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Journal Article

Extrusion Foaming of Nano-Clay-Filled Wood Fiber Composites for Automotive Applications

2008-04-14
2008-01-1264
This paper presents the foaming behaviors of high-density polyethylene (HDPE)-based and polypropylene (PP)-based wood fiber composites with a small amount of nanosized clay. Melt compounding was used to prepare various types of clay-filled, wood fiber composites, such as intercalated and exfoliated clay composites. Their morphology was determined by using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The extrusion foaming was conducted using N2 as the blowing agent. The cell nucleation and growth behaviors of composite foams were studied while varying temperature, pressure, wood fiber content, and clay content. The effects of clay content and exfoliation degree on the final cell morphology of wood fiber/polyolefin/clay nanocomposite foams were identified.
Technical Paper

Influence of Interfacial Interaction on the Foamability of Wood Fiber/HDPE Composites

2007-04-16
2007-01-0577
This research presents a fundamental study of the interaction between chemically modified wood fibers and high density polyethylene (HDPE) to develop wood fiber/HDPE composites with satisfactory performance. This paper investigates the effects of the interfacial properties of HDPE and wood fibers on the rheological properties and foaming behavior of the composites. The surface characteristics of wood fiber were modified by treating the fiber with trialkoxy silane. The effectiveness of chemical surface modifications of wood fiber was characterized using FT-IR. The effect of the interfacial interaction on the foaming behavior was studied via extrusion foaming with a physical blowing agent. The rheological property of the composites with a different interfacial structure were also evaluated by using dynamic oscillatory rheometer.
Technical Paper

Poly (butyl acrylate)-Modified Cellulose Fibres for Toughening WPC

2007-04-16
2007-01-0574
One of the key challenges of the wood polymer composites (WPC) is the inadequate toughness partly due to the incompatibility of the natural fibres and PP matrix. In this work, we performed the surface modification of the natural fibre by either in-situ grafting polymerization of butyl acrylate (PBA) or adsorbing matrix-compatible cationic PBA latex on the fibre surfaces. The results indicated that the mechanical properties of the polypropylene (PP) composites containing the modified fibres, unnotched Izod impact strength in particular, have been improved significantly. The influencing factors and the mechanism of toughening process have also been preliminarily investigated.
Technical Paper

The Effect of Fiber Surface Treatment on the Performance of Hemp Fiber/Acrylic Composites for Automotive Structural Parts

2006-04-03
2006-01-0005
The use of natural fibers for polymer composite materials has increased tremendously in the last few years. This type of reinforcements offers many advantages such as low density, low cost, high specific strength and low environmental impacts. The performance of the natural fiber composites are affected by the fiber loading, the individual mechanical properties of each component (fiber and matrix), and the fiber and matrix adhesion. Concerning the interfacial interaction, natural fibers present a major drawback because of poor compatibility of fibers with most hydrophobic thermoplastic and thermoset matrix. Hemp fiber/acrylic composites were manufactured with sheet molding technique recently. Although mechanical tests give promising results, they exhibit low tensile strength resulting from a poor fiber/matrix adhesion. The moisture resistance property of the sheet molded composites also needs further improvement.
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