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In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.

Engine technologies using efficient combustion and down-sizing turbo have become important in order to reduce automotive CO2 emissions. However, the exhaust gas temperature also becomes lower by these technologies. As a result, the catalyst performance becomes lower. Therefore it is necessary to develop low temperature active catalysts to reduce emissions. This research was focused on Pd/CeO2, and it’s able to oxidize CO at low temperatures. In order to increase the catalyst activity, the addition of some elements to the CeO2 was studied. Zn addition was found to have an advantage to reduce the CO light off temperature by 60 °C. Then, we tried to clarify the cause of improvement. As a result, it made clear that the Zn addition promotes the active oxygen release from the CeO2 surface. However, repeated engine exhaust gas tests indicated a decline in purification performance.

Regulations that limit emissions of pollutants from gasoline-powered cars and trucks continue to tighten. More than 75% of emissions through an FTP-75 regulatory test are released in the first few seconds after cold-start. A factor that controls the time to catalytic light-off is the heat capacity of the catalytic converter substrate. Historically, substrates with thinner walls and lower heat capacity have been developed to improve cold-start performance. Another approach is to increase porosity of the substrate. A new material and process technology has been developed to significantly raise the porosity of thin wall substrates (2-3 mil) from 27-35% to 55% while maintaining strength. The heat capacity of the material is 30-38% lower than existing substrates. The reduction in substrate heat capacity enables faster thermal response and lower tailpipe emissions. The reliance on costly precious metals in the washcoat is demonstrated to be lessened.

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.