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Technical Paper

Three-Way Catalytic Reaction in an Electric Field for Exhaust Emission Control Application

2021-04-06
2021-01-0573
To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.
Technical Paper

Study of Simple Detection of Gasoline Fuel Contaminants Contributing to Increase Particulate Matter Emissions

2020-04-14
2020-01-0384
The reduction of particulate emissions is one of the most important challenges facing the development of future gasoline engines. Several studies have demonstrated the impact of fuel chemical composition on the emissions of particulate matter, more particularly, the detrimental effect of high boiling point components such as heavy aromatics. Fuel contamination is likely to become a critical issue as new regulations such as Real Driving Emissions RDE involves the use of market fuel. The objective of this study is to investigate several experimental approaches to detect the presence of Diesel contamination in Gasoline which is likely to alter pollutant emissions. To achieve this, a fuel matrix composed of 12 fuels was built presenting diesel fuel in varying concentrations from 0.1 to 2% v/v. The fuel matrix was characterized using several original techniques developed in this study.
Technical Paper

Effect of High RON Fuels on Engine Thermal Efficiency and Greenhouse Gas Emissions

2019-04-02
2019-01-0629
Historically, greenhouse gas (GHG) emissions standards for vehicles have focused on tailpipe emissions. However, sound environmental policy requires a more holistic well-to-wheels (WTW) assessment that includes both production of the fuel and its use in the vehicle. The present research explores the net change in WTW GHG emissions associated with moving from regular octane (RO) to high octane (HO) gasoline. It considers both potential increases in refinery emissions from producing HO fuel and potential reductions in vehicle emissions through the use of fuel-efficient engines optimized for such fuel. Three refinery configurations of varying complexity and reforming capacity were studied. A set of simulations covering different levels of HO gasoline production were run for each refinery configuration.
Technical Paper

Development of High Accuracy NOx Sensor

2019-04-02
2019-01-0749
This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.
Technical Paper

Application of Models of Short Circuits and Blow-Outs of Spark Channels under High-Velocity Flow Conditions to Spark Ignition Simulation

2018-09-10
2018-01-1727
This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.
Technical Paper

Critical Analysis of PM Index and Other Fuel Indices: Impact of Gasoline Fuel Volatility and Chemical Composition

2018-09-10
2018-01-1741
Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.
Technical Paper

Effects of EGR Constituents and Fuel Composition on DISI Engine Knock: An Experimental and Modeling Study

2018-09-10
2018-01-1677
The use of exhaust gas recirculation (EGR) in spark ignition engines has been shown to have a number of beneficial effects under specific operating conditions. These include reducing pumping work under part load conditions, reducing NOx emissions and heat losses by lowering peak combustion temperatures, and by reducing the tendency for engine knock (caused by end-gas autoignition) under certain operating regimes. In this study, the effects of EGR addition on knocking combustion are investigated through a combined experimental and modeling approach. The problem is investigated by considering the effects of individual EGR constituents, such as CO2, N2, and H2O, on knock, both individually and combined, and with and without traces species, such as unburned hydrocarbons and NOx. The effects of engine compression ratio and fuel composition on the effectiveness of knock suppression with EGR addition were also investigated.
Technical Paper

The New Toyota Inline 4-Cylinder 2.5L Gasoline Engine

2017-03-28
2017-01-1021
In order to adapt to energy security and the changes of global-scale environment, further improvement of fuel economy and adaptation to each country’s severer exhaust gas emission regulation are required in an automotive engine. To achieve higher power performance with lower fuel consumption, the engine’s basic internal design such as an engine block and cylinder head were changed and the combustion speed was dramatically increased. Consequently, stroke-bore ratio and valve layout were optimized. Also, both flow coefficient and intake tumble ratio port were improved by adopting a laser cladded valve seat. In addition, several new technologies were adopted. The Atkinson cycle using a new Electrical VVT (Variable Valve Timing) and new combustion technology adopting new multi-hole type Direct fuel Injector (DI) improved engine power and fuel economy and reduced exhaust emissions.
Technical Paper

Development of High Accuracy Rear A/F Sensor

2017-03-28
2017-01-0949
New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.
Journal Article

Development of Ignition Technology for Dilute Combustion Engines

2017-03-28
2017-01-0676
In recent years, from a viewpoint of global warming and energy issues, the need to improve vehicle fuel economy to reduce CO2 emission has become apparent. One of the ways to improve this is to enhance engine thermal efficiency, and for that, automakers have been developing the technologies of high compression ratio and dilute combustion such as exhaust gas recirculation (EGR), and lean combustion. Since excessive dilute combustion causes the failure of flame propagation, combustion promotion by intensifying in-cylinder turbulence has been indispensable. However, instability of flame kernel formation by gas flow fluctuation between combustion cycles is becoming an issue. Therefore, achieving stable flame kernel formation and propagation under a high dilute condition is important technology.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
Technical Paper

Development of Advanced Three-Way Catalyst with Improved NOx Conversion

2015-04-14
2015-01-1005
Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.
Technical Paper

Combustion Development to Achieve Engine Thermal Efficiency of 40% for Hybrid Vehicles

2015-04-14
2015-01-1254
In recent years, enhancing engine thermal efficiency is strongly required. Since the maximum engine thermal efficiency is especially important for HVs, the technologies for improving engine thermal efficiency have been developed. The current gasoline engines for hybrid vehicles have Atkinson cycle with high expansion ratio and cooled exhaust gas recirculation (EGR) system. These technologies contribute to raise the brake engine thermal efficiency to more than 38%.In the near future the consumers demand will push the limit to 40% thermal efficiency. To enhance engine thermal efficiency, it is essential to improve the engine anti-knock quality and to decrease the engine cooling heat loss. To comply with improving the anti-knock quality and decreasing the cooling heat loss, it is known that the cooled EGR is an effective way.
Technical Paper

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle

2014-10-13
2014-01-2809
In this paper, a control strategy to switch NSR (NOx storage and reduction) function from standard DeNOx by rich combustion to DiAir (Diesel NOx After-treatment by Adsorbed Intermediate Reductants) and additional advantages to use HCI (Hydrocarbon Injector) during desulfation were introduced. Investigations under a transient cycle suggest that NOx conversion with DiAir is strongly affected by preliminary NOx storage condition in the NSR catalyst. To avoid NOx breakthrough just after starting HC dosing for DiAir, a rich operation to reduce stored NOx was shown to be important and high NOx conversion could be maintained using this control strategy under a transient cycle. Furthermore, by combining HCI and in-cylinder post injection, usage of rich condition for NSR DeSOx can be expand to wider engine speed and load area.
Journal Article

Thermal Analysis of the Exhaust Line Focused on the Cool-Down Process

2014-04-01
2014-01-0655
At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.
Journal Article

New Combustion Concept for Turbocharged Gasoline Direct-Injection Engines

2014-04-01
2014-01-1210
The advantages of gasoline direct-injection are intake air cooling due to fuel vaporization which reduces knocking, additional degrees of freedom in designing a stratified injection mixture, and capability for retarded ignition timing which shortens catalyst light-off time. Stratified mixture combustion designs often require complicated piston shapes which disturb the fluid flow in the cylinder, leading to power reduction, especially in turbocharged gasoline direct-injection engines. Our research replaced the conventional shell-type shallow cavity piston with a dog dish-type curved piston that includes a small lip to facilitate stratification and minimize flow disturbance. As a result, stable stratified combustion and increased power were both achieved.
Technical Paper

Development of 3-Wet Paint System with Improved Appearance - Paint Design Based on Transfer Mechanism of Unevenness from Under Layers

2014-04-01
2014-01-1048
Waterborne 3-wet paint systems have been developed to reduce volatile organic compounds (VOCs) and CO2 on vehicle painting lines. However, only a small number of vehicles have adopted this system due to limitations in appearance quality (smoothness and gloss). Therefore, a waterborne 3-wet paint system with appearance quality equivalent to a conventional 3-coat 2-bake (3C2B) paint system is under development. This paper describes research for improving appearance quality. After analyzing the unevenness surface formation mechanism of a paint film, this was achieved by adopting base resins with a low glass transition point (Tg) to promote leveling, and reducing the melamine content of the paint to minimize contraction during baking.
Technical Paper

A Solid Particle Number Measurement System Including Nanoparticles Smaller than 23 Nanometers

2014-04-01
2014-01-1604
The particle number (PN) emission regulation has been implemented since 2011 in Europe. PN measurement procedure defined in ECE regulation No. 83 requires detecting only solid particles by eliminating volatile particles, the concentrations of which are highly influenced by dilution conditions, using a volatile particle remover (VPR). To measure PN concentration after the VPR, a particle number counter (PNC) which has detection threshold at a particle size of 23 nm is used, because most solid particles generated by automotive engines are considered to be larger than 23 nm. On the other hand, several studies have reported the existence of solid and volatile particles smaller than 23 nm in engine exhaust. This paper describes investigation into a measurement method for ultrafine PNCs with thresholds of below 23 nm and evaluation of the VPR performance for the particles in this size range. The detection efficiency of an ultrafine PNC was verified by following the ECE regulation procedure.
Technical Paper

Economy with Superior Thermal Efficient Combustion (ESTEC)

2014-04-01
2014-01-1192
From the time the first Hybrid Vehicle (HV) was launched, 17 years have past, and HV vehicles have boosted the global CO2 reduction trend. In order to maximize their merit, many HV engines focused on the best fuel consumption value namely thermal efficiency. This was because HV systems can control the operating area of engine and get merit. However, considering climate change and energy issues, it is important to focus conventional vehicle as well as HV vehicle progress. The Atkinson cycle with a high compression ratio is the typical approach that HV engines use to enhance thermal efficiency. However, the drawback of the high compression ratio is a reduction of engine torque. Thermal efficiency at low load areas is relatively more important with conventional engines than with HV engines and how to overcome these issues is significantly important with conventional engines.
Technical Paper

Influence of Engine Oil Properties on Soot Containing Deposit Formation in Turbocharger Compressor

2013-10-14
2013-01-2500
Due to increasing demands for further CO2 reduction and tighter exhaust emissions regulations, automakers are increasingly downsizing turbo-charged diesel engines by raising specific power, or adopting low-pressure loop exhaust gas recirculation (LPL-EGR) systems to improve the EGR rate. However, adopting a higher boost pressure to increase the specific power, or introducing hot exhaust gas before the turbocharger compressor with the LPL-EGR system creates higher gas temperatures in the compressor, which results in soot-containing deposits derived from the engine oil in the compressor. This phenomenon causes significant deterioration of turbocharger efficiency. Therefore, countermeasures such as restricting boost pressure or limiting EGR usage in the operational map are necessary to prevent engine performance deterioration. Increasing the gas temperature in the compressor while preventing deposit formation should enable further improvements in fuel consumption and engine power.
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