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Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.

Abstract In the current research, an aluminum alloy AA8090 is welded using the friction stir welding (FSW) technique. The main objective is to eliminate the chances of defects in the weld joint, which were observed in the conventional joining process. Experiments were planned according to the one factor at a time (OFAT) approach. The input process parameters involved during the present work are welding speed (WS), rotational speed (RS), tilt angle (TA), and dwell time (DT). However, the response variables investigated at different input parametric combinations are tensile strength (TS), percentage elongation (EL), microhardness (MH), and macroscopic structure. Due to the combination of both attributes of optimization (the higher the better in TS and the lower the better in EL), the multi-performance quality characteristics optimization approach, i.e., grey relational analysis (GRA), is implemented.

Abstract Biodiesel was found to be the best candidate to replace diesel fuel mainly due to being renewable, biodegradable, and non-toxic and reduce greenhouse gases, which cause global warming. Nowadays, biodiesel is blended with diesel fuel in different concentrations depending on the country of usage and is used in diesel engines. Concerns about biodiesel were raised after premature fouling of fuel filters were reported before meeting their mileage requirement. Three filters from Brazil were analyzed using different techniques (Energy Dispersive X-Ray [EDX], Fourier Transform Infrared Spectroscopy [FTIR], Thermogravimetric Analysis [TGA], Time of Flight-Secondary Ion Mass Spectrometry [ToF-SIMS], and Gas Chromatography/Mass Spectrometry [GC/MS]) to understand the chemical composition of the filter deposits and highlight the main compounds responsible for the blockage.

Abstract Sustainable practices are taking precedence across many industries, as evident from their shift towards the use of environmentally responsible materials, such as natural fiber-reinforced acrylated epoxidized soybean oil (NF-AESO). However, due to the lower reactivity of AESO, the curing reaction usually requires higher temperatures and longer curing time (e.g., 150°C for 6-12 h), thus making the entire process unsustainable. In this study, we demonstrate the potential power of photons towards manufacturing NF-AESO composites in a sustainable manner at room temperature (RT) within 10 min. Two photoinitiators, i.e., the 2,2-dimethoxy phenylacetophenone (DMPA) and 1-hydroxycyclohexyl phenyl ketone (HCPK), were evaluated and compared with the thermal initiator, i.e., tert-butyl perbenzoate (TBPB). Based on the mechanical performance of the AESOs, the photoinitiation system for NF-AESO was optimized.

Abstract Engine oils have complex packages of additives aimed at improving their tribological properties. However, interactions between elements of these additives may hinder the cooling ability of these oils. The current article addresses the influence of the interaction between chemical elements of oil additives on the cooling capacity of oils for different wall superheats (0°C-150°C) and oil bulk temperatures (60°C, 100°C, and 150°C). A back-propagation neural network (BPNN) is used to conduct the present work. The NN is trained on experimental heat transfer data of five commercial engine oils. Enhancement intensity, interaction sensitivity, and interaction stability of additive elements are investigated for the range of element concentrations of the experimental dataset.

Abstract Epoxies, synthesized from bisphenol-A (BPA) and epichlorohydrin (ECH), are predominantly used as coatings, adhesives, and matrix material in fiber-reinforced composites for body-in-white (BiW) applications in the automotive sector. However, given the production of conventional epoxies from nonrenewable petroleum resource and toxicity of BPA, several initiatives have been undertaken by researchers to synthesize alternative epoxies from various bio-sources that are free of BPA and exhibit similar mechanical performance. As a result, such bio-sourced epoxies are almost immediately termed as “ecofriendly,” despite the lack of comprehensive evaluation of their ecological performance that takes into account enhanced natural resource usage and associated impacts accompanying such epoxies.

Abstract The purpose of this article is to study the antifriction and anti-wear effect of GCr15 bearing steel under paraffin base oil and the base oil with two additives of T405 sulfurized olefin and nano-MoS2 and compare the synergistic lubrication effect of two different additives (MoS2 and T405) in paraffin base oil. The tribological properties of GCr15 bearing steel under different lubrication conditions were tested on a ball-on-disk tribometer. The three-dimensional profile of disk’s worn surfaces and the scanning electron microscope (SEM) micrographs of corresponding steel balls were analyzed at the same time. The wettability of lubricating oils on the surface of friction pairs and the dispersibility of MoS2 in base oil were characterized.

Abstract Metal Pick-Up (MPU) is a problematic phenomenon in automotive disc brakes. MPU generally forms as some metal lumps on the surface of the brake pad. If brake pads have MPU, during braking they would cause grooving of the disc rotor, generating brake noise and deteriorating the performance of the brake. The previous literature has so far reported that the source of the MPU is an Fe component from a disc rotor or brake pads. However, only a few of the generation mechanisms of MPU have been proven. We investigate MPU to completely elucidate the mechanism of MPU generation by using different analyses than the previous literature. First, to find out the source of MPU generation, we focus on the chemical reaction of a certain component with wear debris during braking, and some of the verification experiments are conducted under the conditions of simulated friction interface.

Engineering plastics are widely used in many tribological applications due to their inherent advantages such as reduced weight, ease of manufacturing, improved chemical compatibility, and damping characteristics. However, the process of selecting an appropriate polymeric material system for a specific application involves significant experimentation.

Abstract Automotive interior coatings for flexible and rigid substrates represent an important segment within automotive coating space. These coatings are used to protect plastic substrates from mechanical and chemical damage, in addition to providing colour and design aesthetics. These coatings are expected to resist aggressive chemicals, fluids, and stains while maintaining their long-term physical appearance and mechanical integrity. Designing such coatings, therefore, poses significant challenges to the formulators in effectively balancing these properties. Among many factors affecting coating properties, the cross-link density (XLD) and solubility parameter (δ) of coatings are the most predominant factors.

Abstract Current End-of-Life Vehicle (ELV) recycling processes are mainly based on mechanical separation techniques. These methods are designed to recycle those metals with the highest contribution in the vehicle weight such as steel, aluminum, and copper. However, a conventional vehicle uses around 50 different types of metals, some of them considered critical by the European Commission. The lack of specific recycling processes makes that these metals become downcycled in steel or aluminum or, in the worst case, end in landfills. With the aim to define several ecodesign recommendations from a raw material point of view, it is proposed to apply a thermodynamic methodology based on exergy analysis. This methodology uses an indicator called thermodynamic rarity to assess metal sustainability. It takes into account the quality of mineral commodities used in a vehicle as a function of their relative abundance in Nature and the energy intensity required to extract and process them.

Abstract In this paper, the results of experiments to determine the effects of silicon-containing compounds in biogas on the performance of spark-ignited gas engines for use in CNG vehicles are presented. Initial research was performed on micro-CHP units, which have many features common with automotive engines, to identify engine components sensitive for silica deposition prior to investigating a practical CNG engine. The experiments on the micro-CHP units revealed that the catalyst was the most sensitive part for silica fouling, with strong impact on the reduction of NOx. With the insight gained from these experiments, an 9-week endurance test was performed on a light-duty CNG vehicle.

Abstract The supersession of metallic alloys with lightweight, high-strength composites is popular in the aircraft industry. However, aviation electronic enclosures for large format batteries and high power conversion electronics are still primarily made of aluminum alloys. These aluminum enclosures have attractive properties regrading structural integrity for the heavy internal parts, electromagnetic interference (EMI) suppression, electrical bonding for the internal cells, and/or electronics and failure containment. This paper details a lightweight carbon fiber composite chassis developed at Meggitt Sensing Systems (MSS) Securaplane, with a copper metallic mesh co-cured onto the internal surfaces resulting in a 50% reduction in weight when compared to its aluminum counterpart. In addition to significant weight reduction, it provides equal or improved performance with respect to EMI, structural and flammability performance.

Abstract The use of nanomaterials and nanostructures have been revolutionizing the advancements of science and technology in various engineering and medical fields. As an example, Carbon Nanotubes (CNTs) have been extensively used for the improvement of mechanical, thermal, electrical, magnetic, and deteriorative properties of traditional composite materials for applications in high-performance structures. The exceptional materials properties of CNTs (i.e., mechanical, magnetic, thermal, and electrical) have introduced them as promising candidates for reinforcement of traditional composites. Most structural configurations of CNTs provide superior material properties; however, their geometrical shapes can deliver different features and characteristics. As one of the unique geometrical configurations, helical CNTs have a great potential for improvement of mechanical, thermal, and electrical properties of polymeric resin composites.

Abstract Tin sulfides (SnS and SnS2), represent a safer and greener alternative to other metal sulfides such as copper sulfides, and MoS2 etc. Their behavior is usually associated to that of solid lubricants such as graphite. A mixture of tin sulfides, with the 65 wt% of SnS2, has been characterized by scanning electron microscopy and by thermal gravimetric analysis (TGA). In order to investigate the effect of tin sulfides upon two crucial friction material ingredients, two mixtures were prepared: the former was made by mixing tin sulfides with a natural flake graphite and the latter was made mixing tin sulfides with a straight novolak. They were analyzed by TGA and differential thermal analysis (DTA) in both nitrogen and air. Some interferences were detected between tin sulfides and graphite in air.