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A recently developed in-cylinder fuel injection probe was used to deposit a small amount of liquid fuel on various surfaces within the combustion chamber of a 4-valve engine that was operating predominately on liquefied petroleum gas (LPG). A fast flame ionization detector (FFID) was used to examine the engine-out emissions of unburned and partially-burned hydrocarbons (HCs). Injector shut-off was used to examine the rate of liquid fuel evaporation. The purpose of these experiments was to provide insights into the HC formation mechanism due to in-cylinder wall wetting. The variables investigated were the effects of engine operating conditions, coolant temperature, in-cylinder wetting location, and the amount of liquid wall wetting. The results of the steady state tests show that in-cylinder wall wetting is an important source of HC emissions both at idle and at a part load, cruise-type condition. The effects of wetting location present the same trend for idle and part load conditions.