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NOx emissions from diesel passenger vehicles affect the atmospheric environment. It is difficult to evaluate the NOx emissions influenced by environmental conditions such as humidity and temperature, traffic conditions, driving patterns, etc. In the authors’ previous study, real-driving experiments were performed on city and highway routes using a diesel passenger car with only an exhaust gas recirculation system. A statistical prediction model of NOx emissions was considered for simple estimations in the real world using instantaneous vehicle data measured by the portable emissions measurement system and global positioning system. The prediction model consisted of explanatory variables, such as velocity, acceleration, road gradient, and position of transmission gear. Using the explanatory variables, NOx emissions on the city and highway routes was well predicted using a diesel vehicle without NOx reduction devices.

Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

A mixed time-scale subgrid large eddy simulation was used to simulate mixture formation, combustion and soot formation under the influence of turbulence during diesel engine combustion. To account for the effects of engine wall heat transfer on combustion, the KIVA code's standard wall model was replaced to accommodate more realistic boundary conditions. This were carried out by implementing the non-isothermal wall model of Angelberger et al. with modifications and incorporating the log law from Pope's method to account for the wall surface roughness. Soot and NOx emissions predicted with the new model are compared to experimental data acquired under various EGR conditions.

The objective of this paper is to investigate the potential of lean burn combustion to improve the thermal efficiency of spark ignition engine. Experiments used a single cylinder gasoline spark ignition engine fueled with primary reference fuel of octane number 90, running at 4000 revolution per minute and at wide open throttle. Experiments were conducted at constant fueling rate and in order to lean the mixture, more air is introduced by boosted pressure from stoichiometric mixture to lean limit while maintaining the high output engine torque as possible. Experimental results show that the highest thermal efficiency is obtained at excess air ratio of 1.3 combined with absolute boosted pressure of 117 kPa. Three dimensional computational fluid dynamic simulation with detailed chemical reactions was conducted and compared with results obtained from experiments as based points.

The objective of the present study is to analyze soot formation in diesel engine combustion by using multi-dimensional combustion simulations with a parallelized explicit ODE solver. Parallelized CHEMEQ2 was used to perform detailed chemical kinetics in KIVA-4 code. CHEMEQ2 is an explicit stiff ODE solver developed by Mott et al. which is known to be faster than traditional implicit ODE solvers, e.g., DVODE. In the present study, about eight times faster computation was achieved with CHEMEQ2 compared to DVODE when using a single thread. Further, by parallelizing CHEMEQ2 using OpenMP, the simulations could be run not only on calculation servers but also on desktop machines. The computation time decreases with the number of threads used. The parallelized CHEMEQ2 enabled combustion and emission characteristics, including detailed soot formation processes, to be predicted using KIVA-4 code with detailed chemical kinetics without the need for reducing the reaction mechanism.

As the petroleum depletion, some of this demand will probably have to be met by increasing the production of diesel fuels from heavy oil or unconventional oil in the near future. Such fuels may inevitably have a lower cetane number (CN) with a higher concentration of aromatic components. The objective of the present research is to identify the effects of a typical biodiesel fuel as a CN improver for a light-duty diesel engine for passenger cars. Our previous study indicates that methyl oleate (MO), which is an oxygenated fuel representative of major constituents of many biodiesel types, can reduce soot and NOx emissions simultaneously by optimizing performance under exhaust gas recirculation (EGR) when used as a diesel fuel additive. In addition, it was found that MO tends to reduce the ignition delay. We employed a 2.2 L passenger car DI diesel engine complying with the Euro 4 emissions regulation.

The objective of the present research is to analyze the effects of using oxygenated fuels (FAMEs) on diesel engine combustion and emission (NOx and soot). We studied methyl oleate (MO), which is an oxygenated fuel representative of major constituents of many types of biodiesels. Engine tests and numerical simulations were performed for 100% MO (MO100), 40% MO blended with JIS#2 diesel (MO40) and JIS#2 diesel (D100). The effects of MO on diesel combustion and emission characteristics were studied under engine operating conditions typically encountered in passenger car diesel engines, focusing on important parameters such as pilot injection, injection pressure and exhaust gas recirculation (EGR) rate. We used a diesel engine complying with the EURO4 emissions regulation, having a displacement of 2.2 L for passenger car applications. In engine tests comparing MO with diesel fuel, no effect on engine combustion pressure was observed for all conditions tested.

N₂O is known to have a significantly high global warming potential. We measured N₂O emissions in engine-bench tests by changing the NO/NH₃ ratio and exhaust gas temperature at the oxidation catalyst inlet in a heavy-duty diesel engine equipped with a urea SCR (selective catalytic reduction) system. The results showed that the peak N₂O production ratio occurred at an exhaust gas temperature of around 200°C and the maximum value was 84%. Moreover, the N₂O production ratio increased with increasing NO/NH₃. Thus, we concluded that N₂O is produced via the NO branching reaction. Based on our results, two methods were proposed to decrease N₂O formation. At low temperatures ~200°C, NO should be reduced by controlling diesel combustion to lower the contribution of NO to N₂O production. This is essential because the SCR system cannot reduce NOx at low temperatures.

Reduction of exhaust emissions and BSFC has been studied using a high boost, a wide range and high-rate EGR in a Super Clean Diesel, six-cylinder heavy duty engine. In the previous single-turbocharging system, the turbocharger was selected to yield maximum torque and power. The selected turbocharger was designed for high boosting, with maximum pressure of about twice that of the current one, using a titanium compressor. However, an important issue arose in this system: avoidance of high boosting at low engine speed. A sequential and series turbo system was proposed to improve the torque at low engine speeds. This turbo system has two turbochargers of different sizes with variable geometry turbines. At low engine speed, the small turbocharger performs most of the work. At medium engine speed, the small turbocharger and large turbocharger mainly work in series.

Reduction of exhaust emissions and BSFC was studied for high pressure, wide range, and high EGR rates in a Super-clean Diesel six-cylinder heavy duty engine. The GVW 25-ton vehicle has 10.52 L engine displacement, with maximum power of 300 kW and maximum torque of 1842 Nm. The engine is equipped with high-pressure fuel injection of a 200 MPa level common-rail system. A variable geometry turbocharger (VGT) was newly designed. The maximum pressure ratio of the compressor is about twice that of the previous design: 2.5. Additionally, wide range and a high EGR rate are achieved by high pressure-loop EGR (HP-EGR) and low pressure-loop EGR (LP-EGR) with described VGT and high-pressure fuel injection. The HP-EGR can reduce NOx concentrations in the exhaust pipe, but the high EGR rate worsens smoke. The HP-EGR system layout has an important shortcoming: it has great differences of the intake EGR gas amount into each cylinder, worsens smoke.

For reducing NOx emissions, EGR is effective, but an excessive EGR rate causes the deterioration of smoke emission. Here, we have defined the EGR rate before the smoke emission deterioration while the EGR rate is increasing as the limiting EGR rate. In this study, the high rate of EGR is demonstrated to reduce BSNOx. The adapted methods are a high fuel injection pressure such as 200 MPa, a high boost pressure as 451.3 kPa at 2 MPa BMEP, and the air intake port that maintains a high air flow rate so as to achieve low exhaust emissions. Furthermore, for withstanding 2 MPa BMEP of engine load and high boosting, a ductile cast iron (FCD) piston was used. As the final effect, the installations of the new air intake port increased the limiting EGR rate by 5%, and fuel injection pressure of 200 MPa raised the limiting EGR rate by an additional 5%. By the demonstration of increasing boost pressure to 450 kPa from 400 kPa, the limiting EGR rate was achieved to 50%.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

A urea SCR system was combined with a DPF system to reduce NOx and PM in a four liters turbocharged with intercooler diesel engine. Significant reduction in NOx was observed at low exhaust gas temperatures by increasing NH3 adsorption quantity in the SCR catalyst. Control logic of the NH3 adsorption quantity for transient operation was developed based on the NH3 adsorption characteristics on the SCR catalyst. It has been shown that NOx can be reduced by 75% at the average SCR inlet gas temperature of 158 deg.C by adopting the NH3 adsorption quantity control in the JE05 Mode.

The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.

Urea-SCR system has a high NOx reduction potential in the steady-state diesel engine operation. In complicated transient operations, however, there are certain problems with the urea-SCR system in that NOx reduction performance degrades and adsorbed NH3 would be emitted. Here, optimum urea injection methods and exhaust bypass control to overcome these problems are studied. This exhaust bypass control enables NO/NOx ratio at the inlet of SCR catalyst to be decreased widely, which prevents over production of NO2 at the pre-oxidation catalyst. Steady-state and simple transient engine tests were conducted to clarify NOx reduction characteristics when optimum urea injection pattern and exhaust bypass control were applied. In simple transient test, only the engine load was rapidly changed for obtaining the fundamental knowledge concerning the effect of those techniques.

Urea SCR (Selective Catalytic Reduction) system has high potential of reducing NOx. But such as system durability and safety under deteriorated catalysts conditions have not been well enough clarified because it is new technology for vehicles. In this paper, current NOx emission level of an engine equipped with urea SCR system is discussed and then exhaust emission characteristics were analyzed when the SCR catalyst and/or oxidation catalyst lose their functions. When both SCR and oxidation catalyst were de-activated, not only NOx but also PM increased remarkably, which were much more than the engine-out emissions. Oxidation catalyst downstream of SCR catalyst was effective to suppress such deteriorations.

Recently, after-treatment techniques for diesel engine emission have made remarkable progress with the development of suitable De-NOx catalysts. The urea-injection SCR system is one of the candidates for a high efficiency De-NOx method for diesel engine emissions. This system reduces NOx through a reaction with ammonia (NH3) that is generated from injected urea. In this system, it is very important to control the amount and timing of the urea injection so as to minimize the NH3 gas slip. Therefore, NH3 gas measurement is becoming important during the development of NOx after-treatment systems even though NH3 is not a target component of the current emission regulations. In this paper, a new NH3 gas analyzer utilizing a chemi-luminescence detection (CLD) method has been developed. The new NH3 analyzer consists of dual detectors (DCLDs) and a furnace for a NH3 oxidization catalyst. Real-time concentration of NH3 can be calculated from the difference of NOx readings of two detectors.

To improve urban air pollution, stringent emissions regulations for heavy-duty diesel engines have been proposed and will become effective in Japan, the EU, and the United States in a few years. To comply with such future regulations, it is critical to investigate the effects of intake and injection parameters and fuel properties on engine performance, efficiency and emissions characteristics, associated with the use of aftertreatment systems. An experimental study was carried out to identify such effects. In addition, the KIVA-3 code was used to gain insight into cylinder events. The results showed improvements in NOx-Smoke and BSFC trade-offs at high-pressure injection in conjunction with EGR and supercharging.

To clarify the effect of fuel properties on diesel exhaust emissions, direct injection of two component fuels with approximately zero aromatic content and sulfur were attempted in a diesel engine. Fuels were prepared using paraffins having different cetane numbers and boiling points. Parameters considered are the Average Boiling Point (ABP) by volume and the difference of component characteristics for the same ABP. The results indicate that the trade off relation between NOx and particulate matter (PM) emissions depends significantly on ABP or density and is independent of the fuel component. On the other hand, components of the mixed fuels have significant influence on SOF and THC emissions. Fuels having higher amount of low boiling point components emit higher THC. Mixtures of low boiling point-high cetane number fuel and high boiling point-low cetane number fuel or fuel that contains normal paraffins only emit higher SOF.

A numerical study was carried out to investigate combustion characteristics of a dual-fuel gas diesel engine, using a multi-dimensional model combined with detailed chemical kinetics, including 43 chemical species and 173 elementary reactions. In calculations, the effects of initial temperature, EGR ratios on ignition, and combustion were examined. The results indicated EGR combined with intake preheating can favorably reduced NOx and THC emissions simultaneously. This can be explained by the fact that combustion mechanism is changed from flame propagation to HCCl like combustion.