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Fe16N2 is one of the promising candidates for rare-earth free magnets. It possesses a giant saturation magnetization (Ms) and reasonably high magnetocrystalline anisotropy. Past efforts made in synthesizing Fe16N2 were mostly on thin films, foils, and fine powders through different processes including sputtering, ion implantation, chemical reactions, and ball milling; this could cause a challenge of scaling up into massive production. The limitation in massive production of Fe16N2 requires intensive investigations to conquer. Compared with our previous endeavor of the low-temperature synthesizing process of Fe16N2 in bulk form, this paper proposes a method of gaseous nitridation with a high-temperature approach that can improve the process efficiency by applying the quenching and tempering treatment to address the challenge.

A key challenge for the practical introduction of dual-fuel reactivity controlled compression ignition (RCCI) combustion modes in diesel engines is the requirement to store two fuels on-board. This work demonstrates that partially reforming diesel fuel into less reactive products is a promising method to allow RCCI to be implemented with a single stored fuel. Experiments were conducted using a thermally integrated reforming reactor in a reformed exhaust gas recirculation (R-EGR) configuration to achieve RCCI combustion using a light-duty diesel engine. The engine was operated at a low engine load and two reformed fuel percentages over ranges of exhaust gas recirculation (EGR) rate and main diesel fuel injection timing. Results show that RCCI-like emissions of NOx and soot were achieved load using the R-EGR configuration. It was also shown that complete fuel conversion in the reforming reactor is not necessary to achieve sufficiently low fuel reactivity for RCCI combustion.

Partially premixed low temperature combustion (LTC) in diesel engines is a strategy for reducing soot and NOX formation, though it is accompanied by higher unburned hydrocarbon (UHC) emissions compared to conventional mixing-controlled diesel combustion. In this work, two independent methods of quantifying light UHC species from a diesel engine operating in early LTC (ELTC) modes were compared: Fourier transform infrared (FT-IR) spectroscopy and gas chromatography-mass spectroscopy (GC-MS). A sampling system was designed to capture and transfer exhaust samples for off-line GC-MS analysis, while the FT-IR sampled and quantified engine exhaust in real time. Three different ELTC modes with varying levels of exhaust gas recirculation (EGR) were implemented on a modern light-duty diesel engine. GC-MS and FT-IR concentrations were within 10 % for C2H2, C2H4, C2H6, and C2H4O. While C3H8 was identified and quantified by the FT-IR, it was not detected by the GCMS.

Many dual fuel technologies have been proposed for diesel engines. Implementing dual fuel modes can lead to emissions reductions or increased efficiency through using partially premixed combustion and fuel reactivity control. All dual fuel systems have the practical disadvantage that a secondary fuel storage and delivery system must be included. Reforming the primary diesel to a less reactive vaporized fuel on-board has potential to overcome this key disadvantage. Most previous research regarding on-board fuel reforming has been focused on producing significant quantities of hydrogen. However, only partially reforming the primary fuel is sufficient to vaporize and create a less volatile fuel that can be fumigated into an engine intake. At lower conversion efficiency and higher equivalence ratio, reforming reactors retain higher percentage of the inlet fuel’s heating value thus allowing for greater overall engine system efficiency.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.

A fully flexible valve actuation (FFVA) system was developed for a single cylinder research engine to investigate high efficiency clean combustion (HECC) in a diesel engine. The main objectives of the study were to examine the emissions, performance, and combustion characteristics of the engine using late intake valve closing (LIVC) to determine the benefits and limitations of this strategy to meet Tier 2 Bin 5 NOx requirements without after-treatment. The most significant benefit of LIVC is a reduction in particulates due to the longer ignition delay time and a subsequent reduction in local fuel rich combustion zones. More than a 95% reduction in particulates was observed at some operating conditions. Combustion noise was also reduced at low and medium loads due to slower heat release. Although it is difficult to assess the fuel economy benefits of LIVC using a single cylinder engine, LIVC shows the potential to improve the fuel economy through several approaches.

Combustion aerosols consist mainly of elemental and organic carbon (EC and OC). Since EC strongly absorbs light and thus affects atmospheric visibility and radiation balance, there is great interest in its measurement. To this end, the National Institute for Occupational Safety and Health (NIOSH) published a standard method to determine the mass of EC and OC on filter samples. Another common method of measuring carbon in aerosols is the aethalometer, which uses light extinction to measure “black carbon” or BC, which is considered to approximate EC. A third method sometimes used for estimating carbon in submicron combustion aerosols, is to measure particle size distributions using a scanning mobility particle sizer (SMPS) and calculate mass using the assumptions that the particles are spherical, carbonaceous and of known density.

The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.

Earlier work [1] shows that kinetics of Diesel soot oxidation is different from that of ethylene diffusion flame soot oxidation [2], possibly due to metals from lube oil. This study investigates the influence of metals on soot oxidation and the exhaust particle emissions using lube oil dosed fuel (2 % by volume). This method does not simulate normal lube oil consumption, but is used as a means of adding metals to particles for oxidation studies. This study also provides insight into the effect of systems that mix lube oil with fuel to minimize oil change service. The HTO-TDMA (High Temperature Oxidation-Tandem Differential Mobility Analyzer) technique [1] was used to measure the surface specific oxidation rate of Diesel particles over the temperature range 500-750 °C. Diesel particles sampled from the exhaust stream of a Diesel engine were size segregated by differential mobility and oxidized in situ in air in a heated flow tube of known residence time and temperature profile.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.

Particle size distribution and number concentration measurements have been made in the diluted exhaust of a medium-duty, turbocharged, aftercooled, direct-injection Diesel engine using a unique variable residence time micro-dilution system that allows systematic variation of dilution and sampling conditions, and a scanning mobility particle sizer (SMPS). The measurements show that the number concentrations in the nanoparticle (Dp < 50 nm) and the ultrafine (Dp < 100 nm) ranges are very sensitive to dilution conditions and fuel sulfur content. Changes in concentration of up to two orders of magnitude have been observed when conditions are varied over the range that might be encountered in typical laboratory dilution systems. For example, at a dilution ratio of 12, dilution temperature of 32 °C, and a residence time of 1000 ms, the number concentrations reach 6 × 108 part.

Particle concentrations and size distributions were measured in the exhaust of a turbocharged, aftercooled, direct-injection, Diesel engine equipped with a ceramic filter (trap). Measurements were performed both upstream and downstream of the filter using a two-stage, variable residence time, micro-dilution system, a condensation particle counter and a scanning mobility particle sizer set up to count and size particles in the 7-320 nm diameter range. Engine operating conditions of the ISO 11 Mode test were used. The engine out (upstream of filter) size distribution has a bimodal, log normal structure, consisting of a nuclei mode with a geometric number mean diameter, DGN, in the 10-30 nm range and an accumulation mode with DGN in the 50-80 nm range. The modal structure of the size distribution is less distinct downstream of the filter. Nearly all the particle number emissions come from the nuclei mode, are nanoparticles (Dp < 50nm), and are volatile.

Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.

Particulate emissions from heavy-duty buses were measured in real time under conditions encountered during the standard Central Business District (CBD) driving cycle. The buses tested were equipped with 1994 Detroit Diesel Engine Corporation 6V92-TA engines, and some included after treatment devices on the exhaust. Instantaneous, time-resolved measurements of CO2 and amorphous carbon concentrations were obtained using an optical extinction technique and compared to simultaneous results obtained using conventional dilution tunnel sampling methods. Good agreement was obtained between the real-time extinction measurements and the diluted CO2 and cycle-integrated filter measurements. The instantaneous measurements revealed that acceleration transients accounted for roughly 80% of the particulate mass emitted during the cycle but only about 45% of the fuel consumption.

Low emission heavy-duty diesel engines are increasingly utilizing four-valve designs with vertical central injectors. However, two-valve DI diesel engines with inclined injectors offset from the centerline of the piston bowl are likely to continue to be used in medium and light duty applications for some time. In such situations, designing of the hole-type nozzle is very difficult and may cause unavoidable back-drilling problems. The purpose of this paper is to solve back-drilling problems connected with hole-type nozzles and improve fuel-air mixing which leads to more efficient combustion. Based on geometric considerations, this paper introduces single-cone hole-type nozzles, double-cone hole-type nozzles, and the critical principal angles for hole-type nozzles. The single-cone hole-type nozzles and double-cone hole-type nozzles can meet requirements for height of the spray impingement points and spray orifice distribution angle at the same time.

A system has been developed that allows near real time measurements of total, volatile, and nonvolatile particle concentrations in engine exhaust. It consists of a short section of heated catalyst, a cooling coil, and an electrical aerosol analyzer. The performance of this catalytic stripper system has been characterized with nonvolatile (NaCl), volatile sulfate ((NH4)2 SO4), and volatile hydrocarbon (engine oil) particles with diameters ranging from 0.05-0.5 μm. The operating temperature of 300°C gives essentially complete removal of volatile sulfate and hydrocarbon particles, but also leads to removal of 15-25% of solid particles. This system has been used to determine total, volatile, and nonvolatile particle concentrations in the exhaust of a Diesel engine and a spark ignition engine. Volatile volume fractions measured in Diesel exhaust with the catalytic stripper system increased from 19-65% as the equivalence ratio (load) decreased from 0.64-0.13.

As part of an ongoing program to control the emissions of diesel-powered equipment used in underground mines, the U. S. Bureau of Mines evaluated exhaust emissions from a compression ignition engine using oxygenated diesel fuels and a diesel oxidation catalyst (DOC). The fuels include neat (100%) soy methyl ester (SME), and a blend of 30% SME (by volume) with 70% petroleum diesel fuel. A Caterpillar 3304 PCNA engine was tested for approximately 50 hours on each fuel. Compared with commercial low-sulfur diesel fuel (D2), neat SME increased volatile organic diesel particulate matter (DPM) but greatly decreased non-volatile DPM, for a net decrease in total DPM. The DOC further reduced volatile and total DPM NOx emissions were slightly reduced for the case of neat SME, but otherwise were not significantly affected. Peak brake power decreased 9% and brake specific fuel consumption increased 13 to 14% for the neat methyl soyate because of its lower energy content compared with D2.

Results of comparisons of computed and measured soot and NO in a direct-injection Diesel engine are presented. The computations are carried out using a three-dimensional model for flows, sprays and combustion in Diesel engines. Autoignition of the Diesel spray is modeled using an equation for a progress variable which measures the local and instantaneous tendency of the fuel to autoignite. High temperature chemistry is modeled using a local chemical equilibrium model coupled to a combination of laminar kinetic and turbulent characteristic times. Soot formation is kinetically controlled and soot oxidation is represented by a model which has a combination of laminar kinetic and turbulent mixing times. Soot oxidation appears to be controlled near top-dead-center by mixing and by kinetics as the exhaust is approached. NO is modeled using the Zeldovich mechanism.

Results of three-dimensional computations of non-vaporizing and vaporizing Diesel sprays in a very high pressure (up to 18.4 MPa without combustion) environment are presented. These pressures and corresponding density ratios of ambient gas to injected liquid are about a factor of two greater than those in current Diesel engines. The spray model incorporates a line source for drops, heat, mass and momentum exchange between the gas and liquid phases, turbulent dispersion of drops, collisions and coalescences, and drop breakup. The accuracy of the model is assessed by making comparisons of computed and measured spray penetrations. Reasonable agreement is obtained for a broad range of conditions. A scaling for time and axial distance clarifies these results.