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The effects of fuel injection and spark timing on engine-out, regulated (total HC, NOx, and CO) and speciated HC emissions have been investigated for a 0.31L, single-cylinder, direct-injection, spark-ignition (DISI) engine equipped with an air-forced fuel injector. When the timing of the start of the air injection (SOA) is varied during high stratification operation, the mole fractions of all regulated emissions vary sharply over relatively small (20-30 crank angle degrees) changes in SOA. In addition, the distribution of exhaust hydrocarbon species changes significantly. As stratification increases, the contribution of unburned paraffinic fuel components to the HC emissions decreases by a factor of two while the olefinic partial oxidation products increase. When the spark timing is varied during high stratification operation, the HC emissions increase sharply as the spark timing is retarded relative to MBT.

A single-cylinder, spark-ignited engine was run on a certification test gasoline to saturate the oil in the sump with fuel through exposure to blow-by gas. The sump volume was large relative to production engines making its absorption-desorption time constant long relative to the experimental time. The engine was motored at 1500 RPM, 90° C coolant and oil temperature, and 0.43 bar MAP without fuel flow. Exhaust HC concentrations were measured by on-line FID and GC analysis. The total motoring HC emissions were 150 ppmC1; the HC species distribution was heavily weighted to the low-volatility components in the gasoline. No high volatility components were visible. The engine was then fired on isooctane fuel at the above conditions, producing a total engine-out HC emission of 2300 ppmC1 for Φ = 1.0 and MBT spark timing.

Total and speciated, engine-out, hydrocarbon (HC) emissions have been measured as a function of time after a 23°C cold start of a gasoline-fueled, V-8 engine. Hydrocarbon emissions from two fuel injection systems were compared: a production port-fuel-injection (PFI) system; and a pre-vaporized (heated) central-fuel-injection (PV-CFI) system. The results indicate that, for this particular engine at the chosen operating conditions, the effect of fuel preparation on HC emissions during cold start is minimal at low load (2.57 bar IMEP (gross), MAP = 0.34 bar) but becomes significant at higher load (5.15 bar IMEP, MAP = 0.58 bar) early in the cold start. Comparison of the relative contribution to the exhaust HC of a series of fuel-derived alkanes suggests that fuel absorption in oil films is a minor contributor to HC emissions from this engine during a 23°C cold start.

Absorption of fuel in engine oil layers has been shown to be a possible source of hydrocarbon (HC) emissions from spark-ignited engines. However, the magnitude of this source in a normally operating engine has not been determined unambiguously. In these experiments, a series of n-alkanes of widely different solubility (n-hexane through undecane) was added (1.5 wt % each) to a Base gasoline (CA Phase 2). Steady-state experiments were carried out at two coolant temperatures (339 and 380 K) using a single-cylinder engine with the combustion chamber of a production V-8. Both total and speciated engine-out HC emissions were measured. The emissions indices of the heavier dopants did not increase relative to hexane at either coolant temperature.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

Modern four-valve engines are running at ever higher compression ratios in order to improve fuel efficiency. Hotter cylinder bores also can produce increased fuel economy by decreasing friction due to less viscous oil layers. In this study changes in compression ratio and coolant temperature were investigated to quantify their effect on exhaust emissions. Tests were run on a single cylinder research engine with a port-deactivated 4-valve combustion chamber. Two compression ratios (9.15:1 and 10.0:1) were studied at three air/fuel ratios (12.5, 14.6 and 16.5) at a part load condition (1500 rpm, 3.8 bar IMEP). The effect of coolant temperature (66 °C and 108°C) was studied at the higher compression ratio. The exhaust was sampled and analyzed for both total and speciated hydrocarbons. The speciation analysis provided concentration data for hydrocarbons present in the exhaust containing twelve or fewer carbon atoms.

For several years, a single-cylinder, spark-ignited engine without catalyst has been operated at Ford on single-component fuels that are constituents of gasoline as well as on simple fuel mixtures. This paper presents a review of these experiments as well as others pertinent to understanding hydrocarbon emissions. The engine was run at four steady-state conditions which are typical of normal operation. The fuel structure and the engine operating conditions affected both the total HC emissions and the reactivity of these emissions for forming photochemical smog in the atmosphere. These experiments identified major precursor species of the toxic HC emissions benzene and 1,3-butadiene to be alkylated benzenes and either straight chain terminal olefins or cyclic alkanes, respectively. In new data presented, the primary exhaust hydrocarbon species from MTBE combustion is identified as isobutene.

Currently most automotive manufacturers calibrate for rich air/fuel ratios at wide open throttle which produces lower exhaust gas temperatures. Future federal emissions regulations may require less enrichment under these conditions. This study was undertaken to address the question of what happens to engine-out hydrocarbon emissions with different air/fuel ratios at wide open throttle. Tests were run on a single cylinder research engine with a two valve combustion chamber at a compression ratio of 9:1. The test matrix included three air/fuel ratios (10.5, 12.5 and 14.5) and two speeds (1500 and 3000 rpm) at wide open throttle as well as three air/fuel ratios (12.5, 14.6 and 16.5) at a part load condition (1500 rpm, 3.8 bar IMEP). The exhaust was sampled and analyzed for both total and speciated hydrocarbons. The speciation analysis provided concentration data for hydrocarbons present in the exhaust containing twelve or fewer carbon atoms.

Speciated HC emissions from the exhaust system of a production engine without an active catalyst have been obtained with 3 sec time resolution during a 70°F cold start using two control strategies. For the conventional cold start, the emissions were initially enriched in light fuel alkanes and depleted in heavy aromatic species. The light alkanes fell rapidly while the lower vapor pressure aromatics increased over a period of 50 sec. These results indicate early retention of low vapor pressure fuel components in the intake manifold and exhaust system. Loss of higher molecular weight HC species does occur in the exhaust system as shown by experiments in which the exhaust system was preheated to 100° C. The atmospheric reactivity of the exhaust HC emissions for photochemical smog formation increases as the engine warms.