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Synthetic fuels can significantly improve the combustion and emission characteristics of heavy-duty diesel engines toward decarbonizing heavy-duty propulsion systems. This work analyzes the effects of engine operating conditions and synthetic fuel properties on spray, combustion, and emissions (soot, NOx) using a supercharging single-cylinder engine experiment and KIVA-4 code combined with CHEMKIN-II and in-house phenomenological soot model. The blended fuel ratio is fixed at 80% diesel and 20% n-paraffin by volume (hereafter DP). Diesel, DP1 (diesel with n-pentane C5H12), DP2 (diesel with n-hexane C6H14), and DP3 (diesel with n-heptane C7H16) are used in engine-like-condition constant volume chamber (CVC) and engine experiments. Boosted engine experiments (1080 rpm, common-rail injection pressure 160 MPa, multi-pulse injection) are performed using the same DP fuel groups under various main injection timings, pulse-injection intervals, and EGR = 0-40%.

A high compression ratio is an effective means for improving the thermal efficiency of an internal combustion engines. However, a high compression ratio leads to a rapid rise in the combustion pressure, as it causes a high impulse force. The impulse force generates vibrations and noise by spreading in the engine. Therefore, reducing the vibration of the combustion (which increases as the compression ratio increases) can improve the thermal efficiency while using the same technology. We are conducting model-based research on technologies for reducing combustion vibration by applying a granular damper to a piston. To efficiently reduce the vibration, we suppress it directly with the piston, i.e., the source of the vibration. Thus, the damping effect is maximized within a minimized countermeasure range.

In our previous reports, we proposed a new focusing engine with high thermal efficiency based on relatively-silent high compression and nearly-complete air-insulation effect, which employs pulsed multi-jets of gas collided around chamber center. Local compression level due to the gas jets colliding around chamber center before reaction can be varied from zero to 100MPa and 3000K, by changing the number of jets and intake pressure. Relatively-silent high compression is possible, because region around chamber wall is at pressure level of traditional engines. This is suitable for various usages of automobiles, aerocrafts, and rockets, and also for various fuels including hydrogen, because high compression around chamber center leads to stable auto-ignition and potential of low NOx at very lean burning operation. We developed two types of focusing compression engines, without and with piston. For the new engine without piston, we obtained nearly-complete air-insulation and high thrust.

We have proposed a new compressive combustion principle leading to the auto-ignition of fuel by focusing compression due to the collision of the pulsed supermulti-jets. This principle has the potential of nearly-complete air insulation due to encasing burned gas around the center of the combustion chamber and a high compression ratio around the chamber center while suppressing vibration and noise levels. We have developed the first prototype engine having a very small combustion chamber of a diameter of 18 mm and also 14 side passages for the supermulti-jets colliding at the chamber center. Combustion experimental results indicating air insulation effect and high thrust over 100 N were obtained as basic data for various types of applications, including automobiles and aerospace usage such as for rockets. However, it was found that higher compression due to more jets is necessary to get stabler combustion.

In this study, reaction path analysis and modeling of NOx reduction phenomena by fast SCR reaction on a Cu-chabazite catalyst were conducted, considering the formation and decomposition of ammonium nitrate (NH4NO3). White crystals of NH4NO3 decompose at temperatures < 200 °C. Thus, the reaction behavior changes at 200 °C under fast SCR reaction conditions. NH4NO3 formation can occur on both Cu sites and Brønsted acid sites, which are active sites for NOx reduction in the Cu-chabazite catalyst, but it is unclear where NH4NO3 accumulates on the catalyst. Analyses using catalyst test pieces with different active sites were performed to estimate this accumulation. The results suggested that NH4NO3 accumulation does not depend on the presence of either Cu sites or Brønsted acid sites. Therefore, it is assumed that NH4NO3 can be accumulated everywhere on the catalyst, including on the zeolite framework. This phenomenon was included in the model as formation/accumulation sites S'.

Performance predictions of advanced turbocharged engines are becoming difficult because conventional engine models are built using performance map data of turbochargers with a proportional integral derivative (PID) controller. Improving prediction capabilities under transient test cycles or real driving conditions is a challenging task. This study applies a machine learning technique to predict turbocharger performances with high accuracy under steady-state and transient conditions. The manipulated signals of engine speed and torque created based on Compressed High-Intensity Radiated Pulse (Chirp signal) and Amplitude-modulated Pseudo-Random Binary Signal (APRBS) are used as inputs to the engine testbed. Data from the engine experiments are used as training data for the AI-based turbocharger model. High prediction accuracy of the AI turbocharger model is achieved with the co-efficient of determination in the model, and cross-validation results are higher than 0.8.

Three-way catalyst (TWC) converters can purify harmful substances, such as carbon monoxide, nitrogen oxides, and hydrocarbons, from the exhaust gases of gasoline engines. However, large amounts of these substances may be emitted before the TWC reaches its light-off temperature during cold starts, and its performance may be impaired by thermal deterioration during high-load driving. In this work, a simulation model was developed using axisuite commercial software by Exothermia S.A to predict the light-off conversion performance of Pd/CeO2-ZrO2-Al2O3 catalysts with different degrees of thermal deterioration. The model considered detailed surface reactions and the main factor of the deterioration mechanism. In the detailed reaction mechanism, adsorption, desorption, and surface reactions of each gas species at active sites of the platinum group metal (PGM) particles were considered based on the Langmuir-Hinshelwood mechanism.

In this study, reaction path analysis and modeling of NOx reduction phenomena by selective catalytic reduction (SCR) with NH3 over a Cu-chabazite catalyst were conducted considering changes in the valence state of Cu sites and local structure due to differences in ligands to the Cu sites. The analysis showed that in the Cu-chabazite catalyst, NOx was mainly reduced by adsorbed NH3 on divalent Cu sites accompanied by a change in valence state of Cu from divalent to monovalent. It is known that the activation energy of NOx reduction on a Cu-chabazite catalyst changes between low temperatures ≤ 200 °C and mid to high temperatures ≥ 300 °C. To express this phenomenon, a reversible hydrolysis reaction based on the difference in coordination state of hydroxyl groups (OH−) to Cu sites at low and high temperatures was introduced into the model.

We have proposed the engine featuring a new compressive combustion principle based on pulsed supermulti-jets colliding through a focusing process in which the jets are injected from the chamber walls to the chamber center. This principle has the potential for achieving relatively silent high compression around the chamber center because autoignition occurs far from the chamber walls and also for stabilizing ignition due to this plug-less approach without heat loss on mechanical plugs including compulsory plasma ignition systems. Then, burned high temperature gas is encased by nearly complete air insulation, because the compressive flow shrinking in focusing process gets over expansion flow generated by combustion.

To identify ways of achieving good mixture formation and heat release in diesel spray combustion, we have performed Large Eddy Simulation (LES) using a detailed chemical reaction mechanism to study the temporal and spatial distribution of the local equivalence ratios and heat release rate. Here we characterize the effect of the fuel injection rate profile on these processes in the combustion chamber of a diesel engine. Two injection rate profiles are considered: a standard (STD) profile, which is a typical modern common rail injection profile, and the inverse delta (IVD) profile, which has the potential to suppress rich mixture formation in the spray tip region. Experimental data indicate that the formation of such mixtures may extend the duration of the late combustion period and thus reduce thermal efficiency.

The authors have previously proposed a plume ignition and combustion concept (i.e., PCC combustion), in which a hydrogen fuel is directly injected to the combustion chamber in the latter half of compression stroke and forms a richer mixture plume. By combusting the plume, both cooling losses and NOx formation are reduced. In this study, thermal efficiency was substantially improved and NOx formation was reduced with PCC combustion by optimizing such characteristics as direction and diameter of the jets in combination with combustion of lean mixture. Output power declined due to the lean mixture, however, was recovered by supercharging while keeping NOx emissions at the same level. Thermal efficiency was further improved by slightly re-optimizing the jet conditions.

A new engine concept based on pulsed supermulti-jets colliding at a small area around the chamber center was proposed in our previous research. It was expected to provide noiseless high compression ratio and nearly-complete air-insulation on chamber walls, leading to high thermal efficiency. In the previous reports, three-dimensional computations for the unsteady compressible Navier-Stokes equation were conducted, which were qualitative because of using regular grid method. This time, we develop a new numerical code in order to quantitatively simulate the compression level caused by the jets colliding with pulse. It is achieved by applying a staggered grid method to improve conservatibity of physical quantities at very high compression in combustion phenomena. Computations at a simple condition were fairly agreed with a theoretical value. Computational results obtained for a complex geometry of an engine by the new code had less error than one with previous codes.

Much effort has been devoted to studies on auto-ignition engines of gasoline including homogeneous-charge combustion ignition engines over 30 years, which will lead to lower exhaust energy loss due to high-compression ratio and less dissipation loss due to throttle-less device. However, the big problem underlying gasoline auto-ignition is knocking phenomenon leading to strong noise and vibration. In order to overcome this problem, we propose the principle of colliding pulsed supermulti-jets. In a prototype engine developed by us, octagonal pulsed supermulti-jets collide and compress the air around the center point of combustion chamber, which leads to a hot spot area far from chamber walls. After generating the hot spot area, the mechanical compression of an asymmetric double piston unit is added in four-stroke operation, which brings auto-ignition of gasoline.

Experimental studies were carried out to investigate the effect of soot deposition on NOx purification phenomena in an ammonia selective catalytic reduction coated diesel particulate filter (SCR/DPF) catalyst. To study soot deposition effects on the chemical reactions and mass transfer, two types of testing device were used. A synthetic gas bench enabling tests to be conducted with temperature and flow rate ranges relevant to real driving conditions was used to investigate the soot influence on reduction of NOx to N2 (DeNOx). A micro-reactor that removed the effect of soot deposition on mass transfer in the catalyst layer was used to analyze chemical reactions on a soot surface and their interaction with the SCR catalyst. A filter test brick of a Cu-zeolite SCR/DPF catalyst and a powder catalyst were used for the synthetic gas bench and micro-reactor tests, respectively. Engine soot was sampled in all the tests.

In our previous papers, a new concept of a compressive combustion engine (Fugine) was proposed based on the collision of pulsed supermulti-jets, which can enclose the burned gas around the chamber center leading to an air-insulation effect and also a lower exhaust gas temperature due to high single-point compression. In order to examine the compression level and air-insulation effect as basic data for application to automobiles, aircraft, and rockets, a prototype engine based on the concept, i.e., a piston-less prototype engine with collision of bi-octagonal pulsed multi-jets from fourteen nozzles, was developed. Some combustion results [Naitoh et al. SAE paper, 2016] were recently reported. However, there was only one measurement of wall temperature and pressure in the previous report. Thus, in this paper, more experimental data for pressures and temperatures on chamber walls and exhaust temperatures, are presented for the prototype engine.

For various densities of gas jets including very light hydrogen and relatively heavy ones, the penetration length and diffusion process of a single high-speed gas fuel jet injected into air are computed by performing a large eddy simulation (LES) with fewer arbitrary constants applied for the unsteady three-dimensional compressible Navier-Stokes equation. In contrast, traditional ensemble models such as the Reynolds-averaged Navier-Stokes (RANS) equation have several arbitrary constants for fitting purposes. The cubic-interpolated pseudo-particle (CIP) method is employed for discretizing the nonlinear terms. Computations of single-component nitrogen and hydrogen jets were done under initial conditions of a fuel tank pressure of gas fuel = 10 MPa and back pressure of air = 3.5 MPa, i.e., the pressure level inside the combustion chamber after piston compression in the engine.

Computational and theoretical analyses for a new type of engine (Fugine), which was proposed by us based on the colliding of pulsed supermulti-jets, indicate a potential for very high thermal efficiencies and also less combustion noise. Three types of prototype engines were developed. One of them has a low-cost gasoline injector installed in the suction port and a double piston system in which eight octagonal supermulti-jets are injected and collide. Combustion experiments conducted on the prototype gasoline engine show high thermal efficiency comparable to that of diesel engines and less combustion noise comparable to that of traditional spark-ignition gasoline engines. This paper presents some combustion experiments of one of the other piston-less prototype engines having bi-octagonal pulsed multi-jets injected from fourteen nozzles.

A single-point autoignition gasoline engine (Fugine) proposed by us previously has a strongly asymmetric double piston unit without poppet valves, in which pulsed multi-jets injected from eight suction nozzles collide around the combustion chamber center. Combustion experiments conducted on this engine at a low operating speed of 2000 rpm using gasoline as the test fuel under lean burn conditions showed both high thermal efficiency comparable to that of diesel engines and silent combustion comparable to that of conventional spark-ignition gasoline engines. This gasoline engine was tested with a weak level of point compression generated by negative pressure of about 0.04 MPa and also at an additional mechanical homogeneous compression ratio of about 8:1 without throttle valves. After single-point autoignition, turbulent flame propagation may occur at the later stage of heat release.

In recent years, a new type of engine (Fugine) based on the colliding of pulsed supermulti-jets was proposed by us, which indicates the potential for attaining very high thermal efficiencies and also less combustion noise. A prototype engine with eight nozzles for injecting octagonal pulsed supermulti-jets, which was developed with a low-cost gasoline injector and a double piston system, showed high thermal efficiency comparable to that of diesel engines and also less combustion noise comparable to that of traditional spark-ignition gasoline engines. Another type of prototype piston-less engine having fourteen bioctagonal nozzles was also developed and test results confirmed the occurrence of combustion, albeit it was unstable. In this work, time histories of pressure were measured in the combustion chamber of the piston-less prototype engine under a cold flow condition without combustion in order to examine the compression level obtained with the colliding supermulti-jets.

A new engine concept (Fugine) based on colliding pulsed supermulti-jets was proposed in recent years, which is expected to provide high thermal efficiencies over 50% and less combustion noise. Theoretical analyses indicate a high potential for thermal efficiency over 60%. Three types of prototype engines have been developed. The first prototype engine based only on the colliding of pulsed supermulti-jets with fourteen nozzles has no piston compression, while the second type equipped with a low-cost gasoline injector in the suction port has a double piston system and eight jet nozzles. Combustion experiments conducted on the second prototype gasoline engine show high thermal efficiency similar to that of traditional diesel engines and lower combustion noise comparable to that of traditional spark-ignition gasoline engines.