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A GT-SUITE vehicle-aftertreatment model has been developed to examine the cold-start emissions reduction capabilities of a Vacuum Insulated Catalytic Converter (VICC). This converter features a thermal management system to maintain the catalyst monolith above its light-off temperature between trips so that most of a vehicle’s cold-start exhaust emissions are avoided. The VICC thermal management system uses vacuum insulation around the monoliths. To further boost its heat retention capacity, a metal phase-change material (PCM) is packaged between the monoliths and vacuum insulation. To prevent overheating of the converter during periods of long, heavy engine use, a few grams of metal hydride charged with hydrogen are attached to the hot side of the vacuum insulation. The GT-SUITE model successfully incorporated the transient heat transfer effects of the PCM using the effective heat capacity method.