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Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The use of butanol as an alternative biofuel blend component for conventional diesel fuel has been under extensive investigation. However, some fuel properties such as cetane number and lubricity fall below the accepted values as described by the ASTM D 975 diesel specifications. Blending 10% butanol with #2 ULSD decreases the cetane number by 7% (from 41.6 to 39.0). At higher butanol blend levels, i.e., 20% v/v, the cetane number decrease cannot be compensated for; even with the addition of a 2000 ppm level commercial cetane improver. The decreased cetane number, or in other words, increased ignition delay, can be attributed to the increased blend level of low cetane butanol as well as the critical physical properties for better atomization of fuels during auto ignition such as viscosity. The kinematic viscosity dropped sharply with increasing butanol blend level up to 25 % v/v, then increased with further increase of butanol blend level.