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Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

High-pressure gasoline injection can improve combustion efficiency and lower engine-out emissions; however, the spray characteristics of high-pressure gasoline (>500 bar) are not well known. Effects of different injector nozzle geometry on high-pressure gasoline sprays were studied using a constant volume chamber. Five nozzles with controlled internal flow features including differences in nozzle inlet rounding, conicity, and outlet diameter were investigated. Reference grade gasoline was injected at fuel pressures of 300, 600, 900, 1200, and 1500 bar. The chamber pressure was varied using nitrogen at ambient temperature and pressures of 1, 5, 10, and 20 bar. Spray development was recorded using diffuse backlit shadowgraph imaging methods.

The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, called the Particulate Evaluation Index (PEI), and provide the detailed equation in its initial form. In addition, the PEI will be shown to have a good correlation agreement to PMI. The paper will then give a detailed explanation of the data used to develop it. Initial vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.

As European and Chinese tailpipe emission regulations for gasoline light-duty vehicles impose particulate number limits, automotive manufacturers have begun equipping some vehicles with a gasoline particulate filter (GPF). Increased understanding of how soot morphology, reactivity, and GPF loading affect GPF filtration and regeneration characteristics is necessary for advancing GPF performance. This study investigates the impacts of morphology, reactivity, and filter soot loading on GPF filtration and regeneration. Soot morphology and reactivity are varied through changes in fuel injection parameters, known to affect soot formation conditions. Changes in morphology and reactivity are confirmed through analysis using a transmission electron microscope (TEM) and a thermogravimetric analyzer (TGA) respectively.

Combined direct and port fuel injection (i.e., dual injection) in spark ignition engines is of increasing interest due to the advantages for fuel flexibility and the individual merits of each system for improving engine performance and reducing engine-out emissions. Greater understanding of the impact of dual injection will enable deriving the maximum benefit from the two injection systems. This study investigates the effects of dual injection on combustion, especially knock propensity and tolerance to exhaust gas recirculation (EGR) dilution at different levels of EGR. A baseline for comparison with dual injection results was made using direct injection fueling only. A splash blended E20 fuel was used for the direct injection only tests. For the dual injection tests, gasoline, representing 80% by volume of the total fuel, was injected using the direct injector, and ethanol, representing 20% by volume of the total fuel, was injected using the port fuel injector.

Natural gas (NG) is attractive for heavy-duty (HD) engines for reasons of cost stability, emissions, and fuel security. NG cannot be reliably compression-ignited, but conventional gasoline ignition systems are not optimized for NG and are challenged to ignite mixtures that are lean or diluted with exhaust-gas recirculation (EGR). NG ignition is particularly challenging in large-bore engines, where completing combustion in the available time is more difficult. Using two high-speed infrared (IR) cameras with borescopic access to one cylinder of an HD NG engine, the effect of ignition system on the early flame-kernel development and cycle-to-cycle variability (CCV) was investigated. Imaging in the IR yielded strong signals from water emission lines, which located the flame front and burned-gas regions and obviated image intensifiers. A 9.7-liter, six-cylinder engine was modified to enable exhaust-gas recirculation and to provide optical access.

High-pressure gasoline fuel injection is a means to improve combustion efficiency and lower engine-out emissions. The objective of this study was to quantify the effects of fuel injection pressure on transient gasoline fuel spray development for a wide range of injection pressures, including over 1000 bar, using a constant volume chamber and high-speed imaging. Reference grade gasoline was injected at fuel pressures of 300, 600, 900, 1200, and 1500 bar into the chamber, which was pressurized with nitrogen at 1, 5, 10, and 20 bar at room temperature (298 K). Bulk spray imaging data were used to quantify spray tip penetration distance, rate of spray tip penetration and spray cone angle. Near-nozzle data were used to evaluate the early spray development.

Numerous studies have demonstrated the benefits of ethanol in increasing the thermal efficiency of gasoline-fueled spark ignition engines via the higher enthalpy of vaporization and higher knock resistance of ethanol compared with gasoline. This study expands on previous work by considering a split fuel injection strategy with a boosted direct injection spark ignition engine fueled with E0 (100% by volume reference grade gasoline; with research octane number = 91 and motor octane number = 83), E100 (100% by volume anhydrous ethanol), and various splash-blends of the two fuels. Experiments were performed using a production 3-cylinder Ford Ecoboost engine where two cylinders were de-activated to create a single-cylinder engine with a displacement of 0.33 L. The engine was operated over a range of loads with boosted intake manifold absolute pressure (MAP) from 1 bar to 1.5 bar.

Syngas (synthesis gas) aided combustion from various fuel reforming strategies is of increasing interest in boosted lean burn SI engines due to its impact on dilution tolerance and knock resistance. Due to the interest in reformed fuels, more concrete understanding of how to leverage syngas supplementation under various lean conditions is essential to optimize engine performance and derive the most benefit from the availability of syngas in the combustion process. While the impact of syngas supplementation on combustion stability has been studied adequately, detailed understanding of the impact of syngas on knocking is still limited. Hence, this study investigates the effect of syngas (H2/CO) addition on knock tendency under boosted EGR (Exhaust Gas Recirculation) and air diluted conditions. Syngas amount is controlled on an energy basis from 0% to 15% to compare the difference between EGR and air dilution.

The automotive industry has been witnessing a major shift towards downsized boosted direct injection engines due to diminishing petroleum reserves and increasingly stringent emission targets. Boosted engines operate at a high mean effective pressure (MEP), resulting in higher in-cylinder pressures and temperatures, effectively leading to increased possibility of abnormal combustion events like knock and pre-ignition. Therefore, the compression ratio and boost pressure in modern engines are restricted, which in-turn limits the engine efficiency and power. To mitigate conditions where the engine is prone to knocking, the engine control system uses spark retard and/or mixture enrichment, which decrease indicated work and increase specific fuel consumption. Several researchers have advocated water injection as an approach to replace or supplement existing knock mitigation techniques.

This study investigates the use of a characteristic reaction time as a possible method to speed up automotive knock calculations. In an earlier study of HCCI combustion it was found that for ignition at TDC, the ignition delay time at TDC conditions was required to be approximately 10 crank angle degrees (CAD), regardless of engine speed. In this study the analysis has been applied to knock in SI engines over a wide range of engine operating conditions including boosted operation and retarded combustion phasing, typical of high load operation of turbocharged engines. Representative pressure curves were used as input to a detailed kinetics calculation for a gasoline surrogate fuel mechanism with 312 species. The same detailed mechanism was used to compile a data set with traditional constant volume ignition delays evaluated at the peak pressure conditions in the end gas assuming adiabatic compression.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

Cooled EGR provides benefits in better fuel economy and lower emissions by reducing knocking tendency and decreasing peak cylinder temperature in gasoline engines. However, GDI engines have high particle emissions due to limited mixing of fuel and air, and these particle emissions can be a major source of EGR cooler fouling. In order to improve our knowledge of GDI engine EGR cooler fouling, the effects of tube geometry and coolant temperature on EGR cooler performance and degradation were studied using a four cylinder 2.0L turbocharged GDI engine. In addition, deposit microstructure was analyzed to explore the nature of deposits formed under GDI engine operation. The results of this study showed that a dented tube geometry was more effective in cooling the exhaust gas than a smooth tube due to its large surface area and turbulent fluid motion. However, more deposits were accumulated and higher effectiveness loss was observed in the dented tube.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.

The U.S. Renewable Fuel Standard 2 (RFS2) mandates the use of advanced renewable fuels such as cellulosic ethanol to be blended into gasoline in the near future. As such, determining the impact of these new fuel blends on vehicle performance is important. Therefore, General Motors conducted engine dynamometer evaluations on the impact of cellulosic ethanol blends on port fuel injected (PFI) intake valve deposits and gasoline direct injected (GDI) fuel injector plugging. Chemical analysis of the test fuels was also conducted and presented to support the interpretation of the engine results. The chemical analyses included an evaluation of the specified fuel parameters listed in ASTM International's D4806 denatured fuel ethanol specification as well as GC/MS hydrocarbon speciations to help identify any trace level contaminant species from the new ethanol production processes.

Biodiesel, a fuel comprised of mono-alkyl esters of long-chain fatty acids also known as Fatty Acid Methyl Esters(FAME), derived from vegetable oils or animal fats, has become an important commercial marketplace automotive fuel in the United States (US) and around the world over last few years. FAME biodiesels have many chemical and physical property differences compared to conventional petroleum based diesel fuels. Also, the properties of biodiesel vary based on the feedstock chosen for biodiesel production. One of the key differences between petroleum diesel fuels and biodiesel is the energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects the vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb calorimeter, this analytical laboratory testing is time consuming and expensive.

An investigation of high speed direct injection (DI) compression ignition (CI) engine combustion fueled with gasoline injected using a triple-pulse strategy in the low temperature combustion (LTC) regime is presented. This work aims to extend the operation ranges for a light-duty diesel engine, operating on gasoline, that have been identified in previous work via extended controllability of the injection process. The single-cylinder engine (SCE) was operated at full load (16 bar IMEP, 2500 rev/min) and computational simulations of the in-cylinder processes were performed using a multi-dimensional CFD code, KIVA-ERC-Chemkin, that features improved sub-models and the Chemkin library. The oxidation chemistry of the fuel was calculated using a reduced mechanism for primary reference fuel combustion chosen to match ignition characteristics of the gasoline fuel used for the SCE experiments.

A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

A comprehensive experimental and theoretical approach was undertaken to understand the phenomenon of pre-ignition and to assess parameters to improve or even eliminate it completely. Oil mixing with fuel was identified as the leading theory of self ignition of the fuel. End of compression temperature has to meet a minimum level for pre-ignition to take place. In this work a comprehensive list of parameters were identified that have a direct and crucial role in the onset of pre-ignition including liner wetting, injection targeting, stratification, mixture motion and oil formulation. Many secondary effects were identified including ring dynamics, ring tension, spark plug electrode temperature and coolant temperature. CFD has been extensively used to understand test results including wall film, A/F ratio distribution and temperature at the end of compression when looked at in the context of fuel evaporation and mixing.