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Technical Paper

Update on Gasoline Fuel Property and Gasoline Additives Impacts on Stochastic Preignition with Review of Global Market Gasoline Quality

2022-08-30
2022-01-1071
Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.
Technical Paper

Impact of Fuel Detergent Type and Concentration on the Rate and Severity of Stochastic Preignition in a Turbocharged Spark Ignition Direct Injection Gasoline Engine

2021-04-06
2021-01-0490
Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.
Technical Paper

Global Market Gasoline Quality Review: Five Year Trends in Particulate Emission Indices

2021-04-06
2021-01-0623
A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.
Journal Article

Fuel Effects on the Propensity to Establish Propagating Flames at SPI-Relevant Engine Conditions

2021-04-06
2021-01-0488
In order to further understand the sequence of events leading to stochastic preignition in a spark-ignition engine, a methodology previously developed by the authors was used to evaluate the propensity of a wide range of fuels to establishing propagating flames under conditions representative of those at which stochastic preignition (SPI) occurs. The fuel matrix included single component hydrocarbons, binary mixtures, and real fuel blends. The propensity of each fuel to establish a flame was correlated to multiple fuel properties and shown to exhibit consistent blending behaviors. No single parameter strongly predicted a fuel’s propensity to establish a flame, while multiple reactivity-based parameters exhibited moderate correlation. A two-stage model of the flame establishment process was developed to interpret and explain these results.
Journal Article

Detailed Analyses and Correlation of Fuel Effects on Stochastic Preignition

2020-04-14
2020-01-0612
Stochastic or Low-Speed Preignition (SPI or LSPI) is an undesirable abnormal combustion phenomenon encountered in spark-ignition engines. It is characterized by very early heat release and high cylinder pressure and can cause knock, noise and ultimately engine damage. Much of the focus on mitigating SPI has been directed towards the engine oil formulation, leading to the emergence of the Sequence IX test and second-generation GM dexos® oil requirements. Engine design, calibration and fuels also contribute to the prevalence of SPI. As part of a recently completed research consortium, a series of engine tests were completed to determine the impact of fuel composition on SPI frequency. The fuel blends had varying levels of paraffins, olefins, aromatics and ethanol.
Journal Article

Fuel & Lubricant Effects on Stochastic Preignition

2019-01-15
2019-01-0038
In this multi-phase study, fuel and lubricant effects on stochastic preignition (SPI) were examined. First, the behavior of fuels for which SPI data had previously been collected were characterized in terms of their combustion and emissions behavior, and correlations between these characteristics and their SPI behavior were examined. Second, new SPI data was collected for a matrix of fuels that was constructed to test and confirm hypotheses that resulted from interpretation of the earlier data in the study and from data in open literature. Specifically, the extent to which the presence of heavy components in the fuel affected SPI propensity, and the extent to which flame initiation propensity affected SPI propensity, were examined. Finally, the interaction of fuels with lubricants expected to exhibit a range of SPI propensities was examined.
Technical Paper

Investigation of the Impact of Fuel Properties on Particulate Number Emission of a Modern Gasoline Direct Injection Engine

2018-04-03
2018-01-0358
Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.
Technical Paper

A Robust Preignition Rating Methodology: Evaluating the Propensity to Establish Propagating Flames under Real Engine Conditions

2017-10-08
2017-01-2241
In this work, an experimental and analysis methodology was developed to evaluate the preignition propensity of fuels and engine operating conditions in an SI engine. A heated glow plug was introduced into the combustion chamber to induce early propagating flames. As the temperature of the glowplug varied, both the fraction of cycles experiencing these early flames and the phasing of this combustion in the engine cycle varied. A statistical methodology for assigning a single-value to this complex behavior was developed and found to have very good repeatability. The effects of engine operating conditions and fuels were evaluated using this methodology. While this study is not directly studying the so-called stochastic preignition or low-speed preignition problem, it studies one aspect of that problem in a very controlled manner.
Technical Paper

China Market Gasoline Review Using Fuel Particulate Emission Correlation Indices

2017-10-08
2017-01-2401
The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.
Technical Paper

Global Market Gasoline Range Fuel Review using Fuel Particulate Emission Correlation Indices

2016-10-17
2016-01-2251
The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline range fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, with good correlation agreement to PMI. In addition, the paper will cover a global assessment of a gasoline range fuel’s sooting tendency based on the PMI number and the proposed method. Areas around the globe where market gasoline range fuels are of concern will be highlighted, in coordination with the new emissions regulations. Vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.
Technical Paper

Impact of Fuel Octane Rating and Aromatic Content on Stochastic Pre-Ignition

2016-04-05
2016-01-0721
The effects of aromatic content and octane rating of gasoline fuels on stochastic pre-ignition (SPI) behaviors were investigated at typical operating conditions using a modern 2.0 L turbocharged engine. In-cylinder pressure time history measurements made during a speed-load test sequence designed to stimulate SPI were used to determine both the frequency of SPI occurrence and the in-cylinder peak pressure during such events. Six fuels were tested with varying levels of aromatic content (15 - 35% by vol.) and two octane rating levels (∼88 & 94 anti-knock index). The engine was operated using a production-intent calibration with equivalence ratio near one. Pressure and temperature in the intake manifold were held constant near two bar and 35°C respectively. Significant SPI activity was observed, with abnormal event frequencies up to ∼1 SPI event per 1,000 engine cycles and in-cylinder peak pressures up to ∼200 bar.
Technical Paper

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors and Fuel Detergents on Powertrain Intake Valve Deposits

2014-04-01
2014-01-1383
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution systems used for transportation of fuel from refineries. They are also used to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of the types of inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and to show how variation in concentration of components of CIs and detergents impact intake valve deposit formation.
Journal Article

Fuel Octane and Volatility Effects on the Stochastic Pre-Ignition Behavior of a 2.0L Gasoline Turbocharged DI Engine

2014-04-01
2014-01-1226
Classic, hot-spot induced pre-ignition is a phenomenon that has been observed in gasoline spark ignited engines over the past 60-70 years. With the development of turbocharged, direct-injected (DI) gasoline engines, a new pre-ignition phenomenon occurring at low engine speeds and high loads has been encountered. Termed Stochastic Pre-ignition (SPI), it has become a significant issue to address in allowing for the full potential of gasoline turbo DI technology to improve powertrain efficiency. Many researchers are studying all aspects of the causes of Stochastic Pre-ignition, including causes by oil, fuel and engine hardware systems. The focus of this specific research was to study the relationship of fuel octane and volatility to Stochastic Pre-ignition behavior utilizing a GM 2.0L Gasoline Turbocharged DI engine (LHU).
Technical Paper

Destruction of Nitric Oxide via Selective NOx Recirculation During Lean Combustion: A Comparison of Various Engines and Fuels

2006-10-16
2006-01-3369
A series of experiments were performed using a Yanmar TS180, single cylinder, indirect injection (IDI) diesel engine, a natural gas fueled, Olympian G25F1S, spark-ignited, 25 kilowatt generator, and a two-stroke, multi-fuel, spark ignited engine to provide a diverse research platform for the study of in-cylinder NOx destruction (Conversion of NO). For each type of engine, the NOx recirculation step of the selective NOx recirculation (SNR) cycle was simulated by injecting pure nitric oxide (NO) into the intake air at various concentrations, depending on engine type and operating conditions. Previous researchers have attempted to characterize NOx destruction behavior by simulating the NOx recirculation step in both diesel and gasoline engines. Some prior work has suggested that NOx destruction behavior in diesel engines is not dependent on the amount of NO present in the intake air, and that the NOx destruction efficiency was greatly enhanced by increasing engine load.
Technical Paper

Penn State FutureTruck Hybrid Electric Vehicle: Light-Duty Diesel Exhaust Emission Control System to Meet ULEV Emissions Standard

2005-01-24
2005-01-3877
Two of the goals of the Penn State FutureTruck project were to reduce the emissions of the hybrid electric Ford Explorer to ULEV or lower, and improve the fuel economy by 25% over the stock vehicle. The hybrid electric vehicle system is powered with a 103kW 2.5L Detroit Diesel engine which operates with a fuel blend consisting of ultra-low-sulfur diesel and biodiesel (35%). Lower emissions are inherently achieved by the use of biodiesel. Additionally, the engine was fitted with a series of aftertreatment devices in an effort to achieve the low emissions standards. Vehicle testing has shown a gasoline-equivalent fuel economy improvement of approximately 22%, a reduction in greenhouse gas emissions by approximately 38%, and meeting or exceeding stock emissions numbers in all other categories through the use of an advanced catalyst and control strategy.
Technical Paper

Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus

2003-03-03
2003-01-0756
Dimethyl Ether (DME) is a potential ultra-clean diesel fuel. Its unique characteristics require special handling and accommodation of its low viscosity and low lubricity. In this project, DME was blended with diesel fuel to provide sufficient viscosity and lubricity to permit operation of a 7.3 liter turbodiesel engine in a campus shuttle bus with minimal modification of the fuel injection system. A pressurized fuel delivery system was added to the existing common rail injection system on the engine, allowing the DME-diesel fuel blend to be circulated through the rail at pressures above 200 psig keeping the DME in the liquid state. Fuel exiting the rail is cooled by finned tubed heat exchangers and recirculated to the rail using a gear pump. A modified LPG tank (for use on recreational vehicles) stores the DME- diesel fuel blend onboard the shuttle bus.
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