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Technical Paper

Optical Spray Investigations on OME3-5 in a Constant Volume High Pressure Chamber

Synthetic fuels generated with surplus renewable electricity, water and captured CO2, so called E-fuels, offer the possibility to easily store excess energy over long periods of time. Therefore, the ALIGN-CCUS-project seeks to use them for power-generation and as a fuel for the transport-sector. Polyoxymethylene-dimethyl-ethers (POMDMEs, short: OME) are promising E-fuels for passenger-car applications. Their molecular structure is CH3-O-(CH2O)n-CH3. For passenger-car applications, OME-mixtures with n between 3 and 5 seem most suitable, as the mixture is liquid under normal ambient conditions, offers a high cetane-number and sufficient lubricity. Their high flash-point, low toxicity and good miscibility with conventional diesel-fuel also may ease their market-introduction.
Technical Paper

Analysis of the Emission Conversion Performance of Gasoline Particulate Filters Over Lifetime

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Due to their rapid market introduction, extensive field experience with GPFs is not yet available. Especially for four-way catalytic converters, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. In the first part of the paper, experimental GPF ash loading results are presented. Since most of the ash accumulated in the filter results from the combustion of lubricating oil additives, a burner test bench with a purpose-designed oil injection system was chosen for the investigations. The analysis of the backpressure results show that, contrary to high soot loadings, the ash load has a relatively low impact on engine performance and fuel consumption.
Technical Paper

Efficient Test Bench Operation with Early Damage Detection Systems

The efficient operation of test benches within the framework of research and development projects directly correlates with the "health" of the examinee to be investigated. The use of so-called Early Damage Detection Systems (EDDS) is becoming increasingly popular for reasons of Unit Under Test (UUT) monitoring. In the context of this publication the expectations of an EDDS and its structure are discussed as well as its advantages and disadvantages in test bench operation analyzed and compared with the results of measurements. The used EDDS should primarily prevent the damage, up to the loss of the test object by a total loss, in order to ensure a finding possibility of the damaged part at the examined test object. A deviation of the test object behavior from the undamaged condition must be recognized in an early status and must lead to a shutdown of the test bench operation after reaching a defined limit value.
Technical Paper

Virtual Transmission Evaluation Using an Engine-in-the-Loop Test Facility

This paper describes an approach to reduce development costs and time by frontloading of engineering tasks and even starting calibration tasks already in the early component conception phases of a vehicle development program. To realize this, the application of a consistent and parallel virtual development and calibration methodology is required. The interaction between vehicle subcomponents physically available and those only virtually available at that time, is achieved with the introduction of highly accurate real-time models on closed-loop co-simulation platforms (HiL-simulators) which provide the appropriate response of the hardware components. This paper presents results of a heterogeneous testing scenario containing a real internal combustion engine on a test facility and a purely virtual vehicle using two different automatic transmission calibration and hardware setups.
Technical Paper

Influence of Vehicle Operators and Fuel Grades on Particulate Emissions of an SI Engine in Dynamic Cycles

With the implementation of the “Worldwide harmonized Light duty Test Procedure” (WLTP) and the highly dynamic “Real Driving Emissions” (RDE) tests in Europe, different engineering methodologies from virtual calibration approaches to Engine-in-the-loop (EiL) methods have to be considered to define and calibrate efficient exhaust gas aftertreatment technologies without the availability of prototype vehicles in early project phases. Since different types of testing facilities can be used, the effects of test benches as well as real and virtual vehicle operators have to be determined. Moreover, in order to effectively reduce harmful emissions, the reproducibility of test cycles is essential for an accurate and efficient application of exhaust gas aftertreatment systems and the calibration of internal combustion engines.
Journal Article

Improving Engine Efficiency and Emission Reduction Potential of HVO by Fuel-Specific Engine Calibration in Modern Passenger Car Diesel Applications

The optimization study presented herein is aimed to minimize the fuel consumption and engine-out emissions using commercially available EN15940 compatible HVO (Hydrogenated Vegetable Oil) fuel. The investigations were carried out on FEV’s 3rd generation HECS (High Efficiency Combustion System) multi-cylinder engine (1.6L, 4 Cylinder, Euro 6). Using a global DOE approach, the effects of calibration parameters on efficiency and emissions were obtained and analyzed. This was followed by a global optimization procedure to obtain a dedicated calibration for HVO. The study was aiming for efficiency improvement and it was found that at lower loads, higher fractions of low pressure EGR in combination with lower fuel injection pressures were favorable. At higher loads, a combustion center advancement, increase of injection pressure and reduced pilot injection quantities were possible without exceeding the noise and NOx levels of the baseline Diesel.
Journal Article

Assessment of the Full Thermodynamic Potential of C8-Oxygenates for Clean Diesel Combustion

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.
Journal Article

Laser-Induced Incandescence Measurements of Tailor-Made Fuels in an Optical Single-Cylinder Diesel Engine

The influence of two oxygenated tailor-made fuels on soot formation and oxidation in an optical single cylinder research diesel engine has been studied. For the investigation a planar laser-induced incandescence (PLII) measurement technique was applied to the engine in order to detect and evaluate the planar soot distribution for the two bio fuels within a laser light sheet. Furthermore the OH* chemiluminescence and broad band soot luminosity was visualized by high speed imaging to compare the ignition and combustion behavior of tested fuels: Two C8 oxygenates, di-n-butylether (DNBE) and 1-octanol. Both fuels have the same molecular formula but differ in their molecular structure. DNBE ignites fast and burns mostly diffusive while 1-octanol has a low cetane number and therefore it has a longer ignition delay but a more homogeneous mixture at time of ignition. The two bio fuels were finally compared to conventional diesel fuel.
Journal Article

A Sectoral Approach to Modelling Wall Heat Transfer in Exhaust Ports and Manifolds for Turbocharged Gasoline Engines

A new approach is presented to modelling wall heat transfer in the exhaust port and manifold within 1D gas exchange simulation to ensure a precise calculation of thermal exhaust enthalpy. One of the principal characteristics of this approach is the partition of the exhaust process in a blow-down and a push-out phase. In addition to the split in two phases, the exhaust system is divided into several sections to consider changes in heat transfer characteristics downstream the exhaust valves. Principally, the convective heat transfer is described by the characteristic numbers of Nusselt, Reynolds and Prandtl. However, the phase individual correlation coefficients are derived from 3D CFD investigations of the flow in the exhaust system combined with Low-Re turbulence modelling. Furthermore, heat losses on the valve and the seat ring surfaces are considered by an empirical model approach.
Technical Paper

Optical Investigation of Biofuel Effects on NO and PAH Formation in Diesel-Like Jets

In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this reason in this paper a blend out of 1-octanol and di-n-butylether and pure di-n-butylether are investigated in comparison to n-heptane as diesel-like fuel. The alternative fuels have a different combustion behavior particularly concerning important combustion parameters like ignition delay and mixture formation. Especially the formation of pollutants like nitrogen oxides in the combustion of alternative fuels is of global interest. The knowledge of the combustion behavior is important to design new engine geometries or implement a new calibration of the engine. In previous measurements in a single cylinder engine it was found out that both alternative fuels form nearly no soot emissions. For this reason now NOx is investigated optically to avoid the traditional soot NOx trade-off in diesel combustion.
Journal Article

The Oxidation Potential Number: An Index to Evaluate Inherent Soot Reduction in D.I. Diesel Spray Plumes

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.
Journal Article

Mixture-Formation Analysis by PLIF in an HSDI Diesel Engine Using C8-Oxygenates as the Fuel

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.
Journal Article

On the Potential of Oxygenated Fuels as an Additional Degree of Freedom in the Mixture Formation in Direct Injection Diesel Engines

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.
Technical Paper

Performance and Emissions of Lignin and Cellulose Based Oxygenated Fuels in a Compression-Ignition Engine

Lignocellulosic biomass consists of (hemi-) cellulose and lignin. Accordingly, an integrated biorefinery will seek to valorize both streams into higher value fuels and chemicals. To this end, this study evaluated the overall combustion performance of both cellulose- and lignin derivatives, namely the high cetane number (CN) di-n-butyl ether (DnBE) and low CN anisole, respectively. Said compounds were blended both separately and together with EN590 diesel. Experiments were conducted in a single cylinder compression ignition engine, which has been optimized for improved combustion characteristics with respect to low emission levels and at the same time high fuel efficiency. The selected operating conditions have been adopted from previous “Tailor-Made Fuels from Biomass (TMFB)” work.
Journal Article

Utilization of HVO Fuel Properties in a High Efficiency Combustion System: Part 2: Relationship of Soot Characteristics with its Oxidation Behavior in DPF

The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.
Journal Article

Probing Species Formed by Pilot Injection During Re-Compression in a Controlled Auto-Ignition Engine by H2CO LIF and Chemiluminescence Imaging

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.
Technical Paper

C8-Oxygenates for Clean Diesel Combustion

Within this paper, the two possible alternative and biomass-based fuel candidates Di-n-butyl ether (DNBE) and 1-octanol are investigated with regard to their utilization in a diesel-type engine. In order to asses the fuels emission-reduction potential, both have been tested in a single cylinder engine (SCE) and a high pressure chamber (HPC) in comparison to conventional EN590 diesel at various load points. Due to its reduced reactivity 1-octanol features a longer ignition delay and thus higher degrees of homogenization at start of combustion, whereas DNBE ignites rather rapidly in both the HPC and the engine leading to a predominantly mixing controlled combustion. Thus, both fuels feature completely different combustion characteristics. However, compared to diesel, both fuels contribute to a significant reduction in Filter Smoke Number (FSN) up to a factor of 15.
Technical Paper

Optimization of Diesel Combustion and Emissions with Newly Derived Biogenic Alcohols

Modern biofuels offer the potential to decrease engine out emissions while at the same time contributing to a reduction of greenhouse gases produced from individual mobility. In order to deeply investigate and improve the complete path from biofuel production to combustion, in 2007 the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University. Since then, a whole variety of possible fuel candidates have been identified and investigated. In particular oxygenated fuels (e.g. alcohols, furans) have proven to be beneficial regarding the particulate matter (PM)/ NOx trade-off [1, 2, 3] in diesel-type combustion. Alcohols that provide a longer ignition delay than diesel might behave even better with regard to this trade-off due to higher homogenization of the mixture. Recent studies carried out within the Cluster of Excellence have discovered new pathways to derive 1-octanol from biomass [4], which features a derived cetane number (DCN) of 39.
Technical Paper

Tailor-Made Fuels from Biomass: Influence of Molecular Structures on the Exhaust Gas Emissions of Compression Ignition Engines

In order to deeply investigate and improve the complete path from biofuel production to combustion, the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Recently, new pathways have been discovered to synthesize octanol [1] and di-n-butylether (DNBE). These molecules are identical in the number of included hydrogen, oxygen and carbon atoms, but differ in the molecular structure: for octanol, the oxygen atom is at the end of the molecule, whereas for DNBE it is located in the middle. In this paper the utilization of octanol and DNBE in a state-of-the-art single cylinder diesel research engine will be discussed. The major interest has been on engine emissions (NOx, PM, HC, CO, noise) compared to conventional diesel fuel.
Journal Article

Optimization of Diesel Combustion and Emissions with Tailor-Made Fuels from Biomass

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.