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The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-17 (since November 2, 2000, through October 23, 2008). The water supply sources and structure, consumption and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station's water supply hardware with a system for water reclamation from urine SRV-U is emphasized. The prospects of regenerative water supply system development are considered.

An EMU water processing kit (Airlock Coolant Loop Recovery – A/L CLR) was developed as a corrective action to Extravehicular Mobility Unit (EMU) coolant flow disruptions experienced on the International Space Station (ISS) in May of 2004 and thereafter. Conservative schedules for A/L CLR use and component life were initially developed and implemented based on prior analysis results and analytical modeling. The examination of post-flight samples and EMU hardware in November of 2006 indicated that the A/L CLR kits were functioning well and had excess capacity that would allow a relaxation of the initially conservative schedules of use and component life. A relaxed use schedule and list of component lives were implemented thereafter. Since the adoption of the relaxed A/L CLR schedules of use and component lives, several A/L CLR kit items, transport loop water samples and sensitive EMU transport loop components have been examined to gage the impact of the relaxed requirements.

Based on experience obtained in operation of the water and oxygen recovery systems installed onboard the Russian space stations Salut, Mir and the International Space Station ISS, data on the water and oxygen balance for a space station are presented as well as operational parameters and performance data of the systems. Using the data obtained design analysis of an integrated life support system for water and oxygen recovery based on physical/chemical means to be installed on a promising space station is carried out. Mandatory verification tests of new process (technologies) and recovery systems are to be conducted on ISS.

The paper summarizes the experience gained on the ISS water management system during the missions of ISS-1 through ISS-16 (since November 2 2000, through December 31, 2007). The water supply sources and structure, consumption and supply balance at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on a board the ISS and the need to supplement the station's water supply hardware with a system for water reclamation from urine, water from a carbon dioxide reduction system and hygiene water is shown.

Following the Columbia accident, the EMUs (Extravehicular Mobility Units) onboard the ISS (International Space Station) went unused for an extended period of time. Upon startup, the units experienced a failure in the coolant systems. The failure resulted in a loss of EVA (Extravehicular Activity) capability from the US segment of the ISS. A failure investigation determined that chemical and biological contaminants and byproducts from the ISS Airlock Heat Exchanger, and the EMU itself, fouled the magnetically coupled pump in the EMU Transport Loop Fan/Pump Separator leading to a lack of coolant flow. Remediation hardware (the Airlock Coolant Loop Remediation water processing kit) and a process to periodically clean the EMU coolant loops on orbit were devised and implemented. The intent of this paper is to report on the successful implementation of the resultant hardware and process, and to highlight the go-forward plan.

We are developing a drinking water test kit based on colorimetric-solid phase extraction (C-SPE) for use onboard the International Space Station (ISS) and on future Lunar and/or Mars missions. C-SPE involves measuring the change in diffuse reflectance of indicator disks following their exposure to a water sample. We previously demonstrated the effectiveness of C-SPE in measuring iodine in microgravity. This analytical method has now been extended to encompass the measurement of total I (i.e., iodine, iodide, and triiodide). This objective was accomplished by introducing an oxidizing agent to convert iodide and triiodide to iodine, which is then measured using the indicator disks previously developed for iodine. We report here the results of a recent series of C-9 microgravity tests of this method. The results demonstrate that C-SPE technology is poised to meet the total I monitoring requirements of the international space program.

Phase separation is one of the most significant obstacles encountered during the development of analytical methods for water quality monitoring in spacecraft environments. Removing air bubbles from water samples prior to analysis is a routine task on earth; however, in the absence of gravity, this routine task becomes extremely difficult. This paper details the development and initial ground testing of liquid metering centrifuge sticks (LMCS), devices designed to collect and meter a known volume of bubble-free water in microgravity. The LMCS uses centrifugal force to eliminate entrapped air and reproducibly meter liquid sample volumes for analysis with Colorimetric Solid Phase Extraction (C-SPE). Previous flight experiments conducted in microgravity conditions aboard the NASA KC-135 aircraft demonstrated that the inability to collect and meter a known volume of water using a syringe was a limiting factor in the accuracy of C-SPE measurements.

Colorimetric-solid phase extraction (C-SPE) is being developed as a method for in-flight monitoring of spacecraft water quality. C-SPE is based on measuring the change in the diffuse reflectance spectrum of indicator disks following exposure to a water sample. Previous microgravity testing has shown that air bubbles suspended in water samples can cause uncertainty in the volume of liquid passed through the disks, leading to errors in the determination of water quality parameter concentrations. We report here the results of a recent series of C-9 microgravity experiments designed to evaluate manual manipulation as a means to collect bubble-free water samples of specified volumes from water sample bags containing up to 47% air. The effectiveness of manual manipulation was verified by comparing the results from C-SPE analyses of silver(I) and iodine performed in-flight using samples collected and debubbled in microgravity to those performed on-ground using bubble-free samples.

The paper summarizes the six years' experience gained with the ISS water management system during the missions ISS-1 through ISS-14 (since November 2, 2000 through October 31, 2006). The water supply sources, consumption structure and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery during space missions and the prospects of regenerative water supply of an interplanetary space station are discussed. The aim of this paper is to summarize the water supply experience and to provide recommendations for a perspective water supply integrated system based on water recovery.

The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-11 (since November 2 2000, through October 10, 2005). The water supply sources and structure, consumption and supply balance at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station’s water supply hardware with a system for water reclamation from urine SRV-U is shown. The prospects of regenerative water supply system development are considered.

Following the Colombia accident, the Extravehicular Mobility Units (EMU) onboard ISS were unused for several months. Upon startup, the units experienced a failure in the coolant system. This failure resulted in the loss of Extravehicular Activity (EVA) capability from the US segment of ISS. With limited on-orbit evidence, a team of chemists, engineers, metallurgists, and microbiologists were able to identify the cause of the failure and develop recovery hardware and procedures. As a result of this work, the ISS crew regained the capability to perform EVAs from the US segment of the ISS Figure 1.

The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-10 (since November 2 2000, through November 30, 2004). The water supply sources and structure, consumption and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station’s water supply hardware with a system for water reclamation from urine SRV-U is emphasized. The prospects of regenerative water supply system development are considered.

The need to preserve crew health during space missions, combined with the level of demand on both crew time and cargo space, dictates the development of fast, facile methods capable of monitoring trace quantities of several analytes in spacecraft water. This presentation describes our efforts to address this need by using Multiplexed Colorimetric Solid Phase Extraction (MC-SPE). MC-SPE is a sorption-spectrophotometric platform based upon the extraction of analytes onto membranes impregnated with selective colorimetric agents. Quantification is accomplished using Kubelka-Munk values calculated from the diffuse reflectance spectrum of the complex on the surface of the membrane and calibration curves. In traditional C-SPE, concentration factors of up to 1000 can be realized for a single analysis, yielding low detection limits (ppb – ppm range) with a total analysis time of 75–90 s. Herein, we describe the performance and continued refinement of the MC-SPE platform.

We are developing a spacecraft water quality monitoring system based on measuring the change in diffuse reflectance of indicator disks following exposure to a water sample. The most widely used approach for deriving quantitative information from a diffuse reflectance spectrum involves an initial Kubelka-Munk transformation of the reflectance data. Provided the assumptions underlying the transformation are satisfied, the magnitude of the resulting function varies linearly with analyte concentration. We measure diffuse reflectance spectra using a commercial-off-the-shelf handheld spectrophotometer designed for color matching applications. Spectra are currently downloaded and transformed to obtain the value of the Kubelka-Munk function at a detection wavelength diagnostic of the analyte. This value is then used to quantify the analyte via a standard response curve.

The paper deals with the performance data of the service module Zvezda integrated water supply system of the International Space Station (ISS) as of March 31, 2004. The water supply and demand balance are analyzed. It is shown that water recovery from humidity condensate has been especially important when water delivery by Space Shuttles was terminated. The SRV-K contribution in potable water supply for crew needs was up to 76%. The data of humidity condensate and recovered water compositions are reviewed. The effective cooperation of the international partners on part of life support is shown. Water recovery future prospects are discussed.

Archived water samples collected on the International Space Station (ISS) and returned to Earth for analysis have, in a few instances, contained trace levels of heavy metals. Building on our previous advances using Colorimetric Solid Phase Extraction (C-SPE) as a biocide monitoring technique [1, 2], we are devising methods for the low level monitoring of nickel(II), lead(II) and other heavy metals. C-SPE is a sorption-spectrophotometric platform based on the extraction of analytes onto a membrane impregnated with a colorimetric reagent that are then quantified on the surface of the membrane using a diffuse reflectance spectrophotometer. Along these lines, we have analyzed nickel(II) via complexation with dimethylglyoxime (DMG) and begun to examine the analysis of lead(II) by its reaction with 2,5-dimercapto-1, 3, 4-thiadiazole (DMTD) and 4-(2-pyridylazo)-resorcinol (PAR).

A sorption-spectrophotometric platform for the concentration and subsequent quantification of biocides in spacecraft drinking water is described. This methodology, termed Colorimetric Solid Phase Extraction (C-SPE), is based on the extraction of analytes onto a membrane impregnated with a colorimetric reagent. Quantification of the extracted analytes is accomplished by interrogating the surface of the membrane with a commercially available diffuse reflectance spectrophotometer. Ground-based experiments have shown that C-SPE is a viable means to determine biocide concentrations in the range commonly found in water samples from the Space Shuttle and the International Space Station (ISS). This paper details efforts to advance C-SPE closer to space flight qualification and ISS implementation, starting with the modification of the ground based biocide detection platform to simplify operation in a microgravity environment.

The paper deals with the performance data of the service module Zvezda water supply and urine collection systems of the International Space Station (ISS) as of December 31, 2002. The water supply and demand balance are analyzed. The data of humidity condensate and recovered water compositions are reviewed. The effective cooperation of the international partners on part of life support is shown.

The paper deals with the construction and performance data of the service module Zvezda water and oxygen supply systems of the International Space Station (ISS). The performance data at the first 14 months of manned station functioning are provided. The data of humidity condensate and recovered water compositions are reviewed. The water supply and demand balance are analyzed. The system of oxygen generation “Electron-VM” and its functioning results are reviewed. The effective cooperation of the international partners on part of life support is shown.

The paper deals with the construction and performance data of the service module Zvezda water supply system of the International Space Station (ISS). The performance data at an initial phase of manned station functioning are provided. The data on humidity condensate and recovered water composition are reviewed. The water supply and demand balance are analyzed. The effective cooperation of international partners on part of water supply for the crew is shown.