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Technical Paper

Experimental Investigation of Combustion Timing of HVO, RME and Diesel Fuel in a Euro6 Car Engine during Transient Driving Cycles

2019-09-09
2019-24-0138
The current targets to decrease greenhouse gases production, to reduce fossil fuel dependency and to gain energy security and sustainability are driving demand on combustion engine fuels from renewable sources. This effort resulted in utilization of first generation biofuels. Unfortunately, these fuels brought new dilemmas and challenges in general, such as food production competition and land use and, in case of fatty acid methyl esters for compression ignition engines, also technical challenges such as storage stability and deposit formation. Utilization of particle filters and sensitive fuel systems are driving effort to develop compatible renewable biofuels which can be utilized at higher than current shares. Hydrotreated vegetable oils (HVO), as industrially produced biofuels, exhibit some beneficial properties compared to traditional fatty-acid methyl esters especially in terms of oxidation stability, injector fouling, energy content and cetane number.
Technical Paper

Influences of Butanol Blends on Combustion and Emissions of a Small SI Engine

2018-10-30
2018-32-0058
In the general efforts to replace the fossil fuels in transportation by renewable fuels the bioalcohols are an important alternative. The global share of Bioethanol used for transportation is continuously increasing. Butanol, a four-carbon alcohol, is considered in the last years as an interesting alternative fuel, both for Diesel and for Gasoline application. Its advantages for engine operation are: good miscibility with gasoline and diesel fuels, higher calorific value than Ethanol, lower hygroscopicity, lower corrosivity and possibility of replacing aviation fuels. In the present work research with different nButanol portions in gasoline (BuXX)* was performed on the 2-cylinder SI engine with variations of several parameters on engine dynamometer. At different steady state operating points were varied: spark timing (αz), air excess factor (λ) and EGR-rate. Furthermore, the conversion rates and light-off of a 3-way-catalyst were investigated.
Technical Paper

PN-Emissions of Gasoline Cars MPI and Potentials of GPF

2018-04-03
2018-01-0363
Further efforts to reduce the air pollution from traffic are undertaken worldwide and the filtration of exhaust gas will also be increasingly applied on gasoline cars (GPF1 … gasoline particle filter). In the present paper, some results of investigations of nanoparticles from four MPI gasoline cars are represented. The measurements were performed at vehicle tailpipe and in CVS-tunnel. Moreover, two variants of GPF were investigated on a high-emitting modern vehicle, including analytics of PAH and attempts of soot loading in road application. The modern MPI vehicles can emit a considerable amount of PN, which in some cases attains the level of Diesel exhaust gas without DPF and can pass over the actual European limit value for GDI (6.0 x 1011 #/km). The GPF-technology offers in this respect further poten-tials to reduce the PN-emissions of traffic.
Technical Paper

Experimental Investigation of Fuel Injection and Spark Timing for the Combustion of n-Butanol and iso-Butanol and Their Blends with Gasoline in a Two-Cylinder SI Engine

2017-09-04
2017-24-0115
In this study, the combustion of butanol, neat and mixed with gasoline, was investigated on a 0.6 liter two-cylinder spark ignition engine with fully adjustable fuel injection and spark timing, coupled with an eddy current dynamometer. Two isomers of butanol, n-butanol and iso-butanol, were examined. This basic parameter study gives information about potential requirements of engine control systems for butanol FFV. Compared to the traditionally used ethanol, butanol does not exhibit hygroscopic behaviour, is chemically less aggressive and has higher energy density. On other hand, different laminar burning velocity and higher boiling temperature of butanol, compared to gasoline, requires some countermeasures to keep the engine operation reliable and efficient.
Technical Paper

Nanoparticle Emissions of DI Gasoline Cars with/without GPF

2017-03-28
2017-01-1004
In the present paper some results of investigations of nanoparticles from five DI gasoline cars are represented. The measurements were performed at vehicle tailpipe and in CVS-tunnel. Moreover, five variants of “vehicle - GPF” were investigated. These results originate from the project GasOMeP (Gasoline Organic & Metal Particulates), which focused on metal-nanoparticles (including sub 20nm) from gasoline cars with different engine technologies. The PN-emission level of the investigated GDI cars in WLTC without GPF is in the same range of magnitude very near to the actual limit value of 6.0 × 1012 #/km. With the GPF’s with better filtration quality, it is possible to lower the emissions below the future limit value of 6.0 × 1011 #/km. There is no visible nuclei mode and the ultrafine particle concentrations below 10mm are insignificant. Some of the vehicles show at constant speed operation a periodical fluctuation of the NP-emissions, as an effect of the electronic control.
Technical Paper

Effects of Ethanol Blend Fuels E10 and E85 on the Non-Legislated Emissions of a Flex Fuel Passenger Car

2016-04-05
2016-01-0977
A well-balanced use of alternative fuels worldwide is an important objective for a sustainable development of individual transportation. Several countries have objectives to substitute a part of the energy of traffic by ethanol as the renewable energy source. The global share of Bioethanol used for transportation is continuously increasing. Investigations of limited and unregulated emissions of a flex fuel vehicle with gasoline-ethanol blend fuel have been performed in the present work on the chassis dynamometer according to the measuring procedures, which were established in the previous research in the Swiss Network to adequately consider the transient (WLTC) and the stationary operation (SSC). The investigated fuel contained ethanol (E), in the portions of 10% & 85% by volume. The investigated vehicle represented a newer state of technology and an emission level of Euro 5. The engine works with homogenous GDI concept and with 3-W-catalyst (3WC).
Technical Paper

Real Driving Emissions of Two Older Ordinary Cars Operated on High-Concentration Blends of N-Butanol and ISO-Butanol with Gasoline

2015-09-06
2015-24-2488
Butanol, which can be produced from biomass, has been suggested as an alternative to ethanol, due to its higher energy density, lower oxygen content and more favorable hygroscopic and corrosive properties. In the Czech Republic, E85 is widely sold at fuel stations and used in ordinary vehicles, both with and without aftermarket control units. This work investigates the potential of ordinary automobiles to run on butanol, and the associated effects on exhaust emissions under real driving conditions. A Škoda Felicia car with a throttle body injection and a Škoda Fabia car with a multi-point port injection have been run on gasoline and its mixtures with up to 85% volume of ethanol, of n-butanol, and of isobutanol (2-methyl-1-propanol). An auxiliary control unit has been used with higher alcohol content. On each fuel, each car was driven 5-6 times along a local test route.
Technical Paper

Investigations of NO2 in Legal Test Procedure for Diesel Passenger Cars

2015-09-06
2015-24-2510
As a result of increased use of catalytic exhaust aftertreatment systems of vehicles and the low-sulfur Diesel fuels there is an increasing share of nitrogen dioxide NO2 in the ambient air of several cities. This is in spite of lowering the summary nitric oxides NOx emissions from vehicles. NO2 is much more toxic than nitrogen monoxide NO and it will be specially considered in the next legal testing procedures. There are doubts about the accuracy of analyzing the reactive substances from diluted gas and this project has the objective to show how NO2 is changing as it travels down through the exhaust- and the CVS systems. For legal measurements of NO2 a WLTP-DTP subgroup (Worldwide Light Duty Test Procedures - Diesel Test Procedures) proposed different combinations of NOx-analyzers and analysis of NO and NOx. Some of these set-ups were tested in this work.
Journal Article

Effects of n-Butanol and Isobutanol on Particulate Matter Emissions from a Euro 6 Direct-injection Spark Ignition Engine During Laboratory and on-Road Tests

2015-09-06
2015-24-2513
N-butanol and isobutanol are alcohols that can be produced from biomass by fermentation and are possibly more compatible with existing engines than ethanol. This work reports on the effects of these two isomers on exhaust emissions of an unmodified direct injection spark ignition (DISI) engine. A Ford Focus car with a 1.0-liter Euro 6 Ecoboost DISI engine has been tested on a chassis dynamometer using WLTP and Artemis driving cycles, and on the road on a one-hour test loop containing urban, rural and motorway driving. Two isomers of butanol, 1-butanol and 2-methyl-propanol, were each blended with gasoline at 25% volume. Non-oxygenated gasoline and 15% ethanol in gasoline (E15) were used as reference fuels. The vehicle performed well in terms of cold start, drivability, general performance, and off-cycle particle emissions, staying within several mg of particle mass and about 2×1012 particles (per PMP procedure) per km during laboratory tests.
Technical Paper

Experiences from Nanoparticle Research on Four Gasoline Cars

2015-04-14
2015-01-1079
The invisible nanoparticles (NP)*) from combustion processes penetrate easily into the human body through the respiratory and olfactory pathways and carry numerous harmful health effects potentials. NP count concentrations are limited in EU for Diesel passenger cars since 2013 and for gasoline cars with direct injection (GDI) since 2014. The limit for GDI was temporary extended to 6 × 1012 #/km, (regulation No. 459/2012/EU). Nuclei of metals as well as organics are suspected to significantly contribute especially to the ultrafine particle size fractions, and thus to the particle number concentration. In the project GasOMeP (Gasoline Organic & Metal Particulates) metal-nanoparticles (including sub 20nm) from gasoline cars are investigated for different engine technologies. In the present paper some results of investigations of nanoparticles from four gasoline cars - an older one with MPI and three newer with DI - are represented.
Technical Paper

Particle Emissions of Modern Handheld Machines

2014-11-11
2014-32-0036
The progressing exhaust gas legislation for on- and off-road vehicles includes gradually the nanoparticle count limits. The invisible nanoparticles from different emission sources penetrate like a gas into the living organisms and may cause several health hazards. The present paper shows some results of a modern chain saw with & without oxidation catalyst, with Alkylate fuel and with different lube oils. The measurements focused specially on particulate emissions. Particulates were analysed by means of gravimetry (PM) and granulometry SMPS (PN). In this way the reduction potentials with application of the best materials (fuel, lube oil, ox-cat.) were indicated. It has been shown that the particle mass (PM) and the particle numbers (PN), which both consisting almost exclusively of unburned lube-oil, can attain quite high values, but can be influenced by the lube oil quality and can be considerably reduced with an oxidation catalyst.
Technical Paper

Operation of an Ordinary PFI Engine on n-butanol and Iso-butanol and Their Blends with Gasoline

2014-10-13
2014-01-2618
An ordinary, unmodified port fuel injection spark ignition automobile engine with closed-loop air-fuel ratio control and a three-way catalyst was operated on two butanol isomers, n-butanol and iso-butanol, and their blends with gasoline at steady-state operating points covering both common and potentially problematic regimes. The engine control unit was able to maintain the air-fuel ratio while running on both butanol isomers and their blends with gasoline. Only small changes in the heat release rates, small and insignificant decrease in exhaust gas temperatures, and no excessive increase in emissions were observed. Under commanded enrichment operation, the maximum torque, air-fuel ratio and exhaust emissions were comparable among nearly all fuels tested. The exhaust gas temperatures were comparable among fuels, with a moderate increase observed in some regimes during operation with high share of n-butanol in fuel.
Technical Paper

Measurement of Exhaust Emissions of Small Gasoline Engines Under Real-World Driving Conditions

2014-10-13
2014-01-2811
The paper focuses on portable “on-board” instrumentation and methods for evaluation of exhaust emissions from scooters and various small machinery under real-world driving conditions. Two approaches are investigated here. In one, a miniature on-board system mounted on the equipment itself performs online measurements of the concentrations of the pollutants of interest (HC, CO, CO2, NOx, some property of particulate matter), and measurement or computation of the intake air flow. This approach has been used on a 50 cm3 scooter fitted with a 14-kg on-board system and driven on local routes. Measured concentrations of gaseous compounds, particle mass and total particle length were multiplied with the corresponding intake air flow computed from measured engine rpm, intake air manifold pressure and temperature. In the second approach, a full-flow dilution tunnel, gas analyzers and particle measurement or sampling devices are mounted on an accompanying hand cart or vehicle.
Technical Paper

Real-World On-Road Exhaust Emissions from an Ordinary Gasoline Car Operated on E85 and on Butanol-Gasoline Blend

2013-09-08
2013-24-0102
Bioethanol, produced from renewable sources, is promoted as a fuel in higher concentrations in newer flexible fuel engines, and in lower concentrations in the general fleet. Introduction of a blend of 85% ethanol with gasoline (E85) at a competitive price in the Czech Republic has, however, spontaneously resulted in this fuel being used in “ordinary” engines not adapted for this fuel. This study investigates the operation of a typical gasoline car with fuel injection and three-way catalyst on gasoline, E85, and additionally on a blend of 85% n-butanol with gasoline, as butanol features better material compatibility than ethanol. The car was equipped with a portable, on-board emissions monitoring system and driven along a route comprising city and rural roads, including hills. Multiple runs were made on each fuel to verify test-to-test repeatability.
Technical Paper

Investigations of Changes of the 2-Stroke Scooters Nanoparticles in the Exhaust- and CVS-System

2013-09-08
2013-24-0178
Nanoparticle emissions of two 2-stroke scooters were investigated along the exhaust and the CVS (Constant Volume Sampling) systems. Two configurations were tested: regular full-flow dilution configuration (denoted as “closed”) and also a modified sampling configuration (denoted as “open”). The scooters represent two distinct modern technologies. One scooter had direct injection TSDI*) (Two-Stroke Direct Injection). The other had a carburettor. Depending on the technology, the scooters produce different kind of aerosols (state-of-oxidation and SOF content). Moreover, the scooters were operated with and without oxidation catalyst. The tests were performed at two constant vehicular speeds (20 km/h and 40 km/h). The measuring procedures are those established during the previous research of the Swiss Scooter Network. The nanoparticulate emissions were measured using SMPS (Scanning Mobility Particle Sizer) and DC (Diffusion Charging) sensors.
Technical Paper

NO2-Formation in Diesel Particle Filter Systems

2013-04-08
2013-01-0526
NO₂ is much more toxic than NO. The average proportion of NO₂ in exhaust gases of vehicles increases significantly due to the use of oxidation catalysts and catalytic coatings in the exhaust gas systems during the last decades combined with generalization of using low sulfur fuels. Diesel oxidation catalysts (DOC) and Pt-containing DPF coatings are widely used to support the regeneration of particle filters, being a source of strongly increased production of NO₂. The present work shows some examples and summarizes the experiences in this matter performed at the Laboratories for IC-Engines & Exhaust Emissions Control (AFHB) of the University of Applied Sciences Biel-Bienne, Switzerland, during some research activities on engine dynamometers in the years 2010-2012.
Technical Paper

Diesel Emissions with DPF & SCR and Toxic Potentials with BioDiesel (RME) Blend Fuels

2013-04-08
2013-01-0523
The use of alternative fuels and among them the biofuels of 1st generation - fatty acid methyl esters FAME's and pure plants oils - for propulsion of IC engines is an important objective in several countries in order to save the fossil fuels and to limit the CO₂ production. The properties of bio-fuels and bio-blend-fuels can vary and this has an impact on the operation and emissions of diesel engines and on the modern exhaust aftertreatment systems. The present paper represents the most important results obtained with RME at AFHB, EMPA and EC-JRC. Most of the activities were performed in the network project BioExDi (Biofuels, Exhaust Systems Diesel) in collaboration between industry and research institutes.
Technical Paper

Effect of Higher Content N-Butanol Blends on Combustion, Exhaust Emissions and Catalyst Performance of an Unmodified SI Vehicle Engine

2012-09-10
2012-01-1594
To reduce exhaust emissions and dependency on petroleum-based fuels, various alcohols have been considered as gasoline substitutes for spark ignition engines. In the existing vehicle fleet, the use of ethanol, the most widely used alcohol, is practically limited to blends in relatively small concentrations with gasoline, due to its hygroscopicity, aggressivity, substantially lower heat content, and high latent heat. Butanol has relatively low toxicity, can be produced from biomass, and has higher energy density, lower latent heat, lower hygroscopicity and lower aggressivity than ethanol. In this study, the effects of blends of 30% and 50% of n-butanol (1-butanol) with gasoline on combustion process, engine control unit adaptation and exhaust emissions before and after a three-way catalyst were examined on a 1.2-liter, three-cylinder, four-valves-per-cylinder, naturally aspirated port-fuel-injected Skoda 1.2 HTP spark ignition engine coupled to an engine dynamometer.
Technical Paper

DPF's Regeneration Procedures and Emissions with RME Blend Fuels

2012-04-16
2012-01-0844
The fatty acid methyl esters (FAME's) - in Europe mostly RME (Rapeseed methyl ester) - are used in several countries as alternative biogene diesel fuels in various blending ratios with fossil fuels (Bxx). Questions often arise about the influences of these biocomponents on the modern exhaust aftertreatment systems and especially on the regeneration of diesel particle filters (DPF). In the present work different regeneration procedures of DPF systems were investigated with biofuels B0, B20 & B100. The tested regeneration procedures were: - passive regenerations: DOC + CSF; CSF alone, and - active regenerations: standstill burner; fuel injections & DOC. During each regeneration on-line measurements of regulated and unregulated emission components (nanoparticles & FTIR) were conducted. It can be stated that the increased portion of RME in fuel provokes longer time periods to charge the filter with soot.
Technical Paper

Influences of Different Exhaust Filter Configurations on Emissions of a 2-Stroke Scooter Peugeot TSDI

2011-09-11
2011-24-0203
Exhaust emissions measurements of a small 2-S Scooter Peugeot TSDI*), 50cc with different particle filters have been performed in this present work according to the measuring procedures, which were established in the previous research in the Swiss Scooter Network, [1, 2, 3, 4, 5, 6, 7, 8, 9]. The investigated particle filtration materials were supplied from different manufacturers as samples without specifications and they were applied by the research laboratory in a special muffler able to be taken apart. The investigated scooter represented a modern (2002) 2-stroke technology with direct injection, with oxidation catalyst and with injection of the lube oil to the intake air. Since there is a special concern about the particle emissions of the small engines, the particle mass and nanoparticle measurements were systematically carried out. The nanoparticulate emissions were measured by means of SMPS (CPC) and NanoMet*).
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