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The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-17 (since November 2, 2000, through October 23, 2008). The water supply sources and structure, consumption and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station's water supply hardware with a system for water reclamation from urine SRV-U is emphasized. The prospects of regenerative water supply system development are considered.

An EMU water processing kit (Airlock Coolant Loop Recovery – A/L CLR) was developed as a corrective action to Extravehicular Mobility Unit (EMU) coolant flow disruptions experienced on the International Space Station (ISS) in May of 2004 and thereafter. Conservative schedules for A/L CLR use and component life were initially developed and implemented based on prior analysis results and analytical modeling. The examination of post-flight samples and EMU hardware in November of 2006 indicated that the A/L CLR kits were functioning well and had excess capacity that would allow a relaxation of the initially conservative schedules of use and component life. A relaxed use schedule and list of component lives were implemented thereafter. Since the adoption of the relaxed A/L CLR schedules of use and component lives, several A/L CLR kit items, transport loop water samples and sensitive EMU transport loop components have been examined to gage the impact of the relaxed requirements.

Based on experience obtained in operation of the water and oxygen recovery systems installed onboard the Russian space stations Salut, Mir and the International Space Station ISS, data on the water and oxygen balance for a space station are presented as well as operational parameters and performance data of the systems. Using the data obtained design analysis of an integrated life support system for water and oxygen recovery based on physical/chemical means to be installed on a promising space station is carried out. Mandatory verification tests of new process (technologies) and recovery systems are to be conducted on ISS.

The paper summarizes the experience gained on the ISS water management system during the missions of ISS-1 through ISS-16 (since November 2 2000, through December 31, 2007). The water supply sources and structure, consumption and supply balance at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on a board the ISS and the need to supplement the station's water supply hardware with a system for water reclamation from urine, water from a carbon dioxide reduction system and hygiene water is shown.

Following the Columbia accident, the EMUs (Extravehicular Mobility Units) onboard the ISS (International Space Station) went unused for an extended period of time. Upon startup, the units experienced a failure in the coolant systems. The failure resulted in a loss of EVA (Extravehicular Activity) capability from the US segment of the ISS. A failure investigation determined that chemical and biological contaminants and byproducts from the ISS Airlock Heat Exchanger, and the EMU itself, fouled the magnetically coupled pump in the EMU Transport Loop Fan/Pump Separator leading to a lack of coolant flow. Remediation hardware (the Airlock Coolant Loop Remediation water processing kit) and a process to periodically clean the EMU coolant loops on orbit were devised and implemented. The intent of this paper is to report on the successful implementation of the resultant hardware and process, and to highlight the go-forward plan.

The Johnson Space Center Water and Food Analytical Laboratory (WAFAL) performed detailed ground-based analyses of archival water samples for verification of the chemical quality of the International Space Station (ISS) potable water supplies for Expeditions 14 and 15. During the 12-month duration of both expeditions, the Space Shuttle docked with the ISS on four occasions to continue construction and deliver additional crew and supplies; however, no Shuttle potable water was transferred to the station during Expedition 14. Russian ground-supplied potable water and potable water from regeneration of humidity condensate were both available onboard the ISS for consumption by the Expeditions 14 and 15 crews. A total of 16 chemical archival water samples were collected with U.S. hardware during Expeditions 14 and 15 and returned on Shuttle flights STS-116 (12A.1), STS-117 (13A), STS-118 (13A.1), and STS-120 (10A) in December 2006, and June, August, and November of 2007, respectively.

We are developing a drinking water test kit based on colorimetric-solid phase extraction (C-SPE) for use onboard the International Space Station (ISS) and on future Lunar and/or Mars missions. C-SPE involves measuring the change in diffuse reflectance of indicator disks following their exposure to a water sample. We previously demonstrated the effectiveness of C-SPE in measuring iodine in microgravity. This analytical method has now been extended to encompass the measurement of total I (i.e., iodine, iodide, and triiodide). This objective was accomplished by introducing an oxidizing agent to convert iodide and triiodide to iodine, which is then measured using the indicator disks previously developed for iodine. We report here the results of a recent series of C-9 microgravity tests of this method. The results demonstrate that C-SPE technology is poised to meet the total I monitoring requirements of the international space program.

The crews of Expeditions 12 and 13 aboard the International Space Station (ISS) continued to rely on potable water from two different sources, regenerated humidity condensate and Russian ground-supplied water. The Space Shuttle launched twice during the 12-months spanning both expeditions and docked with the ISS for delivery of hardware and supplies. However, no Shuttle potable water was transferred to the station during either of these missions. The chemical quality of the ISS onboard potable water supplies was verified by performing ground analyses of archival water samples at the Johnson Space Center (JSC) Water and Food Analytical Laboratory (WAFAL). Since no Shuttle flights launched during Expedition 12 and there was restricted return volume on the Russian Soyuz vehicle, only one chemical archive potable water sample was collected with U.S. hardware and returned during Expedition 12. This sample was collected in March 2006 and returned on Soyuz 11.

Phase separation is one of the most significant obstacles encountered during the development of analytical methods for water quality monitoring in spacecraft environments. Removing air bubbles from water samples prior to analysis is a routine task on earth; however, in the absence of gravity, this routine task becomes extremely difficult. This paper details the development and initial ground testing of liquid metering centrifuge sticks (LMCS), devices designed to collect and meter a known volume of bubble-free water in microgravity. The LMCS uses centrifugal force to eliminate entrapped air and reproducibly meter liquid sample volumes for analysis with Colorimetric Solid Phase Extraction (C-SPE). Previous flight experiments conducted in microgravity conditions aboard the NASA KC-135 aircraft demonstrated that the inability to collect and meter a known volume of water using a syringe was a limiting factor in the accuracy of C-SPE measurements.

Colorimetric-solid phase extraction (C-SPE) is being developed as a method for in-flight monitoring of spacecraft water quality. C-SPE is based on measuring the change in the diffuse reflectance spectrum of indicator disks following exposure to a water sample. Previous microgravity testing has shown that air bubbles suspended in water samples can cause uncertainty in the volume of liquid passed through the disks, leading to errors in the determination of water quality parameter concentrations. We report here the results of a recent series of C-9 microgravity experiments designed to evaluate manual manipulation as a means to collect bubble-free water samples of specified volumes from water sample bags containing up to 47% air. The effectiveness of manual manipulation was verified by comparing the results from C-SPE analyses of silver(I) and iodine performed in-flight using samples collected and debubbled in microgravity to those performed on-ground using bubble-free samples.

The paper summarizes the six years' experience gained with the ISS water management system during the missions ISS-1 through ISS-14 (since November 2, 2000 through October 31, 2006). The water supply sources, consumption structure and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery during space missions and the prospects of regenerative water supply of an interplanetary space station are discussed. The aim of this paper is to summarize the water supply experience and to provide recommendations for a perspective water supply integrated system based on water recovery.

During the twelve month period comprising Expeditions 10 and 11, the chemical quality of the potable water onboard the International Space Station (ISS) was verified through the return and ground analysis of water samples. The two-man Expedition 10 crew relied solely on Russian-provided ground water and reclaimed cabin humidity condensate as their sources of potable water. Collection of archival water samples with U.S. hardware has remained extremely restricted since the Columbia tragedy because of very limited return volume on Russian Soyuz vehicles. As a result only two such samples were collected during Expedition 10 and returned on Soyuz 9. The average return sample volume was only 250 milliliters, which limited the breadth of chemical analysis that could be performed. Despite the Space Shuttle vehicle returning to flight in July 2005, only two potable water samples were collected with U.S. hardware during Expedition 11 and returned on Shuttle flight STS-114 (LF1).

The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-11 (since November 2 2000, through October 10, 2005). The water supply sources and structure, consumption and supply balance at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station’s water supply hardware with a system for water reclamation from urine SRV-U is shown. The prospects of regenerative water supply system development are considered.

Following the Colombia accident, the Extravehicular Mobility Units (EMU) onboard ISS were unused for several months. Upon startup, the units experienced a failure in the coolant system. This failure resulted in the loss of Extravehicular Activity (EVA) capability from the US segment of ISS. With limited on-orbit evidence, a team of chemists, engineers, metallurgists, and microbiologists were able to identify the cause of the failure and develop recovery hardware and procedures. As a result of this work, the ISS crew regained the capability to perform EVAs from the US segment of the ISS Figure 1.

The paper summarizes the experience gained with the ISS water management system during the missions ISS-1 through ISS-10 (since November 2 2000, through November 30, 2004). The water supply sources and structure, consumption and supply balance and balance specifics at various phases of space station operation are reviewed. The performance data of the system for water recovery from humidity condensate SRV-K and urine feed and pretreatment system SPK-U in the Russian orbital segment are presented. The key role of water recovery on board the ISS and the need to supplement the station’s water supply hardware with a system for water reclamation from urine SRV-U is emphasized. The prospects of regenerative water supply system development are considered.

With the Shuttle fleet grounded, limited capability exists to resupply in-flight water quality monitoring hardware onboard the International Space Station (ISS). As such, verification of the chemical quality of the potable water supplies on ISS has depended entirely upon the collection, return, and ground-analysis of archival water samples. Despite the loss of Shuttle-transferred water as a water source, the two-man crews during Expedition 8 and Expedition 9 maintained station operations for nearly a year relying solely on the two remaining sources of potable water; reclaimed humidity condensate and Russian-launched ground water. Archival potable water samples were only collected every 3 to 4 months from the systems that regenerate water from condensate (SRV-K) and distribute stored potable water (SVO-ZV).

The need to preserve crew health during space missions, combined with the level of demand on both crew time and cargo space, dictates the development of fast, facile methods capable of monitoring trace quantities of several analytes in spacecraft water. This presentation describes our efforts to address this need by using Multiplexed Colorimetric Solid Phase Extraction (MC-SPE). MC-SPE is a sorption-spectrophotometric platform based upon the extraction of analytes onto membranes impregnated with selective colorimetric agents. Quantification is accomplished using Kubelka-Munk values calculated from the diffuse reflectance spectrum of the complex on the surface of the membrane and calibration curves. In traditional C-SPE, concentration factors of up to 1000 can be realized for a single analysis, yielding low detection limits (ppb – ppm range) with a total analysis time of 75–90 s. Herein, we describe the performance and continued refinement of the MC-SPE platform.

We are developing a spacecraft water quality monitoring system based on measuring the change in diffuse reflectance of indicator disks following exposure to a water sample. The most widely used approach for deriving quantitative information from a diffuse reflectance spectrum involves an initial Kubelka-Munk transformation of the reflectance data. Provided the assumptions underlying the transformation are satisfied, the magnitude of the resulting function varies linearly with analyte concentration. We measure diffuse reflectance spectra using a commercial-off-the-shelf handheld spectrophotometer designed for color matching applications. Spectra are currently downloaded and transformed to obtain the value of the Kubelka-Munk function at a detection wavelength diagnostic of the analyte. This value is then used to quantify the analyte via a standard response curve.

The paper deals with the performance data of the service module Zvezda integrated water supply system of the International Space Station (ISS) as of March 31, 2004. The water supply and demand balance are analyzed. It is shown that water recovery from humidity condensate has been especially important when water delivery by Space Shuttles was terminated. The SRV-K contribution in potable water supply for crew needs was up to 76%. The data of humidity condensate and recovered water compositions are reviewed. The effective cooperation of the international partners on part of life support is shown. Water recovery future prospects are discussed.

Ever since the first crew arrived at the International Space Station (ISS), archival potable water samples have been collected and returned to the ground for detailed chemical analysis in order to verify that the water supplies onboard are suitable for crew consumption. The Columbia tragedy, unfortunately, has had a dramatic impact on continued ISS operations. A major portion of the ISS water supply had previously consisted of Shuttle-transferred water. The other two remaining sources of potable water, i.e., reclaimed humidity condensate and Russian-launched ground water, are together insufficient to maintain 3-person crews. The Expedition 7 crew launched in April of 2003 was, therefore, reduced from three to two persons. Without the Shuttle, resupply of ISS crews and supplies is dependent entirely on Russian launch vehicles (Soyuz and Progress) with severely limited up and down mass.