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Internal combustion (IC) engines fueled by hydrogen are among the most efficient means of converting chemical energy to mechanical work. The exhaust has near-zero carbon-based emissions, and the engines can be operated in a manner in which pollutants are minimal. In addition, in automotive applications, hydrogen engines have the potential for efficiencies higher than fuel cells.[1] In addition, hydrogen engines are likely to have a small increase in engine costs compared to conventionally fueled engines. However, there are challenges to using hydrogen in IC engines. In particular, efficient combustion of hydrogen in engines produces nitrogen oxides (NOx) that generally cannot be treated with conventional three-way catalysts. This work presents the results of experiments which consider changes in direct injection hydrogen engine design to improve engine performance, consisting primarily of engine efficiency and NOx emissions.

Injecting liquid water into a fuel/air charge is a means to reduce NOx emissions. Such strategies are particularly important to hydrogen internal combustion engines, as engine performance (e.g., maximum load) can be limited by regulatory limits on NOx. Experiments were conducted in this study to quantify the effects of direct injection of water into the combustion chamber of a port-fueled, hydrogen IC engine. The effects of DI water injection on NOx emissions, load, and engine efficiency were determined for a broad range of water injection timing. The amount of water injected was varied, and the results were compared with baseline data where no water injection was used. Water injection was a very effective means to reduce NOx emissions. Direct injection of water into the cylinder reduced NOx emissions by 95% with an 8% fuel consumption penalty, and NOx emissions were reduced by 85% without any fuel consumption penalty.