influence of Additive Chemistry on Manual Transmission Synchronizer Performance

2002-05-06
2002-01-1697
The lubricant is a key component in the successful operation of a manual transmission, but it is important that the interactive effects with the friction material are understood. This paper examines the effect of several key additive components on the friction and wear performance of a single sinter composition in a carefully controlled laboratory test. In addition, the test method allows one to develop information about the shift behavior of the fluid-synchronizer material combination which provides useful information about shift quality. From the original experimental design program a predictive model was developed and an optimized formulation was tested as a validation of the results.
Technical Paper

Fundamental Studies on ATF Friction, Part II

1998-10-19
982670
Interactions between automatic transmission fluid (ATF) components and composite friction materials and their effect on friction system performance continues to be an active area of interest to the automotive industry. A more fundamental understanding is needed of how base fluids, ATF additives, friction materials, and transmission design interact to produce the observed transmission system performance and durability. We herein report results from investigations carried out using a relatively thermo-oxidatively stable polyalphaolefin (PAO) base fluid treated with components representative of several additive types we previously reported to have significant negative effects on frictional performance. Secondly, we investigated a conventionally refined 150 N base oil treated with a calcium sulfonate detergent previously shown to improve friction performance.
Technical Paper

Understanding Soot Mediated Oil Thickening Through Designed Experimentation - Part 5: Knowledge Exhancement in the GM 6.5L

1997-10-01
972952
Our basic understanding of the chemical and physical nature of soot, its interaction with lubricant components and its role in promoting wear and oil thickening in heavy duty diesel engines continues to grow. Our current study in the GM 6.5L engine focuses on examining the effects of variations in base stock type (Group I vs. Group II), viscosity index improver or viscosity modifier (VM) chemistry (OCP vs. dispersant OCP), zinc dithiophosphate (ZDP) type and dispersant type (low MW vs. high MW) on roller follower wear, viscosity growth and other measured responses. In this study, more robust fluids were tested producing very low wear results and minimal viscosity increase of the lubricant. Fluids containing dispersant OCP (DOCP) and high MW dispersant produced a lower degree of wear, whereas varying the ZDP type (1° vs. 2°) showed no effect on wear. The use of Group II base stocks was associated with significantly lower viscosity increases.
Technical Paper

Formulating for ILSAC GF-2 - Part 1: Obtaining Valve Train Wear Protection While Reducing the Phosphorus Content of a Motor Oil

1995-10-01
952342
The International Lubricant Standardization and Approval Committee (ILSAC) GF-2 requirements for Passenger Car Motor Oils (PCMOs) will lower phosphorus limits from a maximum of 0.12% allowed by ILSAC GF-1 to a maximum of 0.10%. In effect, the ILSAC GF-2 phosphorus limit removes 17% of the most commonly used antiwear and antioxidant additive in current PCMOs, zinc dialkyldithiophosphate (ZDP). This paper outlines some work in ASTM Sequence V engine dynamometer tests to quantify the effect of reducing the ZDP on valve train wear and sludge formation. Engine data for the Sequence VE, the proposed Sequence VF, and the modified Sequence VE are presented. These three tests summarize the evolution of the Sequence V from the Sequence VE for GF-1 to the dual plug Sequence VE configuration for the GF-2 specification.
Technical Paper

Zinc Dialkyldithiophosphate-Dispersant Interactions: Effects on Solution Behavior and Wear

1992-10-01
922282
Interactions between a Zinc dialkyldithiophosphate (ZDP) and three different commercially available succinimide dispersants were observed through changes in solutions behavior, as determined by viscometry and Fourier Transform Infrared spectroscopy (FTIR), and four-ball tests. The viscometric response observed for two component blends of ZDP and succinimide dispersant in white oil changed as a function of the molar Zn to N ratio, indicative of specific interactions. The break in the viscometric response curve occurred at Zn:N=0.13 for all three succinimide dispersants. FTIR spectra of the same ZDP-dispersant blends were examined and similar Zn:N dependencies were observed. Four-ball tests measuring wear scar diameter, seizure load and weld load showed a dependence on the Zn to N ratio similar to that observed by viscometry. At very low Zn to N ratios wear and seizure load were decreased, while at higher ratios the seizure and weld loads were increased over that for ZDP alone.
Technical Paper

Field Test Data Analysis Techniques

1992-10-01
922201
Accurate, timely field test results are necessary to develop and validate lubricants meeting frequently changing performance requirements. Field tests can also provide valuable information about performance deficiencies (e.g., soot related wear) which are not apparent in laboratory development tests. Since field tests are time intensive and increasingly expensive, it is imperative that the data generated provide meaningful results with reasonable expenditures. The data generation and analysis process are being constantly improved according to the principles of quality management. Part of the process improvement focuses on accurate, realistic treatment of the data since more variation is typically observed in field tests than in laboratory tests. One of the most difficult analytical processes occurs with oil consumption data.
Technical Paper

Gasoline and Diesel Fuel Additives for Performance/Distribution Quality - II

1986-09-08
861179
Additives are an integral part of today's fuels. Together with carefully formulated base fuel composition, they contribute to efficiency, dependability and long life of gasoline and diesel engines. As a primer, this paper describes the range of chemical additives formulated for gasoline and diesel fuel and their effects. Specific functions and benefits of additives, typical use levels, and test methods for evaluation are discussed. Additive usage may be divided into three major categories: a) to satisfy desired levels of performance in engines, b) to insure delivery of uncontaminated, on-specification fuels to the end user and c) achieve necessary chemical/physical properties as manufactured by the refiner.
Technical Paper

Maintaining Diesel Fuel Performance at Lowest Cost with Fuel Additives

1985-11-11
852224
Multifunctional additives can compensate for lower quality diesel fuel. Performance and quality have been decreasing worldwide. This has resulted largely from increased use of heavier crude oils and more severe processing to achieve necessary fuel product mix. Fuel additives provide the refiner and marketer with an economic approach to restoring performance and quality. Additives can be formulated to solve many problems related to deposits and wear, which are major factors affecting engine power, economy, emissions and durability. They are of critical importance to the vehicle owner/ operator to maintain dependability and low operating cost. At the same time, the refiner benefits economically through the use of lower cost crudes, greater operational flexibility and ease of adjusting final fuel blends to meet specifications. Typical additive components include: detergent dispersants, inhibitors, stabilizers, cetane improvers, and flow improvers.
Technical Paper

Gasoline and Diesel Fuel Additives for Performance/Distribution/Quality

1984-09-01
841211
Additives are an integral part of today's fuels. Together with carefully formulated base fuel composition, they contribute to efficiency, dependability and long life of gasoline and diesel engines. As a primer, this paper describes the range of chemical additives formulated for gasoline and diesel fuel and their effects. Specific functions and benefits of additives, typical use levels, and test methods for evaluation are discussed. Additive usage may be divided into three major categories: a) to satisfy desired levels of performance in engines, b) to insure delivery of uncontaminated, on-specification fuels to the end user and c) achieve necessary chemical/physical properties as manufactured by the refiner.
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