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A liquid phase LPG injection (LPLi) system has been considered as one of the next generation fuel supply system, since it has a very strong potential to accomplish the higher power, higher efficiency, and lower emission characteristics than the mixer type that is classified as a second generation technology, whereas the LPLi system is classified as a third generation technology. However, when a liquid LPG fuel is injected into the inlet duct of an engine, a large quantity of heat is extracted due to its high latent heat of evaporation. This leads the moisture in the air to freeze around the nozzle exit, which is called icing phenomenon. It may cause damage to the outlet nozzle of an injector or inlet valve seat. In this work, the experimental investigation of the icing phenomenon was carried out. The results showed that humidity of air rather than the temperature of air in the inlet duct mainly controlled the icing process.

An 11L heavy duty LPG MPI engine has been developed using the liquid phase LPG injection system, which is one of the next generation LPG fueling technologies, since the LPG MPI engine can achieve the higher power and efficiency, and lower exhaust emissions than the conventional mixer type system. Two prototypes - a natural aspiration(NA) engine and a turbocharged inter-cooler(TCI) engine - were developed in this work and tested to measure the performance and emissions. For a NA type engine, in order to achieve the low emissions, the stoichiometric air/fuel ratio was adapted with a three-way catalytic converter. Whereas, for a TCI type, the lean burn technology was introduced to minimize the thermal loading due to an increase of the engine power. The results in this work demonstrated that the LPG MPI engines have the higher engine performance and lower exhaust emissions than the base diesel engine.

An LPG engine for heavy duty vehicles has been developed using liquid phase LPG injection (hereafter LPLI) system, which has regarded as as one of next generation LPG fuel supply systems. In this work the optimized piston cavities were investigated and chosen for an LPLI engine system. While the mass production of piston cavities is considered, three piston cavities were tested: Dog-dish type, bathtub type and top-land-cut bathtub type. From the experiments the bathtub type showed the extension of lean limit while achieving the stable combustion, compared to the dog-dish type at the same injection timing. Throughout CFD analysis, it was revealed that the extension of lean limit was due to an increase of turbulence intensity by the enlarged crevice area, and the enlargement of flame front surface owing to the shape of the bathtub piston cavity compared to that of the dog-dish type.

A LPG engine for heavy duty vehicle has been developed using liquid phase LPG injection (hereafter LPLI) system, which has a strong potential as a next generation LPG fuel supply system. It has been revealed in this work that an LPLI system generates higher power, efficiency, and emits lower emission pollutants than the conventional mixer type system. As a preliminary study on the LPLI system applicable to a heavy duty LPG engine, the engine output and combustion performance were investigated with various operating conditions using a single cylinder engine equipped with the different fuel supply systems. Experimental results showed that no problems occurred and the volumetric efficiency and engine output increased, respectively by about 10%, when the LPLI system is used. A decrease of the intake manifold temperature by the LPLI system has also been observed.

This is a preliminary work for the development of a stratified combustion engine using liquefied petroleum gas(LPG) as an alternative fuel. The main objective of this research is to find out the optimizing engine parameters from the viewpoint of mixture formation with the aid of simulation, where the KIVA_ code was used. The combustion characteristics of LPG and gasoline are different because of their different physical properties. Therefore, the numerical simulation was performed for optimizing engine parameters by changing the piston and cylinder geometry, as well as injection conditions. Result showed that geometry of combustion chamber has a great influence on mixture stratification. Also, weaker swirl seems to be better for mixture formation in the vicinity of the spark plug.

Development of LPG SI and CI engines for heavy duty vehicles has been carried out. In order to measure the performance and emissions of an LPG lean burn SI engine, the piston cavity, swirl ratio, and propane-butane fuel ratio were varied and tested. Compared to the bathtub and dog dish cavities, the nebula type cavity showed the best performance in terms of cyclic variation and combustion duration. High swirl improved combustion by achieving a high thermal efficiency and low NOx emissions. A feasibility study of an LPG DI diesel engine also has been carried out to study the effectiveness of the selected cetane enhancing additives:Di-tertiary-butyl peroxide (DTBP). When more than 5 wt% DTBP was added to the base fuel, stable engine operation over a wide range of engine loads was possible. The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%.

The oxidation mechanism of DTBP (Di-tertiary-butyl peroxide) and its role in butane oxidation have been investigated, as it pertains to the development of an LPG DI diesel engine. Ignition delay contours were analyzed to investigate the role of DTBP (ϕ≈0.2 to the total oxygen) in butane oxidation. At higher pressure and lower temperature regions, it was apparent that the addition of DTBP significantly enhances the ignition delay of butane, whereas at lower pressures and higher temperatures, this effect diminishes. Results of this study showed that the role of DTBP to enhance the ignition delay of the base fuel is through rapid heat release, rather than by radicals produced by decomposition during the base fuel ignition delay. Formaldehyde is a principal species involved in reactions for heat release in the higher pressure lower temperature region, comparable to diesel engine operating conditions.

A feasibility study of an LPG DI diesel engine has been carried out to study the effectiveness of two selected cetane enhancing additives: Di-tertiary-butyl peroxide (DTBP) and 2-Ethylhexyl nitrate (EHN). When more than either 5 wt% DTBP or 3.5 wt% 2EHN was added to the base fuel (100 % butane), stable engine operation over a wide range of engine loads was possible (BMEPs of 0.03 to 0.60 MPa). The thermal efficiency of LPG fueled operation was found to be comparable to diesel fuel operation at DTBP levels over 5 wt%. Exhaust emissions measurements showed that NOx and smoke levels can be significantly reduced using the LPG+DTBP fuel blend compared to a light diesel fuel at the same experimental conditions. Correlations were derived for the measured ignition delay, BMEP, and either DTBP concentration or cetane number. When propane was added to a butane base fuel, the ignition delay became longer.

Flame propagation characteristics, in a heavy-duty type LPG lean burn SI engine, were investigated by simulation methodology, using the global one step and the ten step chemical kinetic reaction mechanisms, respectively. The swirl ratio and equivalence ratio were varied to investigate their effects on flame front speed. The effect of increased swirl intensity on flame speed was very minor at ranges of equivalence ratio of this study. Flame front shape, however, was affected by swirl intensity. Circular flame front formed for a higher swirl ratio, which is in a qualitative accordance with that of measurements. Comparison between calculation and measurements of flame propagation characteristics shows a good agreement for both the global one step and the ten step chemical kinetic model. This work concludes that the reduced chemical kinetic reactions, consisting of ten steps, is useful for flame propagation study in an LPG SI engine.

Band spectrum images for CH, OH and CHO were taken in a heavy duty type LPG lean-burn SI engine, to investigate the combustion process as it pertains to the pollutant formation process in the post flame region. Full spectra and band spectrum flame images were observed with a bottom view single cylinder research engine and two high speed cameras. NOx emissions were also measured for excess air ratios ranging from 1.0 to 1.6. A thermodynamic model, including the detailed chemical kinetic mechanism for LPG and NOx formation reactions, was developed to predict the major reaction species in the post flame region, and NOx emissions during the combustion process. The model qualitatively described the flame images for each band spectrum and could predict the measured NOx emissions very well.

Using an extended bottom view piston having a quartz window, flame propagation observation and flame contour analysis were carried out to investigate the combustion characteristics of a heavy-duty type LPG lean burn engine. The swirl ratio and piston cavity configuration were varied to investigate their effects on combustion and engine performance. Gradual reduction of NOx but increased hydrocarbon emissions were measured for leaner mixtures compared to the stoichiometric operation. High swirl apparently accelerated the initial flame kernel development, as evidenced by a shorter crank angle interval from the spark ignition to the maximum cylinder pressure. The ‘D’ type cavity, with an increased squish area located below the intake valve, was shown to have the shortest burn duration among the piston cavities tested. The experimental flame propagation observation procedure was shown to be useful for the study of the combustion process in engines.

Flame propagation at elevated pressures for propane, butane and autogas (20% propane and 80% butane by mass) were investigated. Flame arrival time was measured using ionization probes installed along the wall of a cylindrical combustion chamber. Flame radius was also measured using a laser schlieren technique. Results showed that the flame front speed decreased with increasing initial pressure, and the initial pressure effect on maximum flame front speed was correlated by the relationship Sf = 175·pi-0.15 (for Φ=1.0). Characteristics of flame front speed between propane, butane and autogas were very similar, whereas at fuel-rich conditions flame front speed of butane and autogas were higher than that of propane. A thermodynamic model to predict flame radius and speed as a function of time was derived and tested using measured pressure-time curves.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).