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Over the last decade, there has been an impetus in the automobile industry to develop new diesel injector systems, driven by a desire to reduce fuel consumption and proscribed by the requirement to fulfil legislation emissions. The modern common-rail diesel injector system has been developed by the industry to fulfil these aspirations, designed with ever-higher tolerances and pressures, which have led to concomitant increases in fuel temperatures after compression with reports of fuel temperatures of ~150°C at 1500-2500 bar. This engineering solution in combination with the introduction of Ultra Low Sulphur diesel fuel (ULSD) has been found to be highly sensitive to deposit formation both external injector deposits (EDID) and internal (IDID). The deposits have caused concerns for customers with poor spray patterns misfiring injector malfunction and failure, producing increased fuel consumption and emissions.

The nature of internal diesel injector deposits (IDID) continues to be of importance to the industry, with field problems such as injector sticking, loss of power, increased emissions and fuel consumption being found. The deposits have their origins in the changes in emission regulations that have seen increasingly severe conditions experienced by fuels because of high temperatures and high pressures of modern common rail systems and the introduction of low sulphur fuels. Furthermore, the effect of these deposits is amplified by the tight engineering tolerances of the moving parts of such systems. The nature and thus understanding of such deposits is necessary to both minimising their formation and the development of effective diesel deposit control additives (DCA).