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There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

In the development of a more accurate laboratory scale method, the ability to replicate the thermal oxidative degradation mechanisms seen in gas turbine lubricants, is an essential requirement. This work describes an investigation into the influence of key reaction parameters and the equipment set up upon extent and mechanism of oil degradation. The air flow rate through the equipment was found to be critical to both degradation rate and extent of volatilization loss from the system. As these volatile species can participate in further reactions, it is important that the extent to which they are allowed to leave the test system is matched, where possible, to the conditions in the gas turbine. The presence of metal specimens was shown to have a small influence on the rate of degradation of the lubricant. Loss of metal from the copper and silver specimens due to the mild corrosive effect of the lubricant was seen.

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.