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Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Present-day implementations of premixed compression ignition low temperature (PCI) combustion in diesel engines use higher levels of exhaust gas recirculation (EGR) than conventional diesel combustion. Two common devices that can be used to achieve high levels of EGR are an intake throttle and a variable geometry turbocharger (VGT). Because the two techniques affect the engine air system in different ways, local combustion conditions differ between the two in spite of, in some cases, having similar burn patterns in the form of heat release. The following study has developed from this and other observations; observations which necessitate a deeper understanding of emissions formation within the PCI combustion regime. This paper explains, through the use of fundamental phenomenological observations, differences in ignition delay and emission indices of particulate matter (EI-PM) and nitric oxides (EI-NOx) from PCI combustion attained via the two different techniques to flow EGR.

Lean Premixed Compression Ignition (PCI) low-temperature combustion promises to simultaneously reduce NOx and PM emissions, while suffering a moderate penalty in fuel consumption. Similarly, opportunities exist to develop rich PCI combustion strategies which can provide the necessary exhaust constituents for aggressive regeneration of a Lean NOx Trap (LNT). The current work highlights the development of lean and rich PCI combustion strategies. It is shown that the lean PCI combustion strategy successfully operates with low NOx and PM, at the expense of a 5% increase in fuel consumption over conventional diesel operation. The rich PCI combustion strategy similarly operates with low NOx and PM, and produces enough CO (up to 5% by volume in exhaust) for aggressive regeneration of an LNT.

A compression ignition direct injection (CIDI) engine was used to evaluate the engine-out emissions from four advanced CIDI fuels that define a broad range of properties. The fuels include a market-averaged California fuel (designated CARB) to serve as a benchmark, a petroleum-based low sulfur, low aromatic hydrocracked fuel (LSHC), the LSHC fuel blended with 15% dimethoxy methane (DMM15), and a neat Fischer-Tropsch fuel (FT100). Engine-out particulate matter (PM), oxides of nitrogen (NOx), and performance data were collected at 5 steady-state operating conditions. The engine calibration was optimized for each fuel and operating condition. Fuel injection timing was optimized for best fuel economy and the injection pressure was optimized for minimum smoke. The PM-NOx trade-off for EGR dilution was established for each fuel and operating condition with the optimum injection timing and pressure.

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.