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Non-conventional operating conditions and fuels in diesel engines can produce longer ignition delays compared to conventional diesel combustion. If those extended delays are longer than the injection duration, the ignition and combustion progress can be significantly influenced by the transient following the end of injection (EOI), and especially by the modification of the mixture field. The objective of this paper is to assess how those long ignition delays, obtained by injecting at low in-cylinder temperatures (e.g., 760-800K), are affected by EOI. Two multi-hole diesel fuel injectors with either six 0.20mm orifices or seven 0.14mm orifices have been used in a 2.34L single-cylinder optical diesel engine. We consider a range of ambient top dead center (TDC) temperatures at the start of injection from 760-1000K as well as a range of injection durations from 0.5ms to 3.1ms. Ignition delays are computed through the analysis of both cylinder pressure and chemiluminescence imaging.

A study and analysis of the relation of biodiesel chemical structures to the resulting soot characteristics and soot oxidative reactivity is presented. Soot samples generated from combustion of various methyl esters, alkanes, biodiesel and diesel fuels in laminar co-flow diffusion flames are analyzed to evaluate the impact of fuel-bound oxygen in fatty acid esters on soot oxidation behavior. Thermogravimetric analysis (TGA) of soot samples collected from diffusion flames show that chemical variations in biodiesel ester compounds have an impact on soot oxidative reactivity and soot characteristics in contrast to findings reported previously in the literature. Soot derived from methyl esters with shorter alkyl chains, such as methyl butyrate and methyl hexanoate, exhibit higher reactivity than those with longer carbon chain lengths, such as methyl oleate, which are more representative of biodiesel fuels.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.

The U.S. Army currently uses JP-8 for global operations according to the "one fuel forward policy" that was enacted almost twenty years ago in order to help reduce the logistics burden of supplying a variety of fuels for given Department of Defense vehicle and base applications. One particular challenge with using global JP-8 is the lack of or too broad a range of specified combustion and fuel system affecting properties including ignition quality, high temperature viscosity, and lubricity. In addition to these challenges, the JP-8 fuel specification currently allows the use of blending with certain types of synthetic jet fuels up to 50% by volume. This blended fuel also doesn't include an ignition quality or high temperature viscosity specification, but does include a lubricity specification that is much less restrictive than DF-2.

U.S. Army ground vehicles predominately use JP-8 as the energy source for ground vehicles based on the ‘one fuel forward policy’. Though this policy was enacted almost twenty years ago, there exists little fundamental JP-8 combustion knowledge at diesel engine type boundary conditions. Nevertheless, current U.S. Army ground vehicles predominately use commercial off-the-shelf or modified commercial diesel engines as the prime mover. Unique military engines are typically utilized when commercial products do not meet the mobility and propulsion system packaging requirements of the particular ground vehicle in question.

Current U.S. Army ground vehicles predominately use commercial off-the-shelf or modified commercial diesel engines as the prime mover. Unique military engines are typically utilized when commercial products do not meet the mobility requirements of the particular ground vehicle in question. In either case, such engines traditionally have been calibrated using North American diesel fuel (DF-2) and Jet Propellant 8 (JP-8) compatibility wasn't given much consideration since any associated power loss due to the lower volumetric energy density was not an issue for most applications at then targeted climatic conditions. Furthermore, since the genesis of the ‘one fuel forward policy’ of using JP-8 as the single battlefield fuel there has been limited experience to truly assess fuel effects on diesel engine combustion systems until this decade.

Premixed diesel combustion is intended to supplant conventional combustion in the light to mid load range. This paper demonstrates the operating load limits, limiting criteria, and load-based emissions behavior of a direct-injection, diesel-fueled, premixed combustion mode across a range of test fuels. Testing was conducted on a modern single-cylinder engine fueled with a range of ultra-low sulfur fuels with cetane number ranging from 42 to 53. Operating limits were defined on the basis of emissions, noise, and combustion stability. The emissions behavior and operating limits of the tested premixed combustion mode are independent of fuel cetane number. Combustion stability, along with CO and HC emissions levels, dictate the light load limit. The high load limit is solely dictated by equivalence ratio: high PM, CO, and HC emissions result as overall equivalence ratio approaches stoichiometric.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

This paper studies the effect of nozzle geometry on the flow characteristics inside a diesel fuel injection nozzle and correlates to the subsequent atomization process under different operating conditions, using simple turbulent breakup model. Two kinds of nozzles, valve covered orifice (VCO) and mini-SAC nozzle, with various nozzle design parameters were studied. The internal flow inside the nozzle was simulated using 3-D computational fluid dynamics software with k-ε turbulence model. The flow field at the nozzle exit was characterized by two parameters: the fuel discharge coefficient Cd and the initial amplitude parameter amp0. The latter parameter represents the turbulence characteristics of the exit flow. The effects of nozzle geometry on the mean velocity and turbulent energy distribution of the exit flow were also studied. The characteristics of the exit flow were then incorporated into the spray model in KIVA-II to study the effect of nozzle design on diesel spray behavior.

I The effect of Cetane Number (CN) of the fuel and the addition of cetane improvers on the cold starting and white smoke emissions of a diesel engine was investigated. Tests were conducted on a single-cylinder, four-stroke-cycle, air-cooled, direct-injection, stand-alone diesel engine in a cold room at ambient temperatures ranging from 25 °C to - 5 °C. Five fuels were used. The base fuel has a CN of 49.2. The CN of the base fuel was lowered to 38.7 and 30.8 by adding different amounts of aromatic hydrocarbons. Iso-octyl nitrate is added to the high aromatic fuels in order to increase their CN to 48.6 and 38.9 respectively. Comparisons are made between the five fuels to determine the effect of CN and the additive on cylinder peak pressure, heat release rate, cold start-ability, combustion instability, hydrocarbon emissions and solid and liquid particulates.

A program to explore the effects of natural and additive-derived cetane on various aspects of diesel performance and combustion has been carried out. Procedures have been developed to measure diesel engine fuel consumption and power to a high degree of precision. These methods have been used to measure fuel consumption and power in three heavy-duty direct-injection diesel engines. The fuel matrix consisted of three commercial fuels of cetane number (CN) of 40-42, the same fuels raised to CN 48-50 with a cetane improver additive, and three commercial fuels of base CN 47-50. The engines came from three different U.S. manufacturers and were of three different model years and emissions configurations. Both fuel economy and power were found to be significantly higher for the cetane-improved fuels than for the naturally high cetane fuels. These performance advantages derive mainly from the higher volumetric heat content inherent to the cetane-improved fuels.

After-injection is the introduction of additional fuel to the combustion chamber after the end of the main injection. It is a persistent diesel fuel injection problem which usually results in reduced engine power and economy and increased emissions. After-injection is caused by uncontrolled pressure transients at the injector after the opening of the pump spill port. These pressure transients are related to the wave propagation phenomena in the high-pressure pipeline connecting the pump and injector. Use of experimental trial-and-error methods in attempts to control this phenomenon has met with limited success. The analytical control method described in another paper is used to determine design means by which after-injection may be controlled. Further investigation and evaluation of two design changes which release the injection system excess elastic energy in a controlled manner are considered herein. One design change is the addition of a control valve in the pump delivery chamber.

A theoretical digital simulation of a conventional diesel fuel injection system has been developed. The influence of such factors as wave propagation phenomena, pipe friction, and cavitation are included. The computer results are compared with transient pressures as measured on an actual fuel injection system operated on a test bench. The comparisons show the accuracy and validity of this simulation scheme. Special attention is given to some of the important factors that affect the accuracy of the simulation model. These include the effect of pressure on the fuel bulk modulus and wave speed, the pipe line residual pressure, and the coefficient of discharge of important orifices.

Possible mechanisms for smoke formation in the diesel engine are discussed. Emphasis is placed on the effects of some engine and fuel factors on carbon formation during the course of combustion, including cetane number, fuel volatility, air charge temperature, and after-injection. The tests were made with a single-cylinder, open chamber research engine, with three fuels, covering a wide range of inlet air temperatures and pressures. There is evidence that smoke intensity increased with increase in the cetaine number of the fuels with inlet air temperatures near atmospheric. Increase in the air charge temperature caused an increase in smoke intensity for volatile fuels and had an opposite effect on less volatile fuels for the open chamber engine used. The smoke intensity was found to increase dramatically with after-injection, with all other parameters kept constant. The concept that flame cooling is the main cause for smoke formation is examined.