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Synthetic fuels (e-fuels) synthesized from H2 and CO by renewable electricity are expected as the next- generation diesel fuels and two types of e-fuels have received extensive attention: Fischer-Tropsch (FT) fuel and Oxymethylene dimethyl ether (OME). In this study the effects of OME blending ratios with 0 to 50 vol.% in FT fuels on combustion, emissions and spray characteristics in diesel engines are investigated. The results suggest that the OME blends to FT fuels suppressed the deterioration in combustion efficiency under low intake oxygen concentration conditions. The smoke emissions of FT fuels and OME blended fuels were both lower than those of diesel fuel and decreased with the increase in the OME blend ratio, and the soot-NOx trade-off relation in diesel engines can be improved.

The authors have reported significant smoke reduction in twin shaped semi-premixed diesel combustion with a newly designed combustion chamber to distribute the first and the second sprays into upper and lower layers. However, the first stage premixed combustion tends to advance far from the TDC, resulting in lowering of thermal efficiencies. In this report, improvement of thermal efficiency by optimizing the combustion phase with lower ignitability fuels was identified with the divided combustion chamber. The experiment was conducted with four fuels with different cetane numbers. The first stage premixed combustion can be retarded to the optimum phase with the fuel with cetane number 38, establishing high efficiencies.

Spark knock suppression with hydrogen addition was investigated at two engine speeds (2000 rpm and 4800 rpm). The experimental results showed that the spark knock is strongly suppressed with increasing hydrogen fraction at 2000 rpm while the effect is much smaller at 4800 rpm. To explain these results, chemical kinetic analyses with a two-zone combustion model were performed. The calculated results showed that the heat release in the end gas zone rises in two stages with a remarkable appearance of low temperature oxidation (LTO) at 2000 rpm, while a single stage heat release without apparent LTO process is presented at 4800 rpm due to the shorter residence time in the low temperature region.

In a natural gas fueled engine ignited by diesel fuel, the addition of hydrogen to the engine could be a possible way to improve thermal efficiency and reduce unburned methane which has a warming potential many times that of carbon dioxide as it promotes a more rapid and complete combustion. This study carried out engine experiments using a single cylinder engine with natural gas and hydrogen delivered separately into the intake pipe, and with pilot-injection of diesel fuel. The percentages of hydrogen in the natural gas-hydrogen mixtures were varied from 0% to 50% of the heat value. The results showed that the hydrogen addition has an insignificant effect on the ignition delay of the diesel fuel and that it shortens the combustion duration. The increase in the hydrogen ratio decreased the unburned hydrocarbon emissions more than the reduction of the amount of natural gas that was replaced by the hydrogen.

To improve the combustion characteristics in semi-premixed diesel combustion, consisting in the first-stage premixed combustion of the primary fuel injection and the second-stage spray combustion of the secondary injection, the effect of splitting the primary injection was investigated in a diesel engine and analyzed with a CFD. The indicated thermal efficiency improves due to reductions in heat transfer losses to the in-cylinder wall and the combustion noise is suppressed with the split primary injections. The CFD analysis showed that the reduction in heat transfer loss with the split primary injections is due to a decrease in the combustion quantity near the combustion chamber wall.

The Dual-Fuel (DF) combustion is a promising technology for efficient, low NOx and low exhaust particulate matter (PM) engine operation. To achieve equivalent performance to a DF engine with only the use of conventional liquid fuel, this study proposes the implementation of an on-board fuel reformation process by piston compression. For concept verification, DF combustion tests with representative reformed gas components were conducted. Based on the results, the controllability of the reformed gas composition by variations in the operating conditions of the reformer cylinder were discussed.

Diesel particulate filters (DPF) are widely used in diesel engines, and forced regeneration is necessary to remove particulate matter (PM) accumulating on the DPF. This may be achieved with fuel injected after the main combustion is complete, the socalled “post fuel injection”, and supplied to the diesel oxidation catalyst (DOC) upstream of the DPF. This increases the exhaust gas temperature in the DOC and the DPF is regenerated with the high temperature gas flow. In most cases, the post fuel injection takes place at 30-90CA ATDC, and fuel may impinge on and adhere to the cylinder liner wall in some cases. Buddie and Pischinger [1] have reported a lubricant oil dilution with the post fuel injection by engine tests and simulations, and adhering fuel is a cause of worsening fuel consumption. In this paper, the impingement and adhesion of post diesel fuel injections on the cylinder liner was investigated by an optical method with a high pressure constant volume chamber (ϕ110mm, 883cm3).

The engine performance and the exhaust gas emissions in a dual fuel compression ignition engine with natural gas as the main fuel and a small quantity of pilot injection of diesel fuel with the ultra-high injection pressure of 250 MPa as an ignition source were investigated at 0.3 MPa and 0.8 MPa IMEP. With increasing injection pressure the unburned loss decreases and the thermal efficiency improves at both IMEP conditions. At the 0.3 MPa IMEP the THC and CO emissions are significantly reduced when maintaining the equivalence ratio of natural gas with decreasing the volumetric efficiency by intake gas throttling, but the NOx emissions increase and excessive intake gas throttling results in a decrease in the indicated thermal efficiency. Under the 250 MPa pilot injection condition simultaneous reductions in the NOx, THC, and CO emissions can be established with maintaining the equivalence ratio of natural gas by intake gas throttling.

Premixed diesel combustion blending high volatility fuels into diesel fuel were investigated in a modern diesel engine. First, various fractions of normal heptane and diesel fuel were examined to determine the influence of the blending of a highly ignitable and volatile fuel into diesel fuel. The indicated thermal efficiency improves almost linearly with increasing normal heptane fraction, particularly at advanced injection timings when the fuel is not injected directly into the piston cavity. This improvement is mainly due to decreases in the other losses, ϕother which are calculated with the following equation based on the energy balance. ηu: The combustion efficiency calculated from the exhaust gas compositions ηi: The indicated thermal efficiency ϕex: The exhaust loss calculated from the enthalpy difference between intake and exhaust gas The decreases in the other losses with normal heptane blends are due to a reduction in the unburned fuel which does not reach the gas analyzer.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

The diesel spray characteristics in early pilot and late post fuel injections in a constant volume chamber which can create the in-cylinder conditions of a diesel engine were visualized with high speed video. At the early pilot and late post fuel injection, there was a longer penetration of the liquid phase fuel spray as well as slower evaporation. With normal heptane the impingement of liquid spray with early pilot and post fuel injections can be avoided due to a faster evaporation. The penetration of liquid phase fuel spray increases significantly at low IMEP and late post injection conditions with diesel fuel.

Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.

Diesel-like combustion of an emulsified blend of water and diesel fuel in a constant volume chamber vessel was visualized with high speed color video, further analyzing with a 2-D two color method and shadowgraph images. When the temperature at the fuel injection is 900 K, here while the combustion with unblended diesel fuel in the vessel is similar to ordinary diesel combustion with diffusive combustion, combustion with the emulsified fuel is similar to premixed diesel combustion with a large premixed combustion and very little diffusive combustion. With the emulsified fuel the flame luminosity and temperature are lower, the luminous flame and high temperature regions are smaller, and the duration of the luminous flame is shorter than with diesel fuel. This is due to promotion of premixing with increases in the ignition delay and decreases in the combustion temperature with the water vaporization.

Dual fuel combustion with premixed ethanol as the main fuel and direct injection of diesel fuel as an ignition source poses problems including large unburned emissions and excessively rapid combustion. In this report the influence of compression ratios, injection timings of diesel fuel, and intake oxygen concentrations was systematically investigated in a modern diesel engine. The combustion process was classified into three stages: the first rapid combustion of diesel fuel and the ethanol mixture entrained into the diesel fuel spray; the second mild combustion with flame propagation of the ethanol mixture; and the third rapid combustion with auto-ignition of the unburned ethanol mixture without knocking. The third stage combustion occurs occasionally at several operating conditions and has been termed as PREMIER (premixed mixture ignition in the end-gas region) combustion.

The influence of fuel properties on the operational range and the thermal efficiency of premixed diesel combustion was evaluated with an ordinary diesel fuel, a primary reference fuel for cetane numbers, three primary reference fuels for octane numbers, and two normal heptane-toluene blend fuels in a single-cylinder DI diesel engine. The fuel injection timing was set at 25°CA BTDC and the maximum rate of pressure rise was maintained below 1.0 MPa/°CA when lowering the intake oxygen concentration by cooled EGR. With increasing octane numbers, the higher intake oxygen concentration can be used, resulting in higher indicated thermal efficiency due to a higher combustion efficiency. The best thermal efficiency at the optimum intake oxygen concentration with the ordinary diesel fuel is lower than with the primary reference fuels with the similar ignitability but higher volatility.

Water and diesel fuel emulsions containing 13% and 26% water by volume were investigated in a modern diesel engine with relatively early pilot injection, supercharging, and cooled EGR. The heat release from the pilot injection with water emulsions is retarded toward the top dead center due to the poor ignitability, which enables larger pilot and smaller main injection quantities. This characteristic results in improvements in the thermal efficiency due to the larger heat release near the top dead center and the smaller afterburning. With the 26% water emulsion, mild, smokeless, and very low NOx operation is possible at an optimum pilot injection quantity and 15% intake oxygen with EGR at or below 0.9 MPa IMEP, a condition where large smoke emissions are unavoidable with regular unblended diesel fuel. Heat transfer analysis with Woschni's equation did not show the decrease in cooling loss with the water emulsion fuels.

The influence of fuel volatility on the thermal efficiency of premixed diesel combustion was evaluated with three ordinary diesel fuels with different distillation temperature distributions and also with a primary reference fuel with an octane number of 20 (PRF20) as a high volatility fuel. The experiments were conducted on a single-cylinder DI diesel engine for the premixed diesel combustion with a single injection at 11% intake oxygen concentration and conventional diesel combustion with a pilot fuel injection at 21% intake oxygen concentration. With the premixed diesel combustion, the indicated thermal efficiencies with the ordinary diesel fuels were lower than with PRF20 although the shapes of the rate of heat release and the combustion efficiencies calculated from the exhaust gas components were almost unchanged. With the conventional diesel combustion, the indicated thermal efficiencies with the ordinary diesel fuels and PRF20 were similar.

Combustion and exhaust gas emissions of alcohol and vegetable oil blends including a 20% ethanol + 40% 1-butanol + 40% vegetable oil blend and a 50% 1-butanol + 50% vegetable oil blend were examined in a single cylinder, four-stroke cycle, 0.83L direct injection diesel engine, with a supercharger and a common rail fuel injection system. A 50% diesel oil + 50% vegetable oil blend and regular unblended diesel fuel were used as reference fuels. The boost pressure was kept constant at 160 kPa (absolute pressure), and the cooled low pressure loop EGR was realized by mixing with a part of the exhaust gas. Pilot injection is effective to suppress rapid combustion due to the lower ignitability of the alcohol and vegetable oil blends. The effects of reductions in the intake oxygen concentration with cooled EGR and changes in the fuel injection pressure were investigated for the blended fuels.

The HCCI engine offers the potential of low NOx emissions combined with diesel engine like high efficiency, however HCCI operation is restricted to low engine speeds and torques constrained by narrow noise (HCCI knocking) and misfiring limits. Gasoline like fuel vaporizes and mixes with air, but the mixture may auto-ignite at the same time, leading to heavy HCCI knocking. Retarding the CA50 (the crank angle of the 50% burn) is well known as a method to slow the maximum pressure rise rate and reduce HCCI knocking. The CA50 can be controlled by the fuel composition, for example, di-methyl ether (DME), which is easily synthesized from natural gas, has strong low temperature heat release (LTHR) characteristics and ethanol generates strong LTHR inhibitor effects. The utilization of DME-ethanol binary blended fuels has the potential to broaden the HCCI engine load-speed range.

Characteristics of diesel combustion with low cetane number fuels with similar distillation temperatures to ordinary diesel fuel, including fuels with cetane number 32 and 39 (LC32, LC39), and a blend of n-cetane (n-hexadecane) and iso-cetane (2, 2, 4, 4, 6, 8, 8-heptamethylnonane) with cetane number 32 (CN32), were investigated. The effects of cooled exhaust gas recirculation (EGR) and pilot injection on characteristics of combustion and exhaust gas emissions with these fuels were examined in a naturally aspirated, single cylinder, diesel engine equipped with a common-rail fuel injection system. Even with the low cetane number fuels, quiet combustion with low levels of exhaust gas emissions comparable to ordinary diesel fuel was established by suitable control of intake oxygen levels and pilot injections.