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In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

The growing concern about Greenhouse Gas (GHG) emissions led institutions to further reduce the limits on vehicle-related CO2 emissions. Therefore, car manufacturers are developing vehicles with low environmental impact, like Hybrid-Electric Vehicles (HEVs), which in the series architecture employ an Internal Combustion Engine (ICE) coupled with an electric generator for battery recharging, thus extending the range of a Battery Electric Vehicle (BEV). For this kind of application, small four-stroke Spark Ignition (SI) engines are preferred, as they are a proven and reliable solution to increase the driving range with very low environmental impact. In series hybrid-electric powertrains, the ICE is decoupled from the drive wheels, then it can operate in a steady-state high-efficiency working point, regardless of the power required by the mission profile. The benefits of lean combustion can be exploited to increase efficiency and reduce CO2 and NOx emissions.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

Hydrogen is an energy vector with low environmental impact and will play a significant role in the future of transportation. Converting a spark ignition (SI) engine powered vehicle to H2 fueling has several challenges, but was overall found to be feasible with contained cost. Fuel delivery directly to the cylinder features numerous advantages and can successfully mitigate backfire, a major issue for H2 SI engines. Within this context, the present work investigated the specific fuel system requirements in port- (PFI) and direct-injection (DI) configurations. A 0D/1D model was used to simulate engine operating characteristics in several working conditions. As expected, the model predicted significant improvement of volumetric efficiency for DI compared to the PFI configuration. Boosting requirements were predicted to be at levels quite close to those for gasoline fueling.

In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Hybrid electric vehicles are a suitable solution for the transition from fossil fuels-based transportation to electric mobility. They have the benefits of zero-emissions operation when only the electric engine is used preventing the typical range anxiety of full-electric vehicles. Also, they can have a low battery pack capacity and weight thanks to the continuous recharge from the internal combustion engine that becomes the only responsible for exhaust emissions. A practical solution to limit the combustion engine emissions is represented by the range extender configuration, where the engine works at a fixed operating point with the highest efficiency serving uniquely as a battery charger. In the face of the current world situation and future changes, research for alternative energy sources is crucial. Hydrogen can be used as an alternative fuel for common internal combustion engines; moreover, it has the great advantage of high efficiency (about 44%).

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

The application of an alternative fuel such as hydrogen to internal combustion engines is proving to be an effective and flexible solution for reducing fuel consumption and polluting emissions from engines. An easy to use and immediate application solution is the dual fuel (DF) technology. It has the potential to offer significant improvements in carbon dioxide emissions from light compression ignition engines. The dual fuel concept (natural gas / diesel or hydrogen / diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Nowadays, the stricter regulations in terms of emissions have limited the use of diesel engines on urban roads. On the contrary, for marine and off-road applications the diesel engine still represents the most feasible solution for work production. In the last decades, dual fuel operation with methane supply has been widely investigated. Starting from previous studies on a research engine, where diesel-methane dual fuel combustion has been deepened both experimentally and numerically with the aid of a CFD code, the authors implemented and tested a kinetic mechanism. It is obtained from the combination of the well-established GRIMECH 3.0 and a detailed scheme for a diesel surrogate oxidation. Moreover, the Autoignition-Induced Flame Propagation model, included in the ANSYS Forte® software, is applied because it can be considered the most appropriate model to describe dual fuel combustion.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

Improvement of performance and emission of future internal combustion engine for passenger cars is mandatory during the transition period toward their substitution with electric propulsion systems. In middle time, direct injection spark ignition (DISI) engines could offer a good compromise between fuel economy and exhaust emissions. However, abnormal combustion and particularly knock and super-knock are some of the most important obstacles to the improvement of SI engines efficiency. Although knock has been studied for many years and its basic characteristics are clear, phenomena involved in its occurrence are very complex and are still worth of investigation. In particular, the definition of an absolute knock intensity and the precise determination of the knock onset are arduous and many indexes and methodologies has been proposed. In this work, most used methods for knock onset detection from in- cylinder pressure signal have been considered.

The permanent aim of the automotive industry is the further improvement of the engine efficiency and the simultaneous pollutant emissions reduction. The aim of the study was the optimization of the gasoline combustion by means of a passive prechamber. This analysis allowed the improvement of the engine efficiency in lean-burn operation condition too. The investigation was carried out in a commercial small Spark Ignition (SI) engine fueled with gasoline and equipped with a proper designed passive prechamber. It was analyzed the effects of the prechamber on engine performance, Indicated Mean Effective Pressure, Heat Release Rate and Fuel Consumption were used. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed. Emissions samples were taken from the exhaust flow, just downstream of the valves. Four different engine speeds were investigated, namely 2000, 3000, 4000 and 5000 rpm.

The current legislation does not take into account the limitation of sub 23 nm particles from engine. Nevertheless, the Common Rail Diesel engine emits a large number of nanoparticle, solid and volatiles, that are very dangerous for human health. In this contest, the challenge of the “dieper EU project” is to apply advanced technologies for exhaust after-treatment to existing diesel engines and to optimize the characteristics of a new generation of engines with regards to emissions, fuel consumption and drivability. Aim of the present paper is to provide useful information for the development of the after-treatment system that will have to fulfill Euro6 further steps. In order to characterize the chemical and physical nature of Particulate Matter emitted from Euro 6b Medium Duty diesel engine, the pollutants were collected and analyzed: from engine-out, downstream of the particulate filter (DPF), and at the exit of a selective catalytic reactor (SCR).

The growing concerns on the emission of particles smaller than 23 nm, which are harmful to human health, lead to the necessity of introducing a regulation for these particles not yet included in the current emission standards. Considering that measurements of concentration of sub-23 nm particles are particularly sensitive to the sampling conditions, it is important to identify an effective assessment procedure. Aim of this paper is the characterization of the effect of the sampling conditions on sub-23 nm particles, emitted by PFI (port fuel injection) and DI (direct injection) spark ignition engines fueled with gasoline, ethanol and a mixture of ethanol and gasoline (E30). The experimental activity was carried out on a 250 cm3 displacement four stroke GDI and PFI single cylinder engines. The tests were conducted at 2000 rpm and 4000 rpm full load, representative of the homologation urban driving cycle.

The constant aim of the automotive industry is the further improvement of engine efficiency and the simultaneous reduction of the exhaust emissions. In order to optimize the internal combustion engines it is necessary to further improve the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. In this context, the application of optical diagnostic techniques permits a deep insight into the fundamental processes such as flow development, fuel injection, and combustion process. In this paper the analysis of the combustion process of gaseous fuel ignited by the plasma jets coming from a prechamber was performed. The investigation was carried out in an optically accessible small Direct Injection Spark-Ignition (DI SI) engine fueled with Methane. The ignition was obtained with a properly designed fueled prechamber prototype.

The application of more efficient compression ignition combustion concepts requires advancement in terms of fuel injection technologies. The injector nozzle is the most critical component of the whole injection system for its impact on the combustion process. It is characterized by the number of holes, diameter, internal shape, and opening angle. The reduction of the nozzle hole diameter seems the simplest way to promote the atomization process but the number of holes must be increased to keep constant the injected fuel mass. This logic has been applied to the development of a new generation of injectors. First, the tendency to increase the nozzle number and to reduce the diameter has led to the replacement of the nozzle with a circular plate. The vertical movement of the needle generates an annulus area for the fuel delivery on 360 degrees, so controlling the atomization as a function of the vertical plate position.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.