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Urea-based selective catalytic reduction (SCR) of nitric oxides (NOx) is a key technology for heavy-duty diesel engines to achieve the increasingly stringent NOx emission standards. The aqueous urea injection control is critical for urea-SCR systems in order to achieve high NOx conversion efficiency while restricting the tailpipe ammonia (NH3) slip. For Euro VI emission regulation, an advanced control strategy is essential for SCR systems since its NOx emission limits are tighter and test procedure are more stringent compared to Euro IV and Euro V. The complex chemical kinetics of the SCR process has motivated model-based control design approaches. However, the model is too complex to allow real-time implementation. Therefore, it is very important to have a reduced order model for SCR control system.

Urea selective catalytic reduction (SCR) is a key technology for heavy-duty diesel engines to meet the increasingly stringent nitric oxides (NOx) emission limits of regulations. The urea water solution injection control is critical for urea SCR systems to achieve high NOx conversion efficiency while keeping the ammonia (NH3) slip at a required level. In general, an open loop control strategy is sufficient for SCR systems to satisfy Euro IV and Euro V NOx emission limits. However, for Euro VI emission regulation, advanced control strategy is essential for SCR systems due to its more tightened NOx emission limit and more severe test procedure compared to Euro IV and Euro V. This work proposed an approach to achieve model based closed loop control for SCR systems to meet the Euro VI NOx emission limits. A chemical kinetic model of the SCR catalyst was established and validated to estimate the ammonia storage in the SCR catalyst.