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Di-ethyl ether (DEE) belongs to the family of oxygenated fuels, which have been investigated as an alternative to conventional diesel. However, increasing the proportion of DEE in DEE-diesel blends changes its physicochemical properties. This work shows the non-evaporating and non-reacting spray characteristics of diesel, DEE20 (20% v/v DEE and 80% v/v diesel), and DEE40 (40% v/v DEE and 60% v/v diesel) were investigated. The effect of fuel injection pressure (FIP: 500 and 800 bar) on the spray morphology and droplet size distribution at different axial locations along the spray axis was done. FIP of 800 bar showed a reduction in Sauter mean diameter (SMD) of spray droplets with increasing axial distance due to improved spray atomisation because of the drag forces of the surrounding air on the fuel droplets. DEE20 showed a higher number of droplets having a smaller diameter than DEE40. DEE20 and DEE40 showed superior spray atomisation characteristics than diesel.

The rising concerns of emissions have put enormous strain on the automotive industry. Industry is, therefore looking for next-generation engines and advanced combustion technologies with ultra-low emissions and high efficiency. To achieve this, more insights into the combustion and pollutant formation processes in IC engines is required. Since conventional measures have not been insightful, in-situ measurement of combustion and pollution formation through optical diagnostics is being explored. Gaining full optical access into the diesel engine combustion chamber is a challenging task. The late-compression flow dynamics is not well understood due to limited access into the engine combustion chamber. These flow structures contribute immensely to fuel-air mixing and combustion. The objective of this study is to understand the role of combustion chamber design on vertical plane air-flow structures.

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

In this study, macroscopic spray characteristics of Waste cooking oil (WCO), Jatropha oil, Karanja oil based biodiesels and baseline diesel were compared under simulated engine operating condition in a constant volume spray chamber (CVSC). The high pressure and high temperature ambient conditions of a typical diesel engine were simulated in the CVSC by performing pre-ignition before the fuel injection. The spray imaging was conducted under absence of oxygen in order to prevent the fuels from igniting. The ambient pressure and temperature for non-evaporating condition were 3 MPa and 300 K. Meanwhile, the spray tests were performed under the ambient pressure and temperature of 4.17 MPa and 804 K under evaporating condition. The fuels were injected by a common-rail injection system with injection pressure of 80 MPa. High speed Mie-scattering technique was employed to visualize the evaporating sprays.

Biodiesel made from Jatropha oil by transesterification process has viscosity and other important physical properties comparable to mineral diesel hence it can be used as an alternate fuel in conventional diesel engines. It is important to investigate the spray characteristics of biodiesel because emissions from the engines are dependent on fuel atomization process and resulting fuel-air mixing. This study focuses on the Jatropha biodiesel spray investigations using Phase Doppler Interferometry (PDI) for measurement of various microscopic spray parameters such as Sauter mean diameter (SMD) and spray droplet size and velocity distributions. The spray and engine experiments were carried out for Jatropha biodiesel (JB100) and their 20% blends (JB20) with mineral diesel as baseline. Fuel injection pressure during the spray experiments was maintained at 200 bars for all tests, quite similar to small horse power agricultural engines, and the fuel injection quantity was varied.

Fuel injection pressure (FIP) is one of the most important factors affecting diesel engine performance and particulate emissions. Higher FIP improves the fuel atomization, which results in lower soot formation due to superior fuel-air mixing. The objective of this spray study was to investigate macroscopic and microscopic spray parameters in FIP range of 500-1500 bar, using a solenoid injector for biodiesel blends (KB20 and KB40) and baseline mineral diesel. For these test fuels, effect of ambient pressure on macroscopic spray characteristics such as spray penetration, spray area and cone angle were investigated in a constant volume spray chamber (CVSC). Microscopic spray characteristics such as velocity distribution of droplets and spray droplet size distribution were measured in the CVSC at atmospheric pressure using Phase Doppler Interferometry (PDI).

Diesel particulates are mainly composed of elemental carbon (EC) and organic carbon (OC) with traces of metals, sulfates and ash content. Organic fraction of the particulate are considered responsible for its carcinogenic effects. Diesel oxidation catalyst (DOC) is an important after-treatment device for reduction of organic fraction of particulates. In this study, two non-noble metal based DOCs (with different configurations) were prepared and evaluated for their performance. Lanthanum based perovskite (LaMnO3) catalyst was used for the preparation of DOCs. One of the DOC was coated with support material ceria (5%, w/w), while the other was coated without any support material. Prepared DOCs were retrofitted in a four cylinder water cooled diesel engine. Various emission parameters such as particulate mass, particle number-size distribution, regulated and unregulated emissions, EC/OC etc., were measured and compared with the raw exhaust gas emissions from the prepared DOCs.

Fuel-air mixing is the main parameter, which affects formation of NOx and PM during CI combustion. Hence better understanding of air-flow characteristics inside the combustion chamber of a diesel engine became very important. In this study, in-cylinder air-flow characteristics of four-valve diesel engine were investigated using time-resolved high-speed tomographic Particle Imaging Velocimetry (PIV). For visualization of air-flow pattern, fine graphite particles were used for flow seeding. To investigate the effect of different operating parameters, experiments were performed at different engine speeds (1200 rpm and 1500 rpm), intake air temperatures (room temperature and 50°C) and intake port configurations (swirl port, tangential port and combined port). Intake air temperature was controlled by a closed loop temperature controller and intake ports were deactivated by using a customized aluminum gasket.

Better understanding of flow phenomena inside the combustion chamber of a diesel engine and accurate measurement of flow parameters is necessary for engine optimization i.e. enhancing power output, fuel economy improvement and emissions control. Airflow structures developed inside the engine combustion chamber significantly influence the air-fuel mixing. In this study, in-cylinder air flow characteristics of a motored, four-valve diesel engine were investigated using time-resolved high-speed Tomographic Particle Imaging Velocimetry (PIV). Single cylinder optical engine provides full optical access of combustion chamber through a transparent cylinder and flat transparent piston top. Experiments were performed in different vertical planes at different engine speeds during the intake and compression stroke under motoring condition. For visualization of air flow pattern, graphite particles were used for flow seeding.

Use of biodiesel from non-edible vegetable oil as an alternative fuel to mineral diesel is attractive economically and environmentally. Diesel engines emit several harmful gaseous emissions and some of them are regulated worldwide, while countless others are not regulated. These unregulated species are associated with severe health hazards. Karanja biodiesel is a popular alternate fuel in South Asia and various governments are considering its large-scale implementation. Therefore it is important to study the possible adverse impact of this new alternate fuel. In this study, unregulated and regulated emissions were measured at varying engine speeds (1500, 2500 and 3500 rpm) for various engine loads (0%, 20%, 40%, 60%, 80% and 100% rated load) using 20% Karanja biodiesel blend (KB20) and diesel in a 4-cylinder 2.2L common rail direct injection (CRDI) sports utility vehicle (SUV) engine.

High viscosity of vegetable oil causes ignition problems when used in compression ignition engines. There is a need to reduce the viscosity before using it as engine fuel. Preheating and pre-treating of vegetable oils using waste heat of exhaust gases is one of the techniques, which reduces the viscosity and makes it possible to use it as alternate fuel for some niche applications, without requiring major modifications in the engine hardware. Several applications such as decentralized power generation, agricultural engines, and water pumping engines, can use vegetable oils as an alternative fuel. In present investigation, performance, combustion, and emission characteristics of an engine using preheated 20% blend of Jatropha oil with mineral diesel (J20) has been evaluated at a constant speed (1500 rpm) in a single cylinder four stroke direct injection diesel engine.

Use of alternative fuels, and reduction of particulate and NOx emissions are major challenges for making diesel engines environmentally benign. Measures adopted for reducing gravimetric particulate emissions necessarily always do not reduce particulate number concentration, which is strongly related with adverse health effects. Current emission norms in some parts of the world limit particulate number concentration along with particulate mass. In this scenario, it becomes important to investigate effect of fuel injection parameters and fuel injection strategies such as pilot injections on particulate size-number distribution. A single cylinder research engine is used to evaluate the effect of different fuel injection strategies and injection timings (for pilot and main injections) on particulate size-number distribution and total particulate numbers.

Homogeneous charge compression ignition (HCCI) is an advanced combustion concept that is developed as an alternative to diesel engines with higher thermal efficiency along with ultralow NOx and PM emissions. To study the performance of this novel technique, experiments were performed in a two cylinder engine, in which one cylinder is modified to operate in HCCI mode while other cylinder operates in conventional CI mode. The quality of homogeneous mixture of air and fuel is the key feature of HCCI combustion. Low volatility of diesel is a major hurdle in achieving HCCI combustion because it is difficult to make a homogeneous mixture of air and fuel. This problem is resolved by external mixture preparation technique in uses a dedicated diesel vaporizer with an electronic control system. All the injection parameters such as fuel quantity, fuel injection timing, injection delay etc., are controlled by the injection driver circuit.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

Diesel engines are very efficient prime movers in their power range. Fuel is directly injected into the combustion chamber. Performance and emission characteristics of diesel engines are highly influenced by the fuel spray parameters and atomization of the injected fuel. As the emission regulations become stringent, it is very important to optimize the combustion in internal combustion engines for different fuels including alternative fuels. Spray visualization using optical techniques play a very important role to analyze macroscopic spray parameters and fuel atomization behavior. In the present experimental study, an important alternative CI engine fuel, Karanja oil and its blends with diesel have been investigated for their spray parameters and fuel atomization relative to mineral diesel. These parameters are different for the two fuels because of difference in the viscosity and density of the fuels.

New combustion concepts developed in internal combustion engines such as homogeneous charge compression ignition (HCCI) have attracted serious attention due to the possibilities to simultaneously achieve higher efficiency and lower emissions, which will impact the environment positively. The HCCI combustion concept has potential of ultra-low NOX and particulate matter (PM) emission in comparison to a conventional gasoline or a diesel engine. Environmental Legislation Agencies are becoming increasingly concerned with particulate emissions from engines because the health and environmental effects of particulates emitted are now known and can be measured by sophisticated instruments. Particulate emissions from HCCI engines have been usually considered negligible, and the measurement of mass emission of PM from HCCI combustion systems shows their negligible contribution to PM mass. However some recent studies suggest that PM emissions from HCCI engines cannot be neglected.

Poor oxidation stability is the central problem associated with the commercial acceptance of the biodiesel. The EU standard (EN14214) specifies a minimum value of 6 h for biodiesel induction period at 110°C, measured with Rancimat instrument. Most of the freshly prepared biodiesel generally have lower induction periods than prescribed by the standards. Anti-oxidants are therefore added to enhance the oxidation/ storage stability of biodiesel. Oxidation is an exothermic process, and the reaction heat evolved makes it possible to use thermo gravimetric analysis (TGA). In the present study, the oxidation stability of methyl esters derived from Karanja oil and Neem oil, stabilized with anti-oxidant pyrogalol (PY) was studied by DSC. Onset temperature of freshly prepared Karanja biodiesel (KOME) and Neem biodiesel (NOME) was observed to be 148 and 153°C respectively. The stability increases with increasing anti-oxidant dosage.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

The world energy demand has witnessed uncertainties in two dimensions. The scarcity and depletion of conventional petroleum sources are causes of great concern worldwide. Combustion of fossil fuels has led to unprecedented rise in the global CO2 level, leading to global warming. Therefore, efforts are underway in several countries to search for suitable alternative fuels that are environment friendly. Vegetable oils of non-edible nature are such alternative fuels, which can form part of potential solution. Vegetable oils, due to their agricultural origin, are able to reduce CO2 emissions to the atmosphere along with import substitution of petroleum products In the present research, experiment were designed to study the effect of reducing Neem oil's high viscosity by increasing the fuel temperature and thereby its effect on combustion and emission characteristics of the engine.

Environmental concerns have increased significantly world over in the past decade. Regulatory agencies are becoming increasingly concerned with particulate emissions as the health and environmental effects are getting understood better due to rapid development in instrumentation. Biodiesel is one of the most promising alternative diesel fuels, which is getting global acceptability among the automotive/ engine manufactures as well as users due to numerous benefits it offers over the conventional diesel. While much of literature is available on particulate emitted by diesel fuelled engine, little is known by particulate emissions from biodiesel fuelled compression ignition (CI) engine. This study concentrates on the characterization of particulate emissions from mineral diesel vis-à-vis biodiesel (B100) and its optimum blend (20%, B20) with mineral diesel.