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The reduction of particulate emissions is one of the most important challenges facing the development of future gasoline engines. Several studies have demonstrated the impact of fuel chemical composition on the emissions of particulate matter, more particularly, the detrimental effect of high boiling point components such as heavy aromatics. Fuel contamination is likely to become a critical issue as new regulations such as Real Driving Emissions RDE involves the use of market fuel. The objective of this study is to investigate several experimental approaches to detect the presence of Diesel contamination in Gasoline which is likely to alter pollutant emissions. To achieve this, a fuel matrix composed of 12 fuels was built presenting diesel fuel in varying concentrations from 0.1 to 2% v/v. The fuel matrix was characterized using several original techniques developed in this study.

The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.

The effects of Hydrotreated vegetable oil (HVO) on combustion and emission characteristics in a diesel engine were investigated by using spray analyzer, engine dynamometer and vehicle tests. Spray analysis showed that spray characteristics was virtually the same for HVO and diesel. From the results of the engine dynamometer and the vehicle tests, it was found that the high cetane number and the zero aromatics of HVO could reduce in HC and PM emissions. Moreover, as a result of optimized engine calcification, HVO is capable of improving partial fuel consumption and full-load torque. These results indicate that HVO has beneficial fuel characteristics for diesel engine.

The impact of fatty acid methyl ester (FAME) blended diesel fuel on engine/vehicle systems was comprehensively investigated by vehicle, laboratory and engine tests. In this study, 20% FAME blended fuel (B20) was mainly used and soy bean oil methyl ester (SME) was primarily selected as the FAME. Vehicle testing with long-term fuel storage in vehicle fuel tanks was conducted, considering the most severe conditions in market use. Laboratory and engine tests were also conducted to better understand the vehicle test results. In the vehicle test, engine startability, idle roughness and fuel injection control were evaluated using nine vehicles with plastic or metal fuel tanks. All vehicles showed no problems up to 7 months. While five vehicles with plastic fuel tank did not show any problems throughout the test period up to 18 months, four vehicles with metal fuel tanks experienced malfunctions in engine start or fuel injection control following 8, 13, 13 and 18 months respectively.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

A study of diesel fuel as a lubricant for diesel engines was conducted with the aim of dramatically reducing engine friction and eliminating the need to change the lubricating oil. A prototype single-cylinder engine modified for diesel fuel lubrication was made, and it was confirmed that firing operation is possible. Piston friction during the firing operation was reduced by modifying the shape of the cylinder liner surface to improve the retention of the lubricating oil. The study produced valid findings concerning engine lubrication, not only with diesel fuel, but also with ultra-low viscosity oil.

In order to clarify the diesel fuel spray characteristics inside the cylinder, we developed two novel techniques, which are preparation of same level of temperature and pressure ambient as inside cylinder and quantitative measurement of vapor concentration. The first one utilizes combustion-type constant-volume chamber (inner volume 110cc), which allows 5 MPa and 873K by igniting the pre-mixture (n-pentane and air) with two spark plugs. In the second technique, TMPD vapor concentration is measured by using Laser Induced Exciplex Fluorescence method (LIEF). The concentration is compensated by investigation of the influence of ambient pressure (from 3 to 5 MPa) and temperature (from 550 to 900 K) on TMPD fluorescence intensity. By using two techniques, we investigated the influence of nozzle hole diameter, injection pressure and ambient condition on spray characteristics.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.

Precise analytical methods for characterizing diesel fuel yielding the lowest particulate emissions were developed. The methods consist of preparative-scale high pressure liquid chromatography (HPLC), field ionization mass spectrometry (FIMS), analytical-scale HPLC, and carbon-13 nuclear magnetic resonance spectrometry (13C-NMR). A diesel fuel was first separated into an aliphatic fraction and an aromatic fraction by semipreparative-scale HPLC. Then, the aliphatic fraction was analyzed by FIMS and the spectrum was compared with that of the whole fuel. The aromatic fraction was analyzed by analytical-scale HPLC to obtain the chromatogram of the aromatic hydrocarbons with a high S/N. In addition to these analyses, the fuel was analyzed by 13C-NMR to obtain the concentration of the carbon atoms of the straight chain, branched chain and aromatic-ring in hydrocarbons.

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.

Combustion and exhaust emission characteristics were compared among three representative diesel fuels called “Base (corresponding to a Japanese market fuel)”, “Improved” and Swedish “Class-1” using both a modern small and an optically accessible single-cylinder DI diesel engines. In these tests, the relative amount of PM collected in the exhaust was “Base” >“Class-1” >“Improved” at almost all of the operating conditions. This means that “Class-1” generated more PM than “Improved”, even though “Class-1” has significantly lower distillation temperatures, aromatic content, sulfur, and density compared with “Improved”. There was little difference in combustion characteristics such as heat release rate pattern, mixture formation and flame development processes between these two fuels. However, it was found that “Class-1” contained more branches in the paraffin fraction and more naphthenes.

The compositions of hydrocarbons in diesel fuel, exhaust gas and particulates were analyzed and the relationships among them were determined. It was found that the compositions of the hydrocarbons in the exhaust gas were almost the same as that of the fuel, and that the hydrocarbons in the particulates corresponded to their heavy fractions. When the engine condition was fixed, both the soluble organic fraction (SOF) and insoluble fraction ( ISF) showed positive correlation coefficients versus HC×R310, where HC denotes the hydrocarbon emission and R310 denotes the backend fraction, as measured by the fraction of fuel boiling above 310°C. On the other hand, when the engine condition was varied, ISF had negative correlation coefficients versus HC×R310, while SOF showed positive correlation coefficients.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

The effects of diesel fuel properties (aromatic content, cetane index and T90), cetane improver, oxygenates, high boiling point hydrocarbons and aromatics distribution on diesel exhaust emissions were studied under the Japanese 10-15 test cycle and the ECE+EUDC test cycle. The test vehicle was a TOYOTA COROLLA with a natural aspirated, 2.0L displacement, IDI diesel engine. It was demonstrated that particulate emissions are highly correlated with T90 and that NOx is affected by the aromatic content of fuel. A reduction in particulates emissions was observed in fuel with a lower cetane number by adding cetane improver, but this reduction was limited. Cetane improver had no effect on NOx emissions in the 45 # 60 cetane number range. Oxygenates reduced particulate emissions remarkably but had little effect on NOx emissions. A decrease in the soot in particulates was particularly observed.

The characteristics of exhausted smoke of a methanol DI diesel engine which is ignited by diesel fuel are investigated to clarify the soot formation process. At this engine, very little smoke is exhausted when diesel fuel is kept below a certain amount, so soot and smoke emitting characteristics are studied under the various diesel fuel amounts. By analyzing microstructure of soot, it is found that the soot emitted from the methanol diesel engine is composed of inner core and outer shell, similar to that of the conventional diesel engines. From more detailed qualitative analysis, the calcium percentage from the lubricating oil in outer shell is much higher than that of the conventional diesel engines. In consideration of soot characteristics, spray structure and combustion characteristics, the soot formation process of the methanol diesel engine was clarified.

In many countries, cetane number and distillation properties of diesel fuel have been changing, thus affecting the performance of diesel engines. This paper describes investigations made on the effect of diesel fuel quality on white smoke (one of the important emissions of diesel engines). The result of simple laboratory tests simulating high altitude conditions plus field tests using three types of disel engines supplied with various types of diesel fuels is given. It was found that white smoke appearing tendency correlated best with cetane number and the 90 percent distillation point of the fuel. The field tests performed at high altitude correlated well with the simple laboratory tests.