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Ammonia, often present in exhaust gas samples, is a polar molecule gas that interacts with walls of the gas sampling and analysis equipment resulting in delayed instrument response. A set of experiments quantified various materials and process parameters of a heated sample line system for ammonia (NH3) response using a Fourier Transform infrared spectrometer (FTIR). Response attenuation rates are due to mixing and diffusion during transport as well as NH3 wall storage. Mixing/diffusion effects cause attenuation with a time constant 1-10 seconds. Wall storage attenuation has a time constant 10-200 seconds. The effects of sample line diameter and length, line temperature, line material, hydrated versus dry gas, and flow rate were examined. All of these factors are statistically significant to variation of at least one of the time constants. The NH3 storage on the sample system walls was calculated as a function of the experimental test as well.

The buildup of deposits in EGR coolers causes significant degradation in heat transfer performance, often on the order of 20-30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operating conditions. It is unlikely that EGR cooler deposits can be prevented from forming when soot and HC are present. The presence of cooled surfaces will cause thermophoretic soot deposition and condensation of HC and acids. While this can be affected by engine calibration, it probably cannot be eliminated as long as cooled EGR is required for emission control. It is generally felt that “dry fluffy” soot is less likely to cause major fouling than “heavy wet” soot. An oxidation catalyst in the EGR line can remove HC and has been shown to reduce fouling in some applications. The combination of an oxidation catalyst and a wall-flow filter largely eliminates fouling. Various EGR cooler designs affect details of deposit formation.