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In this work we studied the effects of piston bowl design on combustion in a small-bore direct-injection diesel engine. Two bowl designs were compared: a conventional, omega-shaped bowl and a stepped-lip piston bowl. Experiments were carried out in the Sandia single-cylinder optical engine facility, with a medium-load, mild-boosted operating condition featuring a pilot+main injection strategy. CFD simulations were carried out with the FRESCO platform featuring full-geometric body-fitted mesh modeling of the engine and were validated against measured in-cylinder performance as well as soot natural luminosity images. Differences in combustion development were studied using the simulation results, and sensitivities to in-cylinder flow field (swirl ratio) and injection rate parameters were also analyzed.

The design of modern diesel-powered vehicles involves optimization and balancing of trade-offs for fuel efficiency, emissions, and noise. To meet increasingly stringent emission regulations, diesel powertrains employ aftertreatment devices to control nitrogen oxides, hydrocarbons, carbon monoxide, and particulate matter emissions and use active exhaust warm-up strategies to ensure those devices are active as quickly as possible. A typical strategy for exhaust warm-up is to operate with retarded combustion phasing, limited by combustion stability and HC emissions. The amount of exhaust enthalpy available for catalyst light-off is limited by the extent to which combustion phasing can be retarded. Diesel cetane number (CN), a measure of fuel ignition quality, has an influence on combustion stability at retarded combustion phasing. Diesel fuel in the United States tends to have a lower CN (both minimum required and average in market) than other countries.

Diesel combustion and emissions is largely spray and mixing controlled. Spray and combustion models enable characterization over a range of conditions to understand optimum combustion strategies. The validity of models depends on the inputs, including the rate of injection profile of the injector. One method to measure the rate of injection is to measure the momentum, where the injected fuel spray is directed onto a force transducer which provides measurements of momentum flux. From this the mass flow rate is calculated. In this study, the impact of impingement distance, the distance from injector nozzle exit to the anvil connected to the force transducer, is characterized over a range of 2 - 12 mm. This characterization includes the impact of the distance on the momentum flux signal in both magnitude and shape. At longer impingement distances, it is hypothesized that a peak in momentum could occur due to increasing velocity of fuel injected as the pintle fully opens.

The Leaner Lifted-Flame Combustion (LLFC) strategy offers a possible alternative to low temperature combustion or other globally lean, premixed operation strategies to reduce soot directly in the flame, while maintaining mixing-controlled combustion. Adjustments to fuel properties, especially fuel oxygenation, have been reported to have potentially beneficial effects for LLFC applications. Six fuels were selected or blended based on cetane number, oxygen content, molecular structure, and the presence of an aromatic hydrocarbon. The experiments compared different fuel blends made of n-hexadecane, n-dodecane, methyl decanoate, tri-propylene glycol monomethyl ether (TPGME), as well as m-xylene. Several optical diagnostics have been used simultaneously to monitor the ignition, combustion and soot formation/oxidation processes from spray flames in a constant-volume combustion vessel.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.

The use of exhaust gas recirculation (EGR) in internal combustion engines has significant impacts on combustion and emissions. EGR can be used to reduce in-cylinder NOx production, reduce emitted particulate matter, and enable advanced forms of combustion. To maximize the benefits of EGR, the exhaust gases are often cooled with on-engine liquid to gas heat exchangers. A common problem with this approach is the build-up of a fouling layer inside the heat exchanger due to thermophoresis and condensation, reducing the effectiveness of the heat exchanger in lowering gas temperatures. Literature has shown the effectiveness to initially drop rapidly and then approach steady state after a variable amount of time. The asymptotic behavior of the effectiveness has not been well explained. A range of theories have been proposed including fouling layer removal, changing fouling layer properties, and cessation of thermophoresis.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

Diesel combustion and emissions formation is largely spray and mixing controlled and hence understanding spray parameters, specifically vaporization, is key to determine the impact of fuel injector operation and nozzle design on combustion and emissions. In this study, an eight-hole common rail piezoelectric injector was tested in an optically accessible constant volume combustion vessel at charge gas conditions typical of full load boosted engine operation. Liquid penetration of the eight sprays was determined via processing of images acquired from Mie back scattering under vaporizing conditions by injecting into a charge gas at elevated temperature with 0% oxygen. Conditions investigated included a charge temperature sweep of 800 to 1300 K and injection pressure sweep of 1034 to 2000 bar at a constant charge density of 34.8 kg/m₃.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

The number of control actuators available on spark-ignition engines is rapidly increasing to meet demand for improved fuel economy and reduced exhaust emissions. The added complexity greatly complicates control strategy development because there can be a wide range of potential actuator settings at each engine operating condition, and map-based actuator calibration becomes challenging as the number of control degrees of freedom expand significantly. Many engine actuators, such as variable valve actuation and flow control valves, directly influence in-cylinder combustion through changes in gas exchange, mixture preparation, and charge motion. The addition of these types of actuators makes it difficult to predict the influences of individual actuator positioning on in-cylinder combustion without substantial experimental complexity.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.

A numerical study has been conducted to investigate possible extension of the low load limit of the HCCI operating range by charge stratification using direct injection. A wide range of SOI timings at a low load HCCI engine operating condition were numerically examined to investigate the effect of DI. A multidimensional CFD code KIVA3v with a turbulent combustion model based on a modified flamelet approach was used for the numerical study. The CFD code was validated against experimental data by comparing pressure traces at different SOI’s. A parametric study on the effect of SOI on combustion has been carried out using the validated code. Two parameters, the combustion efficiency and CO emissions, were chosen to examine the effect of SOI on combustion, which showed good agreement between numerical results and experiments. Analysis of the in-cylinder flow field was carried out to identify the source of CO emissions at various SOI’s.

EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

EGR coolers are mainly used on diesel engines to reduce intake charge temperature and thus reduce emissions of NOx and PM. Soot and hydrocarbon deposition in the EGR cooler reduces heat transfer efficiency of the cooler and increases emissions and pressure drop across the cooler. They may also be acidic and corrosive. Fouling has been always treated as an approximate factor in heat exchanger designs and it has not been modeled in detail. The aim of this paper is to look into fouling formation in an EGR cooler of a diesel engine. A 1-D model is developed to predict and calculate EGR cooler fouling amount and distribution across a concentric tube heat exchanger with a constant wall temperature. The model is compared to an experiment that is designed for correlation of the model. Effectiveness, mass deposition, and pressure drop are the parameters that have been compared. The results of the model are in a good agreement with the experimental data.

Meeting diesel engine emission standards for heavy-duty vehicles can be achieved by simultaneous injection of fuel and water. An injection system for instantaneous mixing of fuel and water in the combustion chamber has been developed by injecting water in a mixing passage located in the periphery of the fuel spray. The fuel spray is then entrained by water and hot air before it burns. The experimental work was carried out on a Rapid Compression Machine and on a Komatsu direct-injection heavy-duty diesel engine with a high pressure common rail fuel injection system. It was also supported by Computational Fluid Dynamics simulations of the injection and combustion processes in order to evaluate the effect of water vapor distribution on cylinder temperature and NOX formation. It has been concluded that when the water injection is appropriately timed, the combustion speed is slower and the cylinder temperature lower than in conventional diesel combustion.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.