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The effectiveness of after-treatment systems depends on the exhaust gas temperature, which is low during cold-start. As a result, Euro III, Euro IV and FTP75 require that the emissions tests include exhaust from the beginning of cold start. It is proved that 50%∼80% of HC and CO emissions are emitted during the cold start and the amount of unburned fuel from the crevices during starting is much higher than that under warmed engine conditions. The piston crevices is the most part of combustion chamber crevices, and results of mathematical simulations show that the piston crevice contribution to HC emissions is expected to increase during cold engine operation. Based on the transient HC test data and the double zone combustion model, this paper presents the study of the crevice HC Mechanism of the first firing cycle at cold start on an LPG SI Engine. A fast-response flame ionization detector (FFID) was employed to measure transient HC emissions of the first firing cycle.