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This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.

Pure biodiesel is non-toxic, biodegradable and greenhouse gas neutral alternative fuel with potential successful future but reduced quantitative information is available about the impact of biodiesel on engine durability and long period usage effects. In this study, a commercial light duty Diesel engine installed on an engine test bench has been operated fuelled with pure biodiesel (B100 referred to the EN-14214 standard) during a period test of 300 hours in order to analyze engine performance and components behavior. A engine characterization has been completed using conventional diesel fuel (EN 590). Then, following a specific defined operation cycle and fuelled with pure biodiesel, a study over different engine components such as: engine oil, fuel filters, Diesel Particulate Filter (DPF), so on, has been done in order to obtain possible negative effects and modifications required over maintenance policies applied to them.

In-cylinder emission control strategies, such as modifications of injection pressure and injection timing, have been used by researchers in order to reduce exhaust emissions and to comply with the legislation standards. Since some years ago post-injections have been studied and are well known as being efficient for soot emissions reduction. Although is well known that diesel gaseous and particle mass emissions have been reduced progressively over the last twenty years in response to the restrictive emission legislation and due to the application of new technologies The aim of this work is to help develop and understand the effect of the post-injection on diesel exhaust particle size distributions. The approach is to use a modern, well instrumented research engine equipped with a flexible high pressure fuel injection system. The results of this work are available to help provide guidelines for strategies to achieve reductions of the particle size distributions in diesel engines.